Analysis of the Henze precipitate from the blood cells of the ascidian<Emphasis Type="Italic"> Phallusia mammillata</Emphasis>

The Henze precipitate, a peculiar blue-green microparticulate obtained by lysis of the blood cells of the ascidian Phallusia mammillata (Protochordata), was investigated with atomic force microscopy (AFM), scanning electron microscopy (SEM) and X-ray microanalysis. The precipitate was collected from the Henze solution, an unstable red-brown product obtained by treating blood with distilled water, whose degradation yields a characteristic blue-green product. The microparticulates measured 50–100 µm in diameter and appeared irregular in shape. SEM examination showed smooth, roughly round boundaries. The microparticulate surface examined with AFM appeared as an irregular matrix formed by 70–320-nm-wide mammillate composites, including and embedding small (500–800 nm wide) crystal-like multilayered formations. X- ray analysis showed that the elements present in these same precipitates were mainly C, Si, Al and O. The microparticulate composition appeared close to those of natural waxes or lacquers, embedding amorphous silicates and/or other Si–Al components. The unusual occurrence of Si in ascidian blood and its role are discussed.     

Metallisch leitende Polymere — Jagdgründe für Solitonen?

Polyacetylene is presented as the prototype of a metallic conducting polymer. The concepts of one-dimensional metal physics are illustrated and special attention is drawn to a structural defect called “soliton”. Electrical, magnetic, and optical experiments connected with solitons are discussed. The authors' opinion is expressed that present experimental results do not yet furnish strong evidence for the existence of solitons in polyacetylene, but that the soliton idea is a fruitful stimulus for further investigations and novel applications.