Occurence and Distribution of Polycyclic Aromatic Hydrocarbons in Ankara Precipitation

Urban atmospheric environment contains many trace organic pollutants that are related to the incomplete fuel combustion in domestic heating, industrial plants and automobile traffic. Removal of these pollutants from the atmosphere takes place through wet and dry deposition as well as chemical transformations. In this study, concentrations of polycyclic aromatic hydrocarbons (PAHs) in wet deposition samples were determined at an urban site of Turkey. Wet and dry deposition samples were collected using Andersen Rain Sampler. The sampler was modified accordingly for the collection of organic pollutants. Collected samples were preconcentrated by using solid phase extraction (SPE) disks and consecutively analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Among the 13 compounds quantified in this study, anthracene, fluoranthene, and pyrene were found more frequently and at elevated concentrations (202, 271 and 260 ng L^-1 mean concentrations, respectively).Concentrations of PAHs were found to be high in winter period.     

Pilot‐scale demonstration of in situ capping of PCB‐containing sediments in the lower Grasse River

A fish‐consumption advisory is currently in effect in a seven‐mile stretch of the Grasse River in Massena, New York, due to elevated levels of PCBs in fish tissue. One remedial approach that is being evaluated to reduce the PCB levels in fish from the river is in situ capping. An in‐river pilot study was conducted in the summer of 2001 to assess the feasibility of capping PCB‐containing sediments of the river. The study consisted of the construction of a subaqueous cap in a seven‐acre portion of the river using various combinations of capping materials and placement techniques. Optimal results were achieved with a 1:1 sand/topsoil mix released from a clamshell bucket either just above or several feet below the water surface. A longer‐term monitoring program of the capped area commenced in 2002. Results of this monitoring indicated: 1) the in‐place cap has remained intact since installation; 2) no evidence of PCB migration into and through the cap; 3) groundwater advection through the cap is not an important PCB transport mechanism; and 4) macroinvertebrate colonization of the in‐place cap is continuing. Additional follow‐up monitoring in the spring of 2003 indicated that a significant portion of the cap and, in some cases, the underlying sediments had been disturbed in the period following the conclusion of the 2002 monitoring work. An analysis of river conditions in the spring of 2003 indicated that a significant ice jam had formed in the river directly over the capping pilot study area, and that the resulting increase in river velocities and turbulence in the area resulted in the movement of both cap materials and the underlying sediments. The pilot cap was not designed to address ice jam–related forces on the cap, as the occurrence of ice jams in this section of the river had not been known prior to the observations conducted in the spring of 2003. These findings will preclude implementation of the longer‐term monitoring program that had been envisioned for the pilot study. The data collected immediately after cap construction in 2001 and through the first year of monitoring in 2002 serve as the basis for the conclusions presented in this article. It should be recognized that, based on the observation made in the spring of 2003, some of these conclusions are no longer valid for the pilot study area.The occurrence of ice jams in the lower Grasse River and their importance on sediments and PCBs within the system are currently under investigation. © 2003 Wiley Periodicals, Inc.     

Mitigating nutrient leaching with a sub-surface drainage layer of granulated tires

Markets for scrap tires have expanded since the early 1990s with the development of value-added applications such as tire-derived fuel and crumb-rubber-amended asphalt. Granulated tires have also displayed the ability to adsorb volatile organic compounds, indicating that the rubber material can be a useful filter media. Sand-based root zones, typically used for golf course putting green and athletic field construction, lack sufficient cation exchange capacity to restrict nitrogen and phosphorus migration through the root zone and into sub-surface drainage systems. Therefore, the adsorptive properties of tire rubber for retaining nitrogen and phosphorus were studied when applied as a distinct sub-surface drainage or intermediate layer in golf course putting greens. A statistically significant reduction in the concentration of nitrate in leachate was achieved by replacing traditional pea gravel with equally sized granulated tires for the drainage layer media, although the mechanism of nitrate mitigation remains unclear. The results indicate that using granulated tires as a drainage layer or fill material beneath sand-based root zones does not compromise the function of the profile or quality of the vegetation while creating an environmentally beneficial and value-added option for scrap tire reuse.     

Assessing the Performance Level of a Water System

Water, Air, &; Soil Pollution: Focus - What should System Managers prefer? Systems that never fail or systems that remain safe during a failure? The present paper tries to give an answer to this...     

Biodegradable Water Soluble Copolymer for Antimicrobial Applications

Synthesis and characterization of novel biodegradable, water soluble and optically active DL-malic acid (DMA) and citric acid (CA) copolymers were studied for possible use as antibacterial agents. The copolymers were synthesized by direct bulk melt condensation in the absence of a catalyst above 150 °C. Characterization of obtained copolymers was carried out with the help of infrared absorption spectra, differential scanning calorimetry and thermo gravimetric analysis. The antibacterial activity of copolymers against bacteria was investigated. The results obtained shows the above copolymers possess a broad wound dressing activity against different types of bacteria and may be useful as antibacterial agents.     

Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions

Activated carbon, developed from fertilizer waste, has been used for the removal of Hg²⁺, Cr⁶⁺, Pb²⁺, and Cu²⁺. Mass transfer kinetic approach has been successfully applied for the determination of various parameters necessary for designing a fixed-bed absorber. Parameters selected are the length of the (PAZ) primary adsorption zone (δ), total time involved for the establishment of primary adsorption zone (t_x), mass rate of flow to the absorber (F_m), time for primary adsorption zone to move down its length (t_δ), amount of adsorbate adsorbed in PAZ from breakpoint to exhaustion (M_s), fractional capacity (f), time of initial formation of PAZ (t_f) and per cent saturation of column at break point. Chemical regeneration has been achieved with 1 M HNO₃.     

电化学间接氧化法处理H2S气体的研究

采用填料塔对铁盐溶液吸收H2S 的过程进行了初步研究,考察了气液比、填料层高度、吸收温度、Fe^3 浓度,进气H2S浓度和H^ 浓度等因素对H2S去除率的影响。结果表明,气液比、 填料层高度和吸收温度对吸收效率的影响比较显著。通过正交试验选出最佳工艺条件,在此工艺条件下H2S的去除率 接近100％。     

Sorption of Some Rare Earth Elements from Acidic Solution onto Poly(acrylic acid–co-acrylamide/16, 16-dimethylheptadecan-1-amine) Composite

Journal of Polymers and the Environment - In this study, Acrylic acid (AA), acrylamide (AM), and 16,16-dimethylheptadecan-1-amine (PJM-T) were copolymerized using gamma irradiation with 60Co...     

Characterization and Biotechnological Functional Activities of Exopolysaccharides Produced by Lysinibacillus fusiformis KMNTT-10

Journal of Polymers and the Environment - In this study, the production and physicochemical characterization of exopolysaccharide (EPS) produced by Lysinibacillus fusiformis KMNTT-10 were...