Effectiveness of porous covers for control of ammonia, reduced sulfur compounds, total hydrocarbons, selected volatile organic compounds, and odor from hog manure storage lagoons

Anaerobic lagoons are a major source of odor at concentrated animal feeding operations. Seven different kinds of artificial (geotextile and polyethylene foam) and natural (straw and redwood) permeable lagoon covers were evaluated for their potential to reduce odorous emissions generated by anaerobic waste lagoons. A novel floating sampling raft was constructed and used to simultaneously evaluate the effectiveness of lagoon covers on an operating swine waste lagoon. The air collected from the raft was evaluated for odor, total reduced sulfur (TRS) compounds, ammonia, total hydrocarbons, dimethyldisulfide, and trimethylamine. The emission rates from the lagoon were highly variable both temporally and spatially. All of the lagoon covers substantially reduced TRS emissions and odor. Geotextile fabric and a recycled foam cover exhibited the greatest reduction in total hydrocarbon emissions; natural covers were less effective. Because of consistently low emission rates of ammonia, no statistically significant reduction of ammonia emissions were observed from any of the lagoon covers.     

Using a choice experiment and birder preferences to guide bird‐conservation funding

Conservation of biodiversity, including birds, continues to challenge natural‐area managers. Stated‐preference methods (e.g., choice experiment [CE]) are increasingly used to provide data for valuation of natural ecosystems. We used a CE to calculate birders’ willingness to pay for different levels of bioecological attributes (threatened species, endemic species, and diversity) of birding sites with hypothetical entry fees. The CE was delivered at popular birding and avitourism sites in Australia and the United Kingdom. Latent‐class modeling results revealed heterogeneous preferences among birders and correspondingly variable willingness to pay. Four clear groups were apparent: quantity‐driven birders, special‐birds seekers, confused respondents, and price‐is‐no‐object birders. Quantity‐driven birders were attracted to sites that deliver high levels of diversity and endemic species for which they were willing to pay $135 and $66 to visit, respectively, above what they were willing to pay to visit a site with low levels of diversity and few endemic and threatened species . Special‐bird seekers valued threatened species and high levels of endemic species most (willingness to pay $45 and $46, respectively). Confused respondents’ preferences were difficult to determine, but they were the most sensitive to the hypothetical entry fees, unlike the price‐is‐no‐object birders, who were not at all sensitive to cost. Our findings demonstrate that birders are amenable to paying for their preferred birding experience. These payments could provide an alternative source of funding in some avitourism sites on both public and private land. Such alternative revenue streams should be explored and given full consideration in increasingly competitive conservation‐financing environments.     

Modeling the vapor source term associated with the spill of LNG into a sump or impoundment area

The recent publication of evaluation protocols for vapor source term models and vapor dispersion models have influenced the modeling approaches that can be used for approval of new and expansion projects at LNG receiving terminals. In the past few years the scientific basis of integral vapor source term models has been questioned with growing concerns regarding their validity. In this paper, the shallow water equations (SWEs) were solved to study the characteristics of the evaporating LNG pool associated with a constant flow rate spill of LNG into a concrete sump. In the early stages of pool spreading, the leading edge thickness profile of the SWE model scales with the square root of the distance from the leading edge as the pool spreads. After the edge of the pool reaches the wall, the reflected wave forms a hydraulic jump that travels back towards the center of the pool at a speed that is considerably slower than the initial spreading of the pool. Once the hydraulic jump reaches the center, the pool assumes a nearly flat free surface for the rest of the spill. The pool spreading and the rate of evaporation from the SWEs were then compared to the solution provided by the integral model, PHAST. The two approaches were found to agree well with one another. The SWE model was also used to demonstrate the influence of an elevated spill source. With an elevated source, the LNG pool spreads faster, significantly increasing the initial rate of vaporization and peak vaporization rate. This increase in the initial rate of vaporization could lead to an increase in the vapor cloud hazard distance. The SWE model was also used to demonstrate the influence of an inclined sump floor in the shape of an inverted cone where the spilling LNG accumulates in the low vertex of the cone. Inclined sump floors can be used to significantly reduce the cumulative evaporation, making them attractive as a possible mitigation approach in cases where a containment sump is located close to a property boundary.     

Male's return rate, rather than territory fidelity and breeding dispersal, explains geographic variation in song sharing in two populations of an oscine passerine (Oreothlypis celata)

Males of some oscine passerines learn and share songs of neighboring males. This process can lead to the formation of song pattern neighborhoods or microhabitat song dialects. The degree to which song sharing occurs between populations and the spatial scale over which neighboring males share songs, however, can vary widely, and interpopulation comparisons have suggested that song sharing is more common in residents than in migrants. Here, we examine two populations of the orange-crowned warbler (Oreothlypis celata) to quantify patterns of song sharing at the northern (long-distance migrant) and southern (short-distance migrant) edges of the breeding distribution and to test if return rate, territory fidelity, and breeding dispersal explain the patterns found in the two populations. The southern population (O. celata sordida breeding on Santa Catalina Island, California; 33°N) had a higher annual return rate to their territories and exhibited higher song sharing in neighborhoods than their counterparts (O. celata celata breeding in Fairbanks, Alaska; 64°N). Year-to-year patterns of territory fidelity and breeding dispersal distances were similar between populations. Our results suggest that if migratory distance generally covaries with the proportion of returning males, this could explain different levels of song sharing between the short- and long-distance migrants.     

Reducing the Risk of Accidental Death Due to Vehicle-Related Carbon Monoxide Poisoning

ABSTRACT

Emissions of carbon monoxide (CO) from motor vehicles cause several hundred accidental fatal poisonings annually in the United States. The circumstances that could lead to fatal poisonings in residential settings with motor vehicles as the source of CO were explored. The risk of death in a garage (volume = 90 m³) and a single-family dwelling (400 m³) was evaluated using a Monte Carlo simulation with varying CO emission rates and ventilation rates. Information on emission rates was obtained from a survey of motor vehicle exhaust gas composition under warm idle conditions in California, and information on ventilation rates was obtained from a summary of published measurements in the U.S. housing stock. The risk of death ranged from 16 to 21% for a 3-hr exposure in a garage to 0% for a 1-hr exposure in a house. Older vehicles were associated with a disproportionately high risk of death. Removing all pre-1975 vehicles from the fleet would reduce the risk of death by one-fourth to two-thirds, depending on the exposure scenario. Significant efforts have been made to control CO emissions from motor vehicles with the goal of reducing CO concentrations in outdoor air. Substantial public health benefit could also be obtained if vehicle control measures were designed to take account of acute CO poisonings explicitly.     

Crassostrea virginica as an indicator of lead pollution

After treatment with 1.0 and 3.3 g Pb kg^-1 for 20 weeks in flowing seawater at ambient salinity and temperature, Crassostrea virginica accumulated as much as 6.57 and 11.42 g g^-1 dry weight, respectively, and no mortalities were recorded. Lead uptake was curvilinear; however, the general trend was an increase in lead concentration over time. Dry weight of the oyster had no significant relation with tissue lead concentration (g g^-1); however, a significant positive relationship existed between weight and lead content (g). A decrease in lead concentration in the tissues occurred from mid-August to mid-September despite continuous addition of lead to the seawater. Addition of lead to the seawater was terminated after 20 weeks (October), and lead loss was studied for the following 12 weeks. Lead loss was studied well after spawning in an attempt to eliminate any influence this might have on lead concentration in the tissues. After 4 weeks, approximately 54% of the accumulated lead was lost under conditions of a natural temperature decline. The biological half-life of lead in C. virginica tissues was calculated to be 5.5 weeks. In the ensuing 8 weeks, little or no lead loss was observed. Larvae from each treatment developed to the straight-hinged stage within 48 h with no apparent abnormalities. Lead appeared to have no adverse effect on larvae when parents had been treated with 1.0 and 3.3 g kg^-1 seawater for 10 weeks.     

Monitoring the dispersal of contaminants by wildlife at nuclear weapons production and waste storage facilities

Professor of wildlife biology in the department of biological sciences, California State University. Dr K. Shawn Smallwood is a systems ecologist and may be contacted at 109 Luz Place, Davis, CA 95616, USA. Dr Jan Beyea is a physical scientist with Consulting in the Public Interest, 53 Clinton Street, Lambertville, NJ 08530, USA. The US Government produced and acquired approximately 111 t of plutonium in support of its nuclear weapons programme. Verified reports of the loss of nuclear material into the environment, including loss by animals, has raised questions regarding the monitoring programmes in place on the nuclear facilities. Given these concerns regarding the fate of stored nuclear waste, the authors conducted a review of the wildlife monitoring programme used at nuclear weapons and storage facilities by (1) reviewing the key facets of the monitoring used at the facilities, (2) evaluating published and unpublished data from the facilities and (3) incorporating data from personal site visits. The study concentrated on the Department of Energy's Hanford Reservation in rural south–central Washington and the Rocky Flats Plant in central Colorado. Based on the review, it is concluded that an improved and rigorous environmental surveillance and monitoring programme is needed at both locations. The site surveys identified frequent instances of intrusion into burial sites by animals, most of which had gone unreported by Hanford and Rocky Flats personnel. It was apparent that a significant source of potential contamination was not being adequately monitored at the nuclear waste sites. It is recommended that the development of a systematic, well-planned programme of monitoring animal intrusion on burial sites be considered, coupled with improved training for responsible personnel.     

Adsorption of uranium(VI) on amorphous ferric oxyhydroxide at high concentrations of dissolved carbon(IV) and sulfur(VI)

Amorphous ferric oxyhydroxide is being used to treat groundwater contaminated with uranium(VI); the compound also has potential for use as a component in in situ chemical barriers. To quantitatively evaluate its effectiveness in such applications, adsorption of uranium(VI) onto amorphous ferric oxyhydroxide was experimentally investigated under a wide range of uranium(VI) (8.40·10⁻⁷−2.10·10⁻³ mol L⁻¹; 0.2–500 mg L⁻¹), sulfur(VI) (0–0.07 mol L⁻¹; 0–2240 mg L⁻¹) and carbon(IV) (0–0.0195 mol L⁻¹; 0–234 mg L⁻¹) concentrations, and pH-values (4–9.6). The adsorption behavior of uranium(VI) (uranyl ion and its complexes) is similar to that of other cations; it exhibits a sharp rise in the extent of adsorption with increasing pH. Interactions among uranyl complexes and surface sites are interpreted using a site complexation model. Although the model does not incorporate electrostatics and includes only a single type of adsorption site, it provides a reasonable match to measured adsorption and proton exchange data. The simplicity of the model and the resulting reduction in computational demand allow its efficient incorporation into coupled reaction-transport models.