岷江生态环境问题及其对策研究

本文主要探讨岷江流域的生态环境问题及其对策。全文分为两个部分。(1)研究岷江生态环境问题;(2)解决岷江生态环境问题的主要对策。     

张掖市城区采暖期环境空气中污染物分布特征分析

以张掖市甘州区城区采暖期2008—2012年5年环境空气质量数据为主,对采暖期污染物变化状况及污染物分布情况进行分析。张掖市冬季采暖主要以燃煤为主,能源结构不合理、锅炉污染严重、工业企业结构不合理以及交通污染等原因,使得冬季采暖期间张掖市甘州区城区环境空气中主要污染物为二氧化硫、可吸入颗粒物、二氧化氮,采暖期间污染物浓度随时问呈正态分布特征。结合污染特点,提出调整能源结构、利用清洁能源、加大监管力度等建议,以期改善张掖市采暖期的环境空气质量。     

钻井环境污染源头控制技术综述

通过对国内外石油行业的钻井环境污染源头控制技术的简单综述,分析了钻井工艺可采用小孔径钻井、连续软管工艺、新型固控设施等的技术特点,对选择合适的钻井液以及应用环保型钻井液来减轻污染方面进行了探讨。并展望了我国石油行业钻井环境污染源头控制技术的发展。     

Current Status and Problems in Certification of Sustainable Forest Management in China

Forest certification is a mechanism involving the regulation of trade of forest products in order to protect forest resources and improve forest management. Although China had a late start in adopting this process, the country has made good progress in recent years. As of July 31, 2009, 17 forest management enterprises and more than one million hectares of forests in China have been certified by the Forest Stewardship Council (FSC). Several major factors affect forest certification in China. The first set is institutional in nature. Forest management in China is based on centralized national plans and therefore lacks flexibility. A second factor is public awareness. The importance and value of forest certification are not widely understood and thus consumers do not make informed choices regarding certified forest products. The third major factor is the cost of certification. Together these factors have constrained the development of China’s forest certification efforts. However, the process does have great potential. According to preliminary calculations, if 50% of China’s commercial forests were certified, the economic cost of forest certification would range from US$0.66–86.63 million while the economic benefits for the forestry business sector could exceed US$0.66–86.63 million while the economic benefits for the forestry business sector could exceed US150 million. With continuing progress in forest management practices and the development of international trade in forest products, it becomes important to improve the forest certification process in China. This can be achieved by improving the forest management system, constructing and perfecting market access mechanisms for certificated forest products, and increasing public awareness of environmental protection, forest certification, and their interrelationship.     

散射光下铁(Ⅲ)-丙酮酸盐配合物还原铬(Ⅵ)的研究

研究了在散射光下铁（Ⅲ）-丙酮酸盐配合物对铬（Ⅵ）的光还原反应;考察了溶液pH、铁（Ⅲ）、丙酮酸钠、铬（Ⅵ）浓度对反应的影响;分析了铬（Ⅵ）光还原反应的动力学。实验结果表明：铁（Ⅲ）-丙酮酸盐配合物体系能在较弱的散射光下还原铬（Ⅵ）。在铬（Ⅵ）浓度为19．2μmol／L、铁（Ⅲ）浓度为10．0μmol／L、丙酮酸钠浓度为240μmol／L、pH为3．0、光照240min的条件下,铬（Ⅵ）的还原率达到99．7％。从表观动力学方程的反应级数看,铁（Ⅲ）的级数（0．83）最高,铁（Ⅲ）浓度是影响铬（Ⅵ）光还原反廊速率的主要因素．铁（Ⅱ）是铬（Ⅵ）光还原的主要还原剂。     

煤层底板采动导水破坏深度计算的神经网络方法

在综合分析影响煤层底板采动导水破坏深度因素的基础上,应用人工神经网络方法,建立了底板破坏深度的计算模型.该模型利用现场观测资料作为学习训练样本和测试样本,对模型的测算结果、理论计算值和实测值进行了对比分析.结果表明:用神经网络方法计算底板破坏深度考虑的因素更加全面,结果更接近于实际.笔者研究的计算模型和测算方法,为承压水上安全采煤决策提供了科学依据.     

TiO2气溶胶快速去除空气中的芥子气模拟剂

在自制反应器内,通过喷射法将纳米TiO_2分散成气溶胶形式,用以降解空气中的芥子气模拟剂二乙基硫醚(DES)。利用自行设计的一套气溶胶沉降行为评价装置,对TiO_2气溶胶的释放条件进行了优化。系统研究了相对湿度、反应温度、光强、催化剂加入量、反应物浓度等因素对DES降解速率和彻底矿化速率的影响。结果表明:TiO_2气溶胶对2.80 mg/L(近似芥子气快速致死浓度)DES降解的半衰期由涂覆型TiO_2的34.5 min缩短至8.5 min;TiO_2气溶胶光催化降解DES的最佳相对湿度为35%,此时CO_2最快生成速率可达34.64μg/(L·min),150 min内彻底矿化比例达66.1%;对于1.5 L反应器,催化剂加入量为30 mg时降解DES的量效比达到最佳状态;TiO_2气溶胶光催化适用于含低浓度DES空气的快速净化。     

Thermogravimetric analysis and kinetic study on pyrolysis of representative medical waste composition

To obtain detailed information on the pyrolysis characteristics, a thermogravimetric study on the pyrolysis of 14 typical medical waste compositions was carried out in thermogravimetric analysis (TGA) equipment using dynamic techniques in a stream of N(2). An index representing pyrolysis reactivity of waste was presented. Kinetic parameters were obtained by Coats-Redfern method and used to model the TG curve. The results showed that: (a) Plastic, protein, cellulosic material, synthetic fibre, and rubber entered pyrolysis process in succession. (b) There was one decomposition stage in the pyrolysis of one-off medical glove, operating glove, cellulosic waste, absorbable catgut suture and adhesive plaster, while other components had two obvious weight loss stages. (c) The obtained apparent activation energy for second stage pyrolysis was comparably higher than that for first stage. (d) Each stage was controlled by only one kinetic mechanism, in which kinetic parameters were constant. (e) The degradation kinetics of medical waste may be affected by special physical and chemical treatment in the product manufacturing process. (f) Among 13 waste samples, the pyrolysis index of cellulosic matter was the highest, which indicated cellulosic matter had strong pyrolysis reactivity. (g) With increasing heating rate, TG curve and DTG peak shifted to high temperatures and main reaction interval of the sample became longer.