Carbonization of waste PVC to develop porous carbon material without further activation

Efficient removal of chlorine from PVC achieved by two-stage heat-treatment (280 and 410 degrees C) provided chlorine-free isotropic pitch containing additive. The pitch was stabilized and carbonized into porous carbons with surface areas of approximately 300 m2/g. Resultant porous carbons showed three pore structures of supermicropore, micropore and mesopore. The generation of CO2 from the decomposition of the CaCO3 additive in waste PVC is responsible for the development of porous structures. The surface area of the carbonized product increased after the removal of CaO.     

The Interactive Effects of Fire and Diversity on Short-Term Responses of Ecosystem Processes in Experimental Mediterranean Grasslands

We conducted a field experiment using constructed communities to test whether species richness contributed to the maintenance of ecosystem processes under fire disturbance. We studied the effects of diversity components (i.e., species richness and species composition) upon productivity, structural traits of vegetation, decomposition rates, and soil nutrients between burnt and unburnt experimental Mediterranean grassland communities. Our results demonstrated that fire and species richness had interactive effects on aboveground biomass production and canopy structure components. Fire increased biomass production of the highest-richness communities. The effects of fire on aboveground biomass production at different levels of species richness were derived from changes in both vertical and horizontal canopy structure of the communities. The most species-rich communities appeared to be more resistant to fire in relation to species-poor ones, due to both compositional and richness effects. Interactive effects of fire and species richness were not important for belowground processes. Decomposition rates increased with species richness, related in part to increased levels of canopy structure traits. Fire increased soil nutrients and long-term decomposition rate. Our results provide evidence that composition within richness levels had often larger effects on the stability of aboveground ecosystem processes in the face of fire disturbance than species richness per se.     

Temporal and spatial distributions of sediment total organic carbon in an estuary river

Understanding temporal and spatial distributions of naturally occurring total organic carbon (TOC) in sediments is critical because TOC is an important feature of surface water quality. This study investigated temporal and spatial distributions of sediment TOC and its relationships to sediment contaminants in the Cedar and Ortega Rivers, Florida, USA, using three-dimensional kriging analysis and field measurement. Analysis of field data showed that large temporal changes in sediment TOC concentrations occurred in the rivers, which reflected changes in the characteristics and magnitude of inputs into the rivers during approximately the last 100 yr. The average concentration of TOC in sediments from the Cedar and Ortega Rivers was 12.7% with a maximum of 22.6% and a minimum of 2.3%. In general, more TOC accumulated at the upper 1.0 m of the sediment in the southern part of the Ortega River although the TOC sedimentation varied with locations and depths. In contrast, high concentrations of sediment contaminants, that is, total polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), were found in sediments from the Cedar River. There was no correlation between TOC and PAHs or PCBs in these river sediments. This finding is in contradiction to some other studies which reported that the sorption of hydrocarbons is highly related to the organic matter content of sediments. This discrepancy occurred because of the differences in TOC and hydrocarbon source input locations. It was found that more TOC loaded into the southern part of the Ortega River, while almost all of the hydrocarbons entered into the Cedar River. This study suggested that the locations of their input sources as well as the land use patterns should also be considered when relating hydrocarbons to sediment TOC.     

Carbon emission reduction and cost–benefit of methane digester systems on hog farms in China

Three different sizes of hog farms were selected to analyze the carbon emissions reduction and the cost–benefit of three methane digester systems. The sizes of the digesters are 2,200, 2,200 and 800 m³, respectively. The sales of slaughter hogs from them are 50,000, 35,000 and 10,000 head, respectively. The carbon emissions reductions were 5,237, 4,017, and 1,334 tons, respectively. The results show that while the methane digester systems have a significant effect on carbon emissions reduction, it is difficult to operate the systems sustainably. If the carbon emissions reduction can be traded at high enough prices in the carbon offset markets, then the systems will be profitable and sustainable. Newly established China's domestic carbon offset market could provide this possibility, but more government support is needed. In addition, this study shows that scale economies make the digester adoption relatively more profitable for larger farms than smaller ones.     

Impacts of Changes in Precipitation Amount and Distribution on Water Resources Studied Using a Model Rainwater Harvesting System

Water supply reliability is expected to be affected by both precipitation amount and distribution changes under recent and future climate change. We compare historical (1951‐2010) changes in annual‐mean and annual‐maximum daily precipitation in the global set of station observations from Global Historical Climatology Network and climate models from the Inter‐Sectoral Impact Model Intercomparison Project (ISI‐MIP), and develop the study to 2011‐2099 for model projections under high radiative forcing scenario (RCP8.5). We develop a simple rainwater harvesting system (RWHS) model and drive it with observational and modeled precipitation. We study the changes in mean and maximum precipitation along with changes in the reliability of the model RWHS as tools to assess the impact of changes in precipitation amount and distribution on reliability of precipitation‐fed water supplies. Results show faster increase in observed maximum precipitation (10.14% per K global warming) than mean precipitation (7.64% per K), and increased reliability of the model RWHS driven by observed precipitation by an average of 0.2% per decade. The ISI‐MIP models show even faster increase in maximum precipitation compared to mean precipitation. However, they imply decreases in mean reliability, for an average 0.15% per decade. Compared to observations, climate models underestimate the increasing trends in mean and maximum precipitation and show the opposite direction of change in reliability of a model water supply system.     

A numerical study on the effects of EGR and spark timing to combustion characteristics and NOx emission of a GDI engine

EGR is one of the most significant strategies for reducing especially nitrogen oxides (NO_x) emissions from internal combustion engines. The thermal efficiency of spark ignition engines is lower than compression ignition engines because of its lower compression ratio. If the compression ratio is increased to obtain higher thermal efficiency, there may be a knocking tendency in spark ignition engines. EGR can be used in order to reduce NO_x emissions and avoid knocking phenomena at higher compression ratios. In-cylinder temperature at the end of combustion is decreased and heat capacity of fresh charge is increased when EGR applied. Besides EGR, spark timing is another significant parameter for reducing exhaust emissions such as nitrogen oxides, and unburned hydrocarbon (UHC). In this study the effects of EGR and spark timing on spark ignition engine were investigated numerically. KIVA codes were used in order to model combustion process. The combustion process has been modeled for a single cylinder, four stroke and gasoline direct injection (GDI) spark ignition engine. The results showed that in-cylinder pressure and heat release rate decrease as EGR ratio increase. In-cylinder pressure increases with the advancing of spark timing. Advancing spark timing increases the heat release rate and in-cylinder temperature. The simulation results also showed that EGR reduced exhaust gas temperature and NO_x emissions.     

Upgrading food wastes by means of bromelain and papain to enhance growth and immunity of grass carp (<Emphasis Type="Italic">Ctenopharyngodon idella</Emphasis>)

The fast growing of global aquaculture industry accompanied with increasing pressure on the supply and price of traditional feed materials (e.g., fish meal and soy bean meal). This circumstance has urged the need to search alternative sources of feed stuff. Food waste was used as feed stuff in rearing fish which possess substantial protein and lipid. Grass carp are major species reared in Hong Kong with lower nutritional requirements; it is also an ideal species for investigating the feasibility of using food waste as fish feeds for local aquaculture industry. The growth and immunity, reflected by total protein, total immunologlobulin (IgI), and nitroblue tetrazolium (NBT) activity of grass carp blood, were depressed when feeding with food waste feeds without enzymes. However, the supplementation of bromelain and papain in fish feed enhanced the efficient use of food waste by grass carp, which in turn improved the fish immunity. The present results indicated that the addition of those enzymes could enhance the feed utilization by fish and hematological parameters of grass carp, and the improvement on growth and immunity superior to the control (commercial feed) was observed with the addition of bromelain and papain supplement. Addition of 1 and 2 % mixture of bromelain and papain could significantly enhance the lipid utilization in grass carp.     

Accumulation of Cd,Cu and Zn in shoots of maize (<Emphasis Type="Italic">Zea mays</Emphasis> L.) exposed to 0.8 or 20 nM Cd during vegetative growth and the relation with xylem sap composition

This work focuses on the exposure of maize plants to nanomolar concentrations of Cd, which is relevant for agricultural soils cropped with food and feed plants. Maize plants were cultivated in nutrient solution at 0.8 or 20 nM Cd during the vegetative growth stages. No significant hormesis or toxic effects of Cd were observed on maize growth, but a decrease in the allocation of Cd to shoots between the 0.8 and 20 nM Cd exposures revealed that the plants already responded to these low concentrations of Cd according to a shoot Cd excluder strategy. The Cd, Cu and Zn concentrations in shoots decreased with time as the result of an early decrease in the root/shoot ratio and of a decrease in the coefficient of allocation to aboveground for Zn and Cd at 20 nM. As a consequence, shoots of young plants were richer in micronutrients Cu and Zn but also in toxic Cd. The rate of delivery of Cd, Cu and Zn from xylem sap was successfully used to predict the time course of concentrations of Cd, Cu and Zn in the shoot. However, it overestimated the actual concentrations of Cd in the shoot, presumably because the reallocation of this trace element from shoots back to roots was not taken into account.