Selenium removal and mass balance in a constructed flow-through wetland system

A field study on the removal of Se from agricultural subsurface drainage was conducted from May 1997 to February 2001 in the Tulare Lake Drainage District (TLDD) of San Joaquin Valley, California. A flow-through wetland system was constructed consisting of ten 15- x 76-m unlined cells that were continuously flooded and planted with either a monotype or combination of plants, including sturdy bulrush [Schoenoplectus robustus (Pursh) M.T. Strong], baltic rush (Juncus balticus Willd.), smooth cordgrass (Spartina alterniflora Loisel.), rabbitsfoot grass [Polypogon monspeliensis (L.) Desf.], salt-grass lDistichlis spicata (L.) Greene], cattail (Typha latifolia L.), tule [Schoenoplectus acutus (Muhl. ex Bigelow) A. L?ve & D. L?ve], and widgeon grass (Ruppia maritima L.). One cell had no vegetation planted. The objectives of this research were to evaluate Se removal efficiency of each wetland cell and to carry out a mass balance on Se. The inflow drainage water to the cells had average annual Se concentrations of 19 to 22 microg L(-1) dominated by selenate [Se(VI), 95%]. Average weekly water residence time varied from about 3 to 15 d for Cells 1 through 7 (target 7 d), 19 to 33 d for Cells 8 and 9 (target 21 d), and 13 to 18 d for Cell 10 (target 14 d). Average weekly Se concentration ratios of outflow to inflow ranged from 0.45 to 0.79 and mass ratio (concentration x water volume) from 0.24 to 0.52 for year 2000, that is, 21 to 55% reduction in Se concentration and 48 to 76% Se removal in mass by the wetland, respectively. The nonvegetated cell showed the least Se removal both in concentration and in mass. The global mass balance showed that on the average about 59% of the total inflow Se was retained within the cells and Se outputs were outflow (35%), seepage (4%), and volatilization (2%). Independent measurements of the Se retained in the cells totaled 53% of the total Se inflow: 33% in the surface (0-20 cm) sediment, 18% in the organic detrital layer above the sediment, 2% in the fallen litter, < 1% in the standing plants, and < 1% in the surface water. Thus, about 6% of the total Se inflow was unaccounted for in the internal compartments.     

Weathering of lead bullets and their environmental effects at outdoor shooting ranges

Lead contamination at shooting range soils is of great environmental concern. This study focused on weathering of lead bullets and its effect on the environment at five outdoor shooting ranges in Florida, USA. Soil, plant, and water samples were collected from the ranges and analyzed for total Pb and/or toxicity characteristic leaching procedure (TCLP) Pb. Selected bullet and berm soil samples were mineralogically analyzed with X-ray diffraction and scanning electron microscopy. Hydrocerussite [Pb3(CO3)2(OH)2] was found in both the weathered crusts and berm soils in the shooting ranges with alkaline soil pH. For those shooting ranges with acidic soil pH, hydrocerussite, cerussite (PbCO3), and small amount of massicot (PbO) were predominantly present in the weathered crusts, but no lead carbonate mineral was found in the soils. However, hydroxypyromorphite [(Pb10(PO4)6(OH)2] was formed in a P-rich acidic soil, indicating that hydroxypyromorphite can be a stable mineral in P-rich shooting range soil. Total Pb and TCLP Pb in the soils from all five shooting ranges were significantly elevated with the highest total Pb concentration of 1.27 to 4.84% (w/w) in berm soils. Lead concentrations in most sampled soils exceeded the USEPA's critical level of 400 mg Pb kg(-1) soil. Lead was not detected in subsurface soils in most ranges except for one, where elevated Pb up to 522 mg kg(-1) was observed in the subsurface, possibly due to enhanced solubilization of organic Pb complexes at alkaline soil pH. Elevated total Pb concentrations in bermudagrass [Cynodon dactylon (L.) Pers.] (up to 806 mg kg(-1) in the aboveground parts) and in surface water (up to 289 microg L(-1)) were observed in some ranges. Ranges with high P content or high cation exchange capacity showed lower Pb mobility. Our research clearly demonstrates the importance of properly managing shooting ranges to minimize adverse effects of Pb on the environment.     

Tobacco clones derived from tissue culture with supersensitivity to ozone

At least two supersensitive tobacco somaclones were obtained from tissue culture (TC) , when this approach was used to asexually propagate Bel-W3 tobacco indicator plants. These somaclones can detect as low as 30 ppb ozone for a 4-h exposure duration both within CSTR exposure chambers and in ambient air. Comparison of the injury index and their coefficient of variance showed that the TC plantlets usually have more uniform performance in response to ozone in addition to their higher sensitivity. A quick regeneration procedure was established to preserve the supersensitive germplasm immediately when it was found. The TC plantlets will flower and produce seed similar to seed-grown tobacco. The TC approach proved to be a better propagation system for valuable indicator plant species. The mechanism that causes the variation and the possible difference in their genome from seed-grown tobacco is still unknown. Further studies are needed in the future to determine if factors in the TC system may be responsible for the sensitivity difference.     

Sorption of volatile organic compounds on typical carpet fibers

Measurements of adsorption isotherms for three volatile organic compounds (VOCs) (toluene, 1,2-dichlorobenzene and 1,1,1-trichloroethane) on polyacrylonitrile carpet fibers over the temperature range 25-45 degrees C were carried out in a thermogravimetric analyzer (TGA). Linear isotherms were observed in all cases with values of the Henry coefficient ranging from 0.063 to 0.941 mm. The results of additional experiments carried out in a simple test chamber containing a single source of VOC showed that the carpet fibers acted as a significant sink causing a prolonged elevation of VOC concentration in the air within the chamber. An unsteady-state model is presented, which adequately described the adsorption and desorption phenomena occurring in the test chamber and yielded realistic values of the adsorption and desorption rate constants. There was good agreement between the equilibrium and kinetic constants obtained in the TGA and test chamber experiments.     

FIELD MEASUREMENT OF FLOW VELOCITIES,SUSPENDED SOLIDS CONCENTRATIONS,AND TEMPERATURES IN LAKE OKEECHOBEE1

ABSTRACT: This paper presents a field investigation of collecting hydrodynamic and sediment data in Lake Okeechobee with analyses examining mechanisms affecting sediment resuspension in the lake. Lake Okeechobee is a large subtropical lake located in south central Florida. Three‐dimensional flow velocities, suspended solids concentrations (SSC), and temperatures at four locations were measured from January 18 to March 5, 2000. Analyses of these data indicate that wind is the dominant factor in driving flow velocities and therefore transporting suspended solids. Wind direction also affects the SSC, especially in the north central and west littoral areas of the lake. The surface and bottom velocity components frequently flow in opposite directions, forming a stratification of the water column and preventing suspended solids from settling out. This retention of SSC in the water column may have a strong impact on the water quality of Lake Okeechobee. This study provides valuable storm event data and mechanism analyses, which will improve our understanding of the transport of suspended solids, thermal exchanges, and flow patterns within Lake Okeechobee.     

INTEGRATION OF GEOGRAPHIC INFORMATION SYSTEMS AND A COMPUTER MODEL TO EVALUATE IMPACTS OF AGRICULTURAL RUNOFF ON WATER QUALITY1

ABSTRACT: This study integrates an Agricultural Non-Point Source Pollution Model (AGNPS), the Geographic Resource Analysis Support System (GRASS) (U.S. Army Corps of Engineers, 1987), and GRASS WATERWORKS (a hydrologic modeling tool box being developed at the Michigan State University Center for Remote Sensing) to evaluate the impact of agricultural runoff on water quality in the Cass River, a subwatershed of Saginaw Bay. AGNPS is used to estimate the amounts, origin, and distribution of sediment, nitrogen (N), and phosphorus (P) in the watershed. GRASS and GRASS WATERWORKS are used to generate parameters needed for AGNPS from digital maps, which include soil association, land use, watershed boundaries, water features, and digital elevation. Outputs of the model include spatially distributed estimates of volume and peak runoff, overland and channel erosion, sediment yields, and concentrations of nitrogen and phosphorus. Management scenarios are explored in the AGNPS model to minimize sedimentation and nutrient loading. Scenarios evaluated include variations in crop cover, tillage methods, and other agricultural management practices. In addition, areas vulnerable to erosion are identified for best management practices.     

Infrared spectroscopy studies of the photooxidation of a polyethylene nonwoven fabric

The photooxidation of a nonwoven polyethylene fabric was investigated using Fourier transform infrared photoacoustic spectroscopy. The infrared spectroscopic data indicated that hydroperoxide, alcohol, aldehyde, ketone, carboxylic acid, and anhydride groups were formed as the products of the photooxidation of the polyethylene fabric and that the relative amount of carboxyl among all carbonyls increased as the photooxidation progressed. The distribution of the photooxidation products was inhomogeneous between the two surfaces of the fabric. The highest degree of photooxidation occurred on the surface of the fabric facing the UV radiation source, whereas the lowest degree of photooxidation was on the back surface of the fabric. We also found that the polyethylene nonwoven fabric showed a slower photooxidation rate than the polypropylene nonwoven fabric. The UV radiation at 254 nm caused photooxidation of polyethylene. No photooxidation was observed in the fabric exposed to the UV radiation at 350 nm under the same conditions.     

A COMPARATIVE ANALYSIS OF TECHNIQUES FOR SPATIAL INTERPOLATION OF PRECIPITATION1

One of the problems which often arises in engineering hydrology is to estimate data at a given site because either the data are missing or the site is ungaged. Such estimates can be made by spatial interpolation of data available at other sites. A number of spatial interpolation techniques are available today with varying degrees of complexity. It is the intent of this paper to compare the applicability of various proposed interpolation techniques for estimating annual precipitation at selected sites. The interpolation techniques analyzed include the commonly used Thiessen polygon, the classical polynomial interpolation by least-squares or Lagrange approach, the inverse distance technique, the multiquadric interpolation, the optimal interpolation and the Kriging technique. Thirty years of annual precipitation data at 29 stations located in the Region II of the North Central continental United States have been used for this study. The comparison is based on the error of estimates obtained at five selected sites. Results indicate that the Kriging and optimal interpolation techniques are superior to the other techniques. However, the multiquadric technique is almost as good as those two. The inverse distance interpolation and the Thiessen polygon gave fairly satisfactory results while the polynomial interpolation did not produce good results.     

APPROACHES TO MULTIVARIATE MODELING OF WATER RESOURCES TIME SERIES1

ABSTRACT: Alternative approaches suggested for modeling multiseries of water resources systems are reviewed and compared. Most approaches fall within the general framework of multivariate ARMA models. Formal modeling procedures suggest a three-stage iterative process, namely: model identification, parameter estimation and diagnostic checks. Although a number of statistical tools are already available to follow such modeling process, in general, it is not an easy task, especially if high order vector ARMA models are used. However, simpler ARMA models such as the contemporaneous and the transfer-function models may be sufficient for most applications in water resources. Two examples of modeling bivariate and trivariate streamflow series are included. Alternative modeling procedures are used and compared by using data generation techniques. The results obtained suggest that low order models, as well as contemporaneous ARMA models, reproduce quite well the main statistical characteristics of the time series analyzed. It is assumed that the same conclusions apply for most water resources time series.     

EVALUATION OF NEXRAD STAGE III PRECIPITATION DATA OVER A SEMIARID REGION1

This study examines NEXRAD Stage III product (hourly, cell size 4 km by 4 km) for its ability in estimating precipitation in central New Mexico, a semiarid area. A comparison between Stage III and a network of gauge precipitation estimates during 1995 to 2001 indicates that Stage III (1) overestimates the hourly conditional mean (CM) precipitation by 33 percent in the monsoon season and 55 percent in the nonmonsoon season; (2) overestimates the hourly CM precipitation for concurrent radar‐gauge pairs (nonzero value) by 13 percent in the monsoon season and 6 percent in the nonmonsoon season; (3) overestimates the seasonal precipitation accumulation by 11 to 88 percent in monsoon season and underestimates by 18 to 89 percent in the nonmonsoon season; and (4) either overestimates annual precipitation accumulation up to 28.2 percent or underestimates it up to 11.9 percent. A truncation of 57 to 72 percent of the total rainfall hours is observed in the Stage III data in the nonmonsoon season, which may be the main cause for both the underestimation of the radar rainfall accumulation and the lower conditional probability of radar rainfall detection in the nonmonsoon season. The study results indicate that the truncation caused loss of small rainfall amounts (events) is not effectively corrected by the real‐time rain gauge calibration that can adjust the rainfall rates but cannot recover the truncated small rainfall events. However, the truncation error in the monsoon season may be suppressed due to the larger rainfall rate and/or combined effect of overestimates by bright band and hail contaminations, virga, advection, etc. In general, improvement in NEXRAD performance since the monsoon season in 1998 is observed, which is consistent with the systematic improvement in the NEXRAD network.