Application of in situ biosparging to remediate a petroleum-hydrocarbon spill site: field and microbial evaluation

In this study, a full-scale biosparging investigation was conducted at a petroleum-hydrocarbon spill site. Field results reveal that natural attenuation was the main cause of the decrease in major contaminants [benzene, toluene, ethylbenzene, and xylenes (BTEX)] concentrations in groundwater before the operation of biosparging system. Evidence of the occurrence of natural attenuation within the BTEX plume includes: (1) decrease of DO, nitrate, sulfate, and redox potential, (2) production of dissolved ferrous iron, sulfide, methane, and CO(2), (3) decreased BTEX concentrations along the transport path, (4) increased microbial populations, and (5) limited spreading of the BTEX plume. Field results also reveal that the operation of biosparging caused the shifting of anaerobic conditions inside the plume to aerobic conditions. This variation can be confirmed by the following field observations inside the plume due to the biosparging process: (1) increase in DO, redox potential, nitrate, and sulfate, (2) decrease dissolved ferrous iron, sulfide, and methane, (3) increased total cultivable heterotrophs, and (4) decreased total cultivable anaerobes as well as methanogens. Results of polymerase chain reaction, denaturing gradient gel electrophoresis, and nucleotide sequence analysis reveal that three BTEX biodegraders (Candidauts magnetobacterium, Flavobacteriales bacterium, and Bacteroidetes bacterium) might exist at this site. Results show that more than 70% of BTEX has been removed through the biosparging system within a 10-month remedial period at an averaged groundwater temperature of 18 degrees C. This indicates that biosparging is a promising technology to remediate BTEX contaminated groundwater.     

Application of Klebsiella oxytoca immobilized cells on the treatment of cyanide wastewater

Klebsiella oxytoca, isolated from cyanide-containing industrial wastewater, has been shown to be able to biodegrade cyanide to non-toxic end products. The technology of immobilized cells can be applied in biological treatment to enhance the efficiency and effectiveness of biodegradation. In this study, potassium cyanide was used as the target compound and both alginate and cellulose triacetate techniques were applied for the preparation of immobilized cells. Results from this study show that KCN can be utilized as the sole nitrogen source by K. oxytoca. The free suspension systems reveal that the cell viability was highly affected by initial KCN concentration and pH. Results show that immobilized cell systems could tolerate a higher level of KCN concentration and wider ranges of pH. In the batch experiments, the maximum KCN removal efficiencies using alginate and cellulose triacetate immobilized beads were 0.108 and 0.101mM h(-1) at pH 7, respectively. Results also indicate that immobilized system can support a higher biomass concentration. Complete KCN degradation was observed after the operation of four consecutive degradation experiments with the same batch of immobilized cells. This suggests that the activity of immobilized cells can be maintained and KCN can be used as the nitrogen source throughout KCN degradation experiments. The maximum KCN removal rates using alginate and cellulose triacetate immobilized beads in continuous-column system were 0.224 and 0.192mMh(-1) with initial KCN concentration of 3mM, respectively. Results indicate that the immobilized cells of K. oxytoca would be applicable to the treatment of cyanide-containing wastewaters.     

Assessment model for equipment risk management: Petrochemical industry cases

This study presents an assessment model that examines quantity and quality factors for equipment risk management in the petrochemical industry. The proposed model has five dimensions—financial performance, logistical support, service level, learning and innovation, and risk control. This evaluation model uses 13 strategy subjects and 78 performance-measurement indicators. Performance assessment indicators are initially established and revised based on expert opinions collected via a questionnaire. Further, the analytical network process (ANP) is utilized to calculate the weights of indicators in each layer and to construct assessment models with applicable and valuable references. To determine model practicability, this study assesses four subsidiaries of the case company. Each subsidiary has a capitalization exceeding TWD 50 billion. In addition to evaluating company performance in terms of each dimension and indicator, the proposed model provides a valuable reference for decision-making in equipment risk management.     

Performance assessment for municipal solid waste collection in Taiwan

Collecting municipal solid waste (MSW) is a major and expensive task for local waste management authorities, thus efficient MSW collection is a necessity. This study presents a procedure for developing an aggregate indicator (AI) to assess MSW collection efficiency based on multiple factors. The applicabilities of various key performance indicators (KPIs) are evaluated based on five selection criteria, and five KPIs are chosen to form the AI. The relative efficiencies of local MSW collection services are analyzed by the data envelopment analysis (DEA) method. A set of common weights for all five KPIs is then generated based on DEA results and four selection rules by modifying a previous approach. Finally, the proposed AI is applied to assess the MSW collection services provided by 307 local governments in Taiwan, and associated results are compared and discussed.     

AN ECONOMIC EVALUATION OF TWO WATERSHED MANAGEMENT PRACTICES IN TAIWAN1

ABSTRACT: The main purpose of this study is to evaluate the management practice effects on Ming-Hu and Ming-Tan reservoir watersheds during the past 15 years. It is difficult to economically evaluate a watershed project consisting of a number of multisectoral and long term management practices and regulations. However, the reservoirs’ hydropower operations and their associated benefits and costs are highlighted in this study. The estimated management practice value (net present value) of 351 million NT (New Taiwan) dollars and a benefit-cost ratio of 1.189 are obtained for the Ming-Hu subwatershed. Because the Ming-Tan hydropower station only began commercial operation in 1992 the estimated management practice value is negative 103 million NT dollars (net present value) and the benefit-cost ratio is 0.653 in the Ming-Tan subwatershed. If the analysis period is contained to the year 2010, the benefit-cost ratio of Ming-Tan reservoir subwatershed becomes 1.103. Ming-Hu and Ming-Tan subwatersheds together share the benefit-cost ratio of 1.182 and the net present value of 1,589 million NT dollars. The results of the analyses indicate that the Taiwan Power Company, the watershed management agency, has implemented economically efficient watershed practices and regulations in Ming-Hu and Ming-Tan reservoir watersheds and the watershed management practices are worthwhile and should be sustained.     

Free tropospheric ozone production after deep convection of dispersing tropical urban plumes

Ozone generation is computed in a one-dimensional photochemistry code following convective redistribution of tropical urban effluent into the free troposphere. Simulations are run at several stages of pollutant dilution by surrounding surface air. A threshold boundary layer NO_x concentration of 300 pptv is established for significant production enhancements at upper levels. Areas defined by the 300 pptv level are examined in the Gaussian dispersion framework based on a wet season plume event observed in Amazonia. Pollution travels slowly in the sluggish winds of the equatorial trough. Daily storms are likely to interrupt the effluent while coverages are still on the order of few thousand square kilometers and NO_x concentrations are above the threshold. Dry season plume sizes are difficult to assess because local concentration data are scarce, but it is conceivable that the faster trade winds lead to a several fold extension.     

Shortest service location model for planning waste pickup locations

A municipal solid waste (MSW) and recycled material curbside pickup bus system was recently initiated in a Taiwan city to improve collection service. For such an MSW pickup system, selecting appropriate collection stops critically affects hauling costs and service efficiency. Conventionally, MSW collection points are heuristically and manually chosen, resulting in a hauling system that is not as effective as intended in terms of location suitability and the number of collection points. The Shortest Service Location (SSL) model, which minimizes the sum of service distances, was therefore proposed in this study. The SSL model was compared with two other models for a local MSW pickup system problem. Using georeferenced graphs generated by a geographical information system (GIS) and related programs, the performance of the three models was compared according to walking distance to a service stop, the coverage of a service stop, and the number of service stops. The results show that the SSL solution can shorten walking distances by approximately 10% and reduce the overlap of service areas covered.