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811.
To determine whether loggerhead turtles (Caretta caretta) nesting in southeastern USA exhibit polymorphic foraging strategies, we evaluated skin samples for stable isotopes of carbon (δ13C) and nitrogen (δ15N) from 310 loggerheads from four locations on the east coast of Florida and epibionts from 48 loggerheads. We found a dichotomy between a depleted δ13C cluster and an enriched δ13C cluster. Epibionts from oceanic/pelagic or neritic/benthic habitats were largely consistent with this dichotomy. The bimodal distribution of δ13C could reflect a bimodal foraging strategy or—because of the potential for confounding among four gradients of δ13C in marine environments—a polymodal foraging strategy. We integrate our results with results from other stable isotope studies, satellite telemetry, and flipper tags to evaluate potential foraging strategies. Understanding foraging strategies is essential for development of management plans for this endangered species that has suffered a 43% population decline over the last decade.  相似文献   
812.
PM2.5 (particulate matter less than 2.5 μm in aerodynamic diameter) speciation data collected between 2003 and 2005 at two United State Environmental Protection Agency (US EPA) Speciation Trends Network monitoring sites in the South Coast area, California were analyzed to identify major PM2.5 sources as a part of the State Implementation Plan development. Eight and nine major PM2.5 sources were identified in LA and Rubidoux, respectively, through PMF2 analyses. Similar to a previous study analyzing earlier data (Kim and Hopke, 2007a), secondary particles contributed the most to the PM2.5 concentrations: 53% in LA and 59% in Rubidoux. The next highest contributors were diesel emissions (11%) in LA and Gasoline vehicle emissions (10%) in Rubidoux. Most of the source contributions were lower than those from the earlier study. However, the average source contributions from airborne soil, sea salt, and aged sea salt in LA and biomass smoke in Rubidoux increased.To validate the apportioned sources in this study, PMF2 results were compared with those obtained from EPA PMF (US EPA, 2005). Both models identified the same number of major sources and the resolved source profiles and contributions were similar at the two monitoring sites. The minor differences in the results caused by the differences in the least square algorithm and non-negativity constraints between two models did not affect the source identifications.  相似文献   
813.
Particulate matter (PM) has become a major research issue receiving increasing attention because of its significant negative impact on human health. There are main indicators that next to the morphological characteristics of the particle, also the chemical composition plays an important role in the adverse health effects of PM. In this context, the rather polar organic fraction of PM is expected to play a major role, and advanced analytical techniques are developed to improve the knowledge on the molecular composition of this fraction. One component class that deserves major attention consists of the oxygenated polycyclic aromatic hydrocarbons (PAHs). Those compounds are considered to be among the key compounds in PM toxicity. This paper presents a comprehensive review focusing on the analysis, fate and behavior of oxygenated PAHs in the atmosphere. The first part of the paper briefly introduces (i) the main sources and atmospheric pathways of oxygenated PAHs, (ii) available physical–chemical properties and (iii) their health effects. The second and main part of this paper gives a thorough discussion on the entire analytical sequence necessary to identify and quantify oxygenated PAHs on atmospheric PM. Special attention is given to critical parameters and innovations related to (i) sampling, (ii) sample preparation including both extraction and clean-up, and (iii) separation and detection. Third, the state-of-the-art knowledge about the atmospheric occurrence of oxygenated PAHs is discussed, including an extended overview of reported concentrations presented as a function of sampling season and geographical location. A clear seasonal effect is observed with the median of the oxygenated PAHs concentrations during winter being a factor of 3–4 higher than during summer. However, the oxygenated PAH/parent PAH ratio is about 20 times higher during summer, indicating the importance of photochemical activity in the atmosphere.  相似文献   
814.
Ambient air samples from various studies were analyzed for a specific set of trace-level volatile organic compounds by using a gas chromatograph (GC) equipped with a flame ionization detector (FID) in parallel with an electron capture detector (ECD). The samples were then reanalyzed on a second GC system equipped with a mass selective detector (MSD). GC-FID/ECD data were compared to the nominally correct GC-MSD data to determine the accuracy of the nonspecific detectors, which often do not differentiate the targeted compound from Interfering compounds. Qualitative accuracy (capability for correctly identifying compounds on the basis of retention time only) and quantitative accuracy (capability for correctly measuring the concentration of an identified compound on the basis of peak area) were evaluated. Data are presented on a per-compound basis to provide the combined typical results from air samples collected in three geographic regions: Kanawha Valley, WV; Los Angeles, CA, area; and Houston, TX.  相似文献   
815.
Hawksbill sea turtles, Eretmochelys imbricata, are closely associated with coral reef and other hard-bottom habitats. Seagrass pastures are peripheral habitats for Caribbean hawksbills. With the decline in quality and quantity of coral reefs, seagrass habitats may become more important for hawksbills. We use data from a 30-year mark-recapture study of hawksbills and green turtles, Chelonia mydas, in the southern Bahamas to assess the quality of a seagrass habitat for hawksbills. Size distribution, residence times, and body condition index for the seagrass hawksbill aggregation are similar to those of hawksbill aggregations over Caribbean reefs. Somatic growth rates of seagrass hawksbills are in the upper range of those reported for reef hawksbills. Based on these parameters, peripheral seagrass habitats can support healthy, productive hawksbill aggregations. During the 30-year study, a sixfold variation in green turtle density in the study area did not affect the productivity or body condition of hawksbills.  相似文献   
816.
In Uganda, environmental and natural resource management is decentralized and has been the responsibility of local districts since 1996. This environmental management arrangement was part of a broader decentralization process and was intended to increase local ownership and improve environmental policy; however, its implementation has encountered several major challenges over the last decade. This article reviews some of the key structural problems facing decentralized environmental policy in this central African country and examines these issues within the wider framework of political decentralization. Tensions have arisen between technical staff and politicians, between various levels of governance, and between environmental and other policy domains. This review offers a critical reflection on the perspectives and limitations of decentralized environmental governance in Uganda. Our conclusions focus on the need to balance administrative staff and local politicians, the mainstreaming of local environmental policy, and the role of international donors.  相似文献   
817.
Research on helping has identified positive consequences of helping for the helper, beneficiary, group, and organization. Recent research, however, raises concerns about contingencies that influence the outcomes of helping and suggests the need for a more nuanced perspective on the positive outcomes of helping. In this paper, we develop a novel theoretical perspective to address these contingencies by differentiating between proactive helping and reactive helping. Drawing from the two main theoretical frameworks, which have been used as the basis for studying helping—social exchange theory and functional motives theory—we discuss differences in the positive consequences of reactive and proactive helping for helpers, dyads, groups, and organizations. We submit that reactive helping facilitates heedful relationships, such that it creates and perpetuates social exchange norms that benefit others in the group. Conversely, we posit that proactive helping is often based on fulfilling personal needs, such that it benefits the self in terms of reputational benefits, well‐being, favorable self‐evaluations, need satisfaction, and self‐development. We discuss theoretical implications of this framework for future research on the positive consequences of helping. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
818.
Land use planning (LUP) around industrial sites at risk of major accidents requires the application of sound approaches in the selection of credible accident scenarios. In fact, the ‘technical’ phase of LUP is based on the identification and assessment of relevant accident scenarios. An improper choice of scenarios may critically affect both the ‘technical’ phase of risk assessment and the following ‘policy’ phase concerning decision making on land-use restrictions and/or licensing. The present study introduces a procedure aimed at the systematic identification of reference accident scenarios to be used in the gathering of technical data on potential major accidents, which is a necessary step for LUP around Seveso sites. Possible accident scenarios are generated by an improved version of the MIMAH methodology (Methodology for the Identification of Major Accident Hazards). The accident scenarios are then assessed for LUP relevance considering severity, frequency and time scale criteria. The influence of prevention and mitigation barriers is also taken into account. Two applications are used to demonstrate the proposed procedure. In both case-studies, the proposed methodology proved successful in producing consistent sets of reference scenarios.  相似文献   
819.
The Bow River Basin is a cornerstone of Alberta's development. In 2010, stakeholders representing interests from agriculture, municipalities, environment, and more formed the Bow River Project Research Consortium to help determine the potential for improving the operations in the basin. At present, upstream reservoirs are operated primarily for hydropower, whereas downstream reservoirs are operated for irrigation. Through Collaborative Modeling for Decision Support the stakeholders were able to develop a new method for operating the system that would dramatically improve environmental performance. The main components of the new operating strategy called for: purchase or setting aside of a small amount of storage volume in the power reservoirs; a set of rules for releases from that storage; an agreement by the major irrigation districts with the largest water licenses to utilize their ability to shift deliveries to and from their large offstream storage reservoirs to allow for increased instream flows, and to allow junior water license holders (mainly municipal and industrial supplies) an uninterrupted water supply; limitations of reservoir fluctuations to improve inreservoir habitat for fisheries; and increased minimum flows throughout the system leading to improved environmental outcomes. Costs of this strategy were minimal, impacts on power revenue were estimated at <US$2 million/yr on average. Compensatory arrangements should be possible.  相似文献   
820.
Biodiversity planners increasingly recognise the need for delivering action on a ‘wider countryside’, rather than on a purely site‐centred, basis. Ecological processes often take place at the ‘landscape scale’ and are not sufficiently accommodated within reserves, and a failure to reflect this in biodiversity planning has been one of the contributors to species and habitat decline. However, there are generally few powers to enforce compliance with spatial rural land‐use strategies, and biodiversity plans at the landscape scale must rely heavily on incentives, advice and goodwill. Not surprisingly, this results in a substantial gap between policy and implementation. One way of analysing the causes of, and potential solutions to, implementation failure is to examine the barriers to plan uptake. This paper addresses barriers to biodiversity action in three case‐study areas in terms of ‘force fields’, depicting the nature and strength of negative and positive influences on land managers and conservation staff. It is concluded that a clearer understanding of the nature of ‘barriers’ can lead to improved targeting on potential ‘bridges’ to a better future.  相似文献   
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