Improving environmental risk management through historical impact assessments

A historical contaminant impact assessment was conducted at 48 heavy manufacturing facilities located in 20 different states for a U.S.-based company. The facilities evaluated were industrial manufacturing sites that operated for as long as 100 yr and used several types of hazardous substances, including solvents and degreasers, oils and other petroleum products, paints and pigments, and heavy metals. The purpose of conducting the impact assessment was to provide direction and guidance on future environmental objectives and pollution prevention initiatives. The impact assessment involved examining historical investigative and remediation costs since 1985, types of contaminants, subsurface geology, hydrology, and regulatory requirements. The results reveled that 85% of the historical environmental costs were associated with hexavalent chromium and chlorinated solvents. Other contaminants, such as oils and other petroleum products and other heavy metals, were far more commonly detected but only accounted for the remaining 15% of costs. The results also indicated that the costs are also strongly associated with the type of geologic environment to which the chemicals were released. As a result of these findings, an aggressive pollution prevention program has been initiated to eliminate the use of those contaminants that are especially expensive to remediate and to develop stronger and more effective engineering controls at facilities located in sensitive ecological areas.     

Heavy metals in an urban watershed in southeastern Michigan

The occurrence of heavy metals in the soil was measured over a period of several years to determine background concentrations in a heavily urbanized watershed in southeastern Michigan. A spatially dispersed sample was collected to capture the inherent variability of the soils and historic land use. The analysis focused on 14 metals (antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, thallium, and zinc) that are part of the USEPA's list of the 129 most common pollutants. Metal concentrations were measured at three depths: near-surface (<0.5 m), shallow subsurface (0.5-10 m), and depths greater than 10 m across six soil units in glacial terrain. Additional analyses assessed the metal concentrations in each depth profile across three general land use categories: residential, commercial, and industrial. Metal concentrations were the highest in the near-surface with Pb present at concentrations averaging 15.5 times that of background in industrial areas and approximately 16 times background in residential areas. Cadmium, Hg, and Zn were also present in surface soils at levels of several times that of background. The highest concentrations of each of these metals were present in the clay-rich soils located in the eastern, more urbanized and industrialized part of the watershed. Metals detected at elevated concentrations decreased in concentration with increasing depth and distance from the urbanized and industrialized center of the watershed. Statistically significant differences in the concentrations of heavy metals were also noted between the land use categories, with Cd, Cr, Cu, Pb, Ni, and Zn observed within industrial areas at mean concentrations several times greater than background levels.     

Surface and subsurface geologic risk factors to ground water affecting brownfield redevelopment potential

A model is created for assessing the redevelopment potential of brownfields. The model is derived from a space and time conceptual framework that identifies and measures the surface and subsurface risk factors present at brownfield sites. The model then combines these factors with a contamination extent multiplier at each site to create an index of redevelopment potential. Results from the application of the model within an urbanized watershed demonstrate clear differences between the redevelopment potential present within five different near-surface geologic units, with those units containing clay being less vulnerable to subsurface contamination. With and without the extent multiplier, the total risk present at the brownfield sites within all the geologic units is also strongly correlated to the actual costs of remediation. Thus, computing the total surface and subsurface risk within a watershed can help guide the remediation efforts at broad geographic scales, and prioritize the locations for redevelopment.     

HYDRAULIC AND ECONOMIC BENEFITS OF DOWNSPOUT DWERSION1

ABSTRACT: A downspout diversion program in an urban area is evaluated to assess the impacts on sanitary sewer flow volumes and cost effectiveness. Sanitary sewer flows and wastewater treatment cost data are compared for the five years before and 1.25 years after the downspout diversion was completed. In order to establish a cause and effect relationship between flow volumes and downspout diversion, measurements of precipitation, consumption patterns, and system loss (maintenance, fire flows, main ruptures) for the before and after time periods were obtained. The results indicate the downspout diversion contributed to a reduction of over 25 percent in the mean flow volumes within the sanitary sewer collection network during all rainfall events, with flow reductions ranging from 25 percent to 62 percent for rainfall depths between 6 mm (0.25 inches) and 25.4 mm (1.0 inches). Costs incurred for wastewater treatment were also reduced significantly, as overtime for overflow maintenance was eliminated. Downspout diversion is a viable nonstructural alternative for sthrmwater flow reduction in highly urbanized communities which may lack available space for large scale detention facilities.     

Comparison of mid-block and intersection-related left turn collisions

OBJECTIVES: To evaluate the factors that might influence an occupant's injury severity during a left turn movement. METHODS: We used the National Automotive Sampling System Crashworthiness Data System (1995-2005) to compare crash characteristics and injury outcome between intersection and midblock left turn collisions. RESULTS: A total of 7,396 collisions were evaluated. Traffic control devices were present in 82% of intersection and 10% of mid-block collisions. After adjustment for potential confounding variables, drivers' injury severity was not significantly associated with the crash location. However, front seat passengers in mid-block collisions had 72% higher odds of experiencing an injury with injury severity score > or =9 (odds ratio: 1.72, 95% confidence interval: 1.09-2.69). Our analysis did not show that drivers or passengers in larger vehicles, e.g., sport utility vehicles and mini-vans, were at lower risk of more severe injuries in comparison to the car occupants in sedans. CONCLUSION: We found that in comparison to intersection-related left turn collisions, mid-block crashes are associated with more severe injuries for front seat passengers. Furthermore, size of the turning vehicle was not significantly associated with injury severity for drivers or front seat passengers.     

Green Biomass Materials in Polyurethane Foams

Flexible polyurethane foams were prepared using naturally derived materials as alternatives to conventional auxiliary blowing agents. This research was based on the concept held by some that natural chemicals are better as a part of industrial ecology. The authors have attempted to define the foam manufacturing suitability of natural chemicals, but have not defined or defended the policy implications of such choices. Natural chemicals are often less suitable than those refined from petroleum and may then need some environmental credit related to greater discharge to be viable substitutes. Modest decreases in density (relative to foams without any auxiliary blowing agent) were obtained with the addition of solid CO₂ but other physical properties were not measured. It is unclear whether the reduction in density is a result of the phase change of CO, from solid to liquid within the polyurethane cell matrix or simply a bubbling effect of C02 in solution causing voids within the final product. Although it was anticipated that the high boiling point of limonene, from citrus peeis, would negate effectiveness as an auxiliary blowing agent, there were analogous decreases in foam density. The observed effect might be rationalized by the significant vapor pressure of limonene at temperatures lower than the boiling point. The limonene may be sweptf rom the foam system coincident with the loss of in situ generated CO₂ isoprene, naturally emitted from deciduous vegetation as well as from the combustion of carbonaceous fuels, provides a useful, if not complete, range of foam densities and may then be a partial substitute for halogenated auxiliary blowing agents. Switching from methyiene chloride to isoprene as the auxiliary blowing agent of choice would immediately decrease organic emissions from polyurethane foam plants by 20 percent (molecular weight effect). Regulation as a VOC and the residual acrid odor may be potential drawbacks to commercial utilization of isoprene.     

Water-based condensation particle counters for environmental monitoring of ultrafine particles

TSI Inc. (Shoreview, MN) has introduced three new water-based condensation particle counters (WCPCS) that were designed to detect airborne particles larger than 2.5 nm (model 3786), 5 nm (model 3785), and either 10 or 20 nm (model 3782). These WCPCs are well suited for real-time, environmental monitoring of number concentration of airborne ultrafine particles. Their unique design incorporates the use of water as the working fluid instead of alcohol. Water is odor free, readily available, and eliminates the problem of water condensation and absorption into alcohol working fluids during operation in humid environments. In this study, the performance of three TSI WCPCs was characterized for several aerosol compositions, including sucrose, salt (NaCl), dioctyl sebacate (DOS), dioctyl phthalate (DOP), emery oil (poly-alpha-olefin), silver, impurity residue particles, and ambient aerosol particles. All particles were size selected using a nano differential mobility analyzer (nano-DMA; model 3085, TSI Inc.) to create monodisperse challenge aerosols. The challenge aerosol was mixed uniformly with clean makeup flow and split into a WCPC and a reference instrument to determine the counting efficiency of the WCPC. For the model 3785 WCPC, the D50 (i.e., the particle diameter with 50% counting efficiency) was determined to be 3.1 nm for salt particles, 4.7 nm for sucrose and ambient particles, 5.6 nm for silver particles, and >50 nm for ultrapure oil particles. The sensitivity to oil droplets increased dramatically (D50 < 10 nm) when the oil was slightly contaminated. The D50 of model 3786 ultrafine water-based CPC (UWCPC) was 2.4 nm for impurity residue particles. The D50 of the model 3782 WCPC was 10.8 (with a nominal setting of 10 nm) or 19.8 nm (with a nominal setting of 20 nm) for sucrose particles. All three WCPCs have response times of less than 2 or 3 sec and are therefore able to detect fast-changing events.