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21.
Ning Tang Wanli Xing Lu Yang Hao Zhang Xuan Zhang Yan Wang Pengchu Bai Lulu Zhang Kazuichi Hayakaw Seiya Nagao 《环境科学学报(英文版)》2022,34(11):38-47
A three-year sampling campaign was conducted at a roadside air pollution monitoring station in the urban area of Kanazawa, Japan. Due to a new emission regulation, PAHs levels decreased over the sampling campaign, exhibiting values of 706 ± 413 pg/m3 in 2017, 559 ± 384 pg/m3 in 2018, and 473 ± 234 pg/m3 in 2019. In each year, similar seasonal variations in PAHs levels were observed, with higher levels observed in winter and lower levels in summer. Among the PAHs isomer ratios, we observed that the ratio of benzo[b]fluoranthene (BbF) and benzo[k]fluoranthene (BkF), [BbF]/([BbF] + [BkF]), and the ratio of indeno[1,2,3-cd]pyrene (IDP) and benzo[ghi]perylene (BgPe), [IDP]/([BgPe] + [IDP]), showed stability over the sampling campaign and were less affected by the new emission regulation, seasonal variations, and regional characteristics. When using the combined ratio ranges of 0.66 - 0.80 ([BbF]/([BbF] + [BkF]) and 0.26-0.49 ([IDP]/([BgPe] + [IDP]), traffic emissions were clearly distinguished from other PAHs emission sources. Principal component analysis (PCA) and positive matrix factorization (PMF) were also performed to further analyse the characteristics of traffic-related PAHs. Overall, this study affirmed the effectiveness of the new emission regulation in the reduction of PAHs emissions and provided a combined range for identifying PAHs traffic emission sources. 相似文献
22.
Detection of Dechlorane Plus and brominated flame retardants in marketed fish in Japan 总被引:3,自引:0,他引:3
Kakimoto K Nagayoshi H Yoshida J Akutsu K Konishi Y Toriba A Hayakawa K 《Chemosphere》2012,89(4):416-419
Fish samples purchased from Japanese markets were analyzed for Dechlorane Plus (DP)(syn-, anti-), polybrominated diphenyl ether (PBDE), and hexabromocyclododecane (HBCD)(α, γ). Twenty fish were analyzed using gas chromatography-mass spectrometry for DP and PBDE, and using liquid chromatography-tandem mass spectrometry for HBCD. DP was detected in 18 samples and ∑DP concentrations were <0.2-14.2 pg g−1 wet wt. Among the DP isomers, anti-DP was the dominant residue observed in this study. PBDE was detected in all samples. Concentrations of ∑PBDE ranged from 2.2 to 878 pg g−1 wet wt. HBCD was detected in 18 samples, and ∑HBCD concentrations were <0.02-21.9 ng g−1 wet wt. In fish landed near the East China Sea and the Sea of Japan, we detected relatively high concentrations of DP, PBDE, and HBCD. These results indicate that the seawaters around East Asia are contaminated with flame retardants. This study demonstrates the presence of DP in fish marketed in Japan for the first time. 相似文献
23.
Woli KP Hayakawa A Kuramochi K Hatano R 《Environmental monitoring and assessment》2008,137(1-3):251-260
River water quality was evaluated with respect to eutrophication and land use during spring snowmelt and summer base flow
periods in Abashiri (mixed cropland-livestock farming) and Okoppe (grassland-based dairy cattle farming), eastern Hokkaido,
Japan. Water from rivers and tributaries was sampled during snowmelt and summer base flow periods in 2005, and river flow
was measured. Total N (TN), NO3–N, and Si concentrations were determined using standard methods. Total catchment and upland areas for each sampling site
were determined with ArcGIS hydrology modeling software and 1:25,000-scale digital topographic maps. Specific discharge was
significantly higher during snowmelt than during base flow. In both areas, TN concentrations increased, whereas Si concentrations
decreased, with increased specific discharge, and were significantly higher during snowmelt. The Si:TN mole ratio decreased
to below or close to the threshold value for eutrophication (2.7) in one-third of sites during snowmelt. River NO3–N concentrations during base flow were significantly and positively correlated with the proportion of upland fields in the
catchment in both the Abashiri (r = 0.88, P < 0.001) and Okoppe (r = 0.43, P < 0.01) areas. However, the regression slope, defined as the impact factor (IF) of water quality, was much higher in Abashiri
(0.025) than in Okoppe (0.0094). The correlations were also significantly positive during snowmelt in both areas, but IF was
four to eight times higher during snowmelt than during base flow. Higher discharge of N from upland fields and grasslands
during snowmelt and the resulting eutrophication in estuaries suggest that nutrient discharge during snowmelt should be taken
into account when assessing and monitoring the annual loss of nutrients from agricultural fields. 相似文献
24.
Tohno S Ma CJ Hayakawa S Yamasaki S Kasahara M 《Environmental monitoring and assessment》2006,120(1-3):575-584
The X-ray microprobe system was applied to ultra trace characterization of single Kosa aerosols and non-Kosa aerosols simultaneously collected at Yasaka, Japan and TaeAnn, Korea. We demonstrated remarkable mass increase of heavy metals as well as soil components in individual particles during the Kosa event compared with the non-Kosa period at Yasaka. Backward trajectory analysis suggested that the Kosa samples were in the mixing state of mineral components and anthropogenic heavy elements. Double thin film method was applied to investigate the seasonal change of the mixing states of single sea-salt aerosols associated with chlorine loss due to the heterogeneous reactions between sea-salt particles and acidic gases. It was revealed that the percentages of both chloride-nitrate mixed particles and sulfate-nitrate ones were larger in wintertime than those in summertime and fraction of chloride-nitrate mixed particles increased with an increase of particle size. Comparison between the size-segregated bulk analysis and the single particle analysis demonstrated that remarkable chloride depletion occurred in coarse particles sampled on May in the former analysis, while chloride depletion in coarse particles was not marked in the latter analysis. The discrepancy attributes to the difference of the sampling time between both analyses because significant change of air mass route occurred during the bulk sampling after completion of the single particle sampling. 相似文献