The potential effect of differential ambient and deployment chamber temperatures on PRC derived sampling rates with polyurethane foam (PUF) passive air samplers

Performance reference compound (PRC) derived sampling rates were determined for polyurethane foam (PUF) passive air samplers in both sub-tropical and temperate locations across Australia. These estimates were on average a factor of 2.7 times higher in summer than winter. The known effects of wind speed and temperature on mass transfer coefficients could not account for this observation. Sampling rates are often derived using ambient temperatures, not the actual temperatures within deployment chambers. If deployment chamber temperatures are in fact higher than ambient temperatures, estimated sampler-air partition coefficients would be greater than actual partition coefficients resulting in an overestimation of PRC derived sampling rates. Sampling rates determined under measured ambient temperatures and estimated deployment chamber temperatures in summer ranged from 7.1 to 10 m³ day⁻¹ and 2.2-6.8 m³ day⁻¹ respectively. These results suggest that potential differences between ambient and deployment chamber temperatures should be considered when deriving PRC-based sampling rates.     

The Energy for Growing and Maintaining Cities

Herein we develop a means to differentiate between the energy required to expand and the energy required to maintain the economies of cities. A nonlinear model is tested against historical data for two cities, Hong Kong and Singapore. A robust fit is obtained for Hong Kong, with energy for maintenance close to that for growth, while Singapore, with a weaker fit, is growth dominated. The findings suggest that decreases in either of the per unit maintenance or growth demands can simultaneously cause gross domestic product (GDP) and total energy use to increase. Furthermore, increasing maintenance demands can significantly limit growth in energy demand and GDP. Thus, the low maintenance demands for Hong Kong, and especially Singapore, imply that, all other things being equal, GDP and energy use of these cities will continue to grow, though Singapore’s higher energy use for growth means it will require more energy than Hong Kong.     

国际商会工商业可持续发展宪章及其它志愿举措:在一个正在全球化的世界上空前有关

任何一家公司,无论其规模、行业还是地点如何,都可以通过改善内部的环境、健康与安全管理而对可持续发展做出显著贡献.国际商会工商业可持续发展宪章强调在企业内部引进和发展环境管理实践与体系,作为对可持续发展的一种基本贡献.本文认为,志愿举措,包括像国际商会宪章这样以原则为基础的志愿举措,在全球化、活动家压力和公司环境管理进展等范畴内既是恰当的也是成功的.     

Age and growth of the fan mussel Pinna nobilis from south-east Spanish Mediterranean seagrass (Posidonia oceanica) meadows

The calcitic and aragonitic shell of the fan mussel Pinna nobilis L. contains a record of the environmental changes experienced during its growth. Stable-isotope analyses of oxygen (¹⁸O:¹⁶O) in shell carbonate from the calcitic outer shell-layer have been used to validate the periodicity of clearly defined concentric rings on the aragonitic posterior adductor-muscle scar and to estimate the age and growth of fan mussels growing in Posidonia oceanica (L.) meadows at four locations on the south-east Spanish Mediterranean coast. The stable oxygen-isotope records obtained at intervals along a profile across the shell surface enabled seasonal changes in water temperature to be established, and hence seasonal patterns of shell growth to be inferred. Muscle-scar rings were found to be deposited annually in the shell in the spring and early summer (a period of increasing water temperatures), and represent an interruption in the migration of the posterior adductor muscle along the inner surface of the shell. In small pinnids (<25 cm) accretion of the shell is rapid during the first year, but in the second year it is distinctly slower than at the same time the previous year. This slowing down in growth during the second year coincides with the appearance of the “first” distinct muscle-scar ring, indicating that Pinna nobilis does not form a muscle-scar ring during its first year of shell growth. Maximum growth rates were recorded amongst pinnids from Carboneras, where they achieved a length of 59 cm in 8 yr, whilst those from Aguamarga were estimated to be the oldest (attaining a length of 45 cm in 13 yr). Received: 26 January 1998 / Accepted: 8 October 1998     

Investigating the Uncertainties in the Simple Mass Balance Equation for Acidity Critical Loads for Terrestrial Ecosystems in the United Kingdom

The Simple Mass Balance (SMB)equation has been developed and used as one ofthe principal methods for calculating criticalloads of acidity for forest ecosystems. Criticalloads have formed the basis for informing policyrelated to the control and abatement of emissionsof acidifying pollutants. The SMB equationrelies on a variety of assumptions and dataderived from a variety of sources. Each of thesecomponent constituents has a potential source oferror depending on the method(s) used for theirderivation and the value(s) assigned. The resultis the possibility of generating a range ofcritical load values for a single ecosystem. This paper summarises the SMB equation, examinesthe uncertainties in deriving input values andreviews other works on the key assumptions.     

Catalyzing success in community-based conservation

Efforts to devolve rights and engage Indigenous Peoples and local communities in conservation have increased the demand for evidence of the efficacy of community-based conservation (CBC) and insights into what enables its success. We examined the human well-being and environmental outcomes of a diverse set of 128 CBC projects. Over 80% of CBC projects had some positive human well-being or environmental outcomes, although just 32% achieved positive outcomes for both (i.e., combined success). We coded 57 total national-, community-, and project-level variables and controls from this set, performed random forest classification to identify the variables most important to combined success, and calculated accumulated local effects to describe their individual influence on the probability of achieving it. The best predictors of combined success were 17 variables suggestive of various recommendations and opportunities for conservation practitioners related to national contexts, community characteristics, and the implementation of various strategies and interventions informed by existing CBC frameworks. Specifically, CBC projects had higher probabilities of combined success when they occurred in national contexts supportive of local governance, confronted challenges to collective action, promoted economic diversification, and invested in various capacity-building efforts. Our results provide important insights into how to encourage greater success in CBC.     

The impact of drought on production, consumption and nutrition in southwestern kenya

In this paper I compare the effects of the 1984 drought on agricultural production, income, food consumption, and nutrition of farm and non-farm households in South Nyanza District, Kenya. Survey work covered the period 1984 to 1987. It was the late arrival of the long rains in spring 1984, rather than an absolute shortfall in rain, that caused most of the fluctuations in agricultural production. Agricultural households who were least affected by the drought were able to cope by increasing the amount of cultivated land and by relying more on coarse grain production. Coping strategies for the landless households in South Nyanza were more limited and this group of households therefore experienced greater fluctuations in income between the drought and non-drought periods than did most types of agricultural households. Surprisingly, changes in food consumption between the drought and non-drought periods were small for most households. In spite of differences in production, food availability and incomes, however, the health and nutritional status of pre-school-aged children was not significantly different in the two time periods. Differences in health and nutritional status appear to be influenced more by community-level health and sanitation factors than by differences in agricultural production and incomes in drought and non-drought years.     

Oil spill response capabilities and technologies for ice-covered Arctic marine waters: A review of recent developments and established practices

Renewed political and commercial interest in the resources of the Arctic, the reduction in the extent and thickness of sea ice, and the recent failings that led to the Deepwater Horizon oil spill, have prompted industry and its regulatory agencies, governments, local communities and NGOs to look at all aspects of Arctic oil spill countermeasures with fresh eyes. This paper provides an overview of present oil spill response capabilities and technologies for ice-covered waters, as well as under potential future conditions driven by a changing climate. Though not an exhaustive review, we provide the key research results for oil spill response from knowledge accumulated over many decades, including significant review papers that have been prepared as well as results from recent laboratory tests, field programmes and modelling work. The three main areas covered by the review are as follows: oil weathering and modelling; oil detection and monitoring; and oil spill response techniques.     

Applied geologic,microbiological, and engineering constraints of in-situ BTEX bioremediation

An in-situ bioremediation project has been designed and constructed for a site in south-central Kansas just north of Wichita. A pipeline leaked an unknown quantity of refinedfuels in the 1970s. The spill was undetected until hydrocarbons were found in a nearby municipal water supply well. Of concern, from a regulatory perspective, are the alkylbenzene components found in the groundwater, including benzene, toluene, ethylbenzene, and xylene (BTEX). Initial abatement procedures, including free product removal and pumping, had become ineffective. In-situ bioremediation was selected to complete the restoration process. The project emphasizes the need for a strong understanding of the geologic and hydrogeologic conditions prevalent under the site. Site studies were conducted to determine the distribution and mass of the contaminant and the hydraulic regime. Laboratory microbial studies were used to determine the efficacy of nitrate as a primary electron acceptor. Information from site studies was used to design a treatment system tailored to the requirements of the site. The treatment system is designed to deliver the maximum amount of nutrient-enriched water to the contaminated zone while maintaining hydraulic control of the site.     

Regional carbon cycle responses to 25 years of variation in climate and disturbance in the US Pacific Northwest

Variation in climate, disturbance regime, and forest management strongly influence terrestrial carbon sources and sinks. Spatially distributed, process-based, carbon cycle simulation models provide a means to integrate information on these various influences to estimate carbon pools and flux over large domains. Here we apply the Biome-BGC model over the four-state Northwest US region for the interval from 1986 to 2010. Landsat data were used to characterize disturbances, and forest inventory data were used to parameterize the model. The overall disturbance rate on forest land across the region was 0.8 % year^?1, with 49 % as harvests, 28 % as fire, and 23 % as pest/pathogen. Net ecosystem production (NEP) for the 2006–2010 interval on forestland was predominantly positive (a carbon sink) throughout the region, with maximum values in the Coast Range, intermediate values in the Cascade Mountains, and relatively low values in the Inland Rocky Mountain ecoregions. Localized negative NEPs were mostly associated with recent disturbances. There was large interannual variation in regional NEP, with notably low values across the region in 2003, which was also the warmest year in the interval. The recent (2006–2010) net ecosystem carbon balance (NECB) was positive for the region (14.4 TgC year^?1). Despite a lower area-weighted mean NECB, public forestland contributed a larger proportion to the total NECB because of its larger area. Aggregated forest inventory data and inversion modeling are beginning to provide opportunities for evaluating model-simulated regional carbon stocks and fluxes.