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71.
Shivaramaiah HM Sanchez-Bayo F Al-Rifai J Kennedy IR 《Journal of environmental science and health. Part. B》2005,40(5):711-720
Although the use of endosulfan to control cotton pests has declined, this insecticide still has widespread application in agriculture and can contaminate riverine systems as runoff from soil or by aerial deposition. The degradation of endosulfan in pure water at different pH values of 5, 7 and 9 and in river water from the Namoi and the Hawkesbury rivers of New South Wales (NSW), Australia, was studied in the laboratory. Endosulfan transformation into endosulfan sulfate in river water using artificial mesocosms was also investigated. The results show endosulfan is stable at pH 5, with increasing rates of disappearance at pH 7 and pH 9 by chemical hydrolysis. Incubation of endosulfan with river water at pH 8.3 resulted in the disappearance of endosulfan and the formation of endosulfan diol due to the alkaline pH as well as formation of endosulfan sulfate. Although the degradation of endosulfan by Anabaena, a blue-green alga, did not result in the transformation of endosulfan to endosulfan sulfate, we conclude that other microorganisms catalyzed the formation of the sulfate. Significant conversions of endosulfan into endosulfan sulfate were also reported from associated field studies using artificial mesocoms containing irrigation water from rivers inhabitated by micro-macro fauna. From these results, we conclude that the presence of endosulfan sulfate in river water cannot be used to distinguish contamination by runoff from soil from contamination by aerial drift or redeposition. 相似文献
72.
73.
The primary objective of this paper is to discuss the limitations of risk management as a strategy for Australian local government climate change adaptation and explore the advantages of complementary approaches, including a social-ecological resilience framework, adaptive and transition management, and vulnerability assessment. Some federal and local government initiatives addressing the limitations of risk-based approaches are introduced. We argue that conventional risk-based approaches to adaptation, largely focused on hazard identification and quantitative modelling, will be inadequate on their own for dealing with the challenges of climate change. We suggest that responses to climate change adaptation should move beyond conventional risk-based strategies to more realistically account for complex and dynamically evolving social-ecological systems. 相似文献
74.
Penaeid shrimp can be useful ecological indicators of linkages between shallow tropical coastal habitats, acting as integrators of carbon and nitrogen sources due to their generalist feeding habits and their mobility between habitats and with tidal cycles. In the current study, the contribution of mangrove, seagrass and microbial mat to the nutrition of two penaeid shrimp species, Penaeus semisulcatus and Metapeneus ensis, in a shallow arid embayment in the Arabian Gulf was assessed through a combination of analysis of stomach contents and dual carbon and nitrogen stable isotope signatures. Shrimp tissue stable isotope signatures identified seagrass as a major source of carbon and nitrogen for both species, contributing 21–38?% (1–99?‰). Microbial mat was also detected as a significant nutritional source for early-stage Metapenaeus affinis postlarvae (1–27?%). However, mangroves were not identified as a significant source, with the range of results including the possibility of a zero contribution. Moreover, the greatest possible contribution of mangroves as source of carbon was less than for the other primary producers. This may be due the high salinity and wide temperature range limiting mangrove productivity as well as the low export of dissolved and particulate organic material out of the mangroves due to low rainfall. 相似文献
75.
The effects of using untreated leachate for supplemental water addition and liquid recirculation on anaerobic digestion of food waste was evaluated by combining cyclic water recycle operations with batch mesophilic biochemical methane potential (BMP) assays. Cyclic BMP assays indicated that using an appropriate fraction of recycled leachate and fresh make up water can stimulate methanogenic activity and enhance biogas production. Conversely increasing the percentage of recycled leachate in the make up water eventually causes methanogenic inhibition and decrease in the rate of food waste stabilization. The decrease in activity is exacerbated as the number cycles increases. Inhibition is possibly attributed to accumulation and elevated concentrations of ammonia as well as other waste by products in the recycled leachate that inhibit methanogenesis. 相似文献
76.
Mitchell Kennedy 《环境质量管理》1999,8(4):53-62
ISO 14001 offers an excellent framework for improving your environmental management system. But making it live up to its potential will depend on using the proper data-gathering and decision-making tools. And one of the best tools around is total cost assessment.© 1999 John Wiley & Sons, Inc. 相似文献
77.
Canopy-forming shrubs are reported to be increasing at sites around the circumpolar Arctic. Our results indicate expansion
in canopy cover and height of willows on Herschel Island located at 70° north on the western Arctic coast of the Yukon Territory.
We examined historic photographs, repeated vegetation surveys, and conducted monitoring of long-term plots and found evidence
of increases of each of the dominant canopy-forming willow species (Salix richardsonii, Salix glauca and Salix pulchra), during the twentieth century. A simple model of patch initiation indicates that the majority of willow patches for each
of these species became established between 1910 and 1960, with stem ages and maximum growth rates indicating that some patches
could have established as late as the 1980s. Collectively, these results suggest that willow species are increasing in canopy
cover and height on Herschel Island. We did not find evidence that expansion of willow patches is currently limited by herbivory,
disease, or growing conditions. 相似文献
78.
Nakayama SM Ikenaka Y Hamada K Muzandu K Choongo K Teraoka H Mizuno N Ishizuka M 《Environmental pollution (Barking, Essex : 1987)》2011,159(1):175-181
Metal (Cr, Co, Cu, Zn, Cd, Pb, Ni) and metalloid (As) accumulation was studied in roadside soil and wild rat (Rattus sp.) samples from near a Pb-Zn mine (Kabwe, Zambia) and the capital city of Zambia (Lusaka). The concentrations of the seven metals and As in the soil samples and Pb in the rat tissue samples were quantified using atomic absorption spectroscopy. The concentrations of Pb, Zn, Cu, Cd, and As in Kabwe soil were much higher than benchmark values. Geographic Information System analysis indicated the source of metal pollution was mining and smelting activity. Interestingly, the area south of the mine was more highly contaminated even though the prevailing wind flow was westward. Wild rats from Kabwe had much higher tissue concentrations of Pb than those from Lusaka. Their body weight and renal Pb levels were negatively correlated, which suggests that mining activity might affect terrestrial animals in Kabwe. 相似文献
79.
Callaghan TV Tweedie CE Akerman J Andrews C Bergstedt J Butler MG Christensen TR Cooley D Dahlberg U Danby RK Daniëls FJ de Molenaar JG Dick J Mortensen CE Ebert-May D Emanuelsson U Eriksson H Hedenås H Henry H R G Hik DS Hobbie JE Jantze EJ Jaspers C Johansson C Johansson M Johnson DR Johnstone JF Jonasson C Kennedy C Kenney AJ Keuper F Koh S Krebs CJ Lantuit H Lara MJ Lin D Lougheed VL Madsen J Matveyeva N Mcewen DC Myers-Smith IH Narozhniy YK Olsson H Pohjola VA Price LW Rigét F Rundqvist S 《Ambio》2011,40(6):705-716
Understanding the responses of tundra systems to global change has global implications. Most tundra regions lack sustained environmental monitoring and one of the only ways to document multi-decadal change is to resample historic research sites. The International Polar Year (IPY) provided a unique opportunity for such research through the Back to the Future (BTF) project (IPY project #512). This article synthesizes the results from 13 papers within this Ambio Special Issue. Abiotic changes include glacial recession in the Altai Mountains, Russia; increased snow depth and hardness, permafrost warming, and increased growing season length in sub-arctic Sweden; drying of ponds in Greenland; increased nutrient availability in Alaskan tundra ponds, and warming at most locations studied. Biotic changes ranged from relatively minor plant community change at two sites in Greenland to moderate change in the Yukon, and to dramatic increases in shrub and tree density on Herschel Island, and in subarctic Sweden. The population of geese tripled at one site in northeast Greenland where biomass in non-grazed plots doubled. A model parameterized using results from a BTF study forecasts substantial declines in all snowbeds and increases in shrub tundra on Niwot Ridge, Colorado over the next century. In general, results support and provide improved capacities for validating experimental manipulation, remote sensing, and modeling studies. 相似文献
80.
This article examines the thermal decomposition of alpha-cypermethrin, one of the most common pyrethroid pesticides. The objective was to identify its decomposition pathways and to gain an understanding into the formation of toxic species in the environment, including those that may behave in combustion systems, especially in fires in the environment, as precursors for PCDD/F (polychlorinated dibenzo-p-dioxins and dibenzofurans). The experiments were conducted under non-oxidative conditions using a tubular reactor housed in a three-zone heating furnace and operated with a dilute stream of alpha-cypermethrin in 99.999% nitrogen. The condensable products were identified and quantitated, after being collected in a cold solvent trap and in an activated charcoal cartridge. The study revealed the formation of pollutants including precursors of toxic PCDD/F such as diphenyl ether and phenol. It was also found that the decomposition of alpha-cypermethrin involved parallel pathways of an unusual vinylcyclopropane rearrangement-cum-aromatisation reaction transforming alpha-cypermethrin and a rupture of the C(O)OC(CN) linkage. The former is similar to that occurring in the decomposition of permethrin pesticide, whereas the latter constitutes a newly discovered channel for the formation of pollutants. Density functional theory (DFT) calculations allowed us to attribute the occurrence of the second pathway to the effect of the cyanide group in significantly weakening the OC bond. 相似文献