Trends in nutrient and sediment retention in Great Plains reservoirs (USA)

Reservoirs are artificial ecosystems with physical, chemical, and biological transitional characteristics between rivers and lakes. Greater water retention time in reservoirs provides conditions for cycling materials inputs from upstream waters through sedimentation, biological assimilation and other biogeochemical processes. We investigated the effects of reservoirs on the water quantity and quality in the Great Plains (Kansas, USA), an area where little is known about these dominant hydrologic features. We analyzed a 30-year time-series of discharge, total phosphorus (TP), nitrate (NO₃ ^?), and total suspended solids (TSS) from six reservoirs and estimated overall removal efficiencies from upstream to downstream, testing correlations among retention, discharge, and time. In general, mean removal of TP (42–74 %), TSS (0–93 %), and NO₃ ^? (11–56 %) from upstream to downstream did not change over 30 years. TP retention was associated with TSS removal, suggesting that nutrient substantial portion of P was adsorbed to solids. Our results indicated that reservoirs had the effect of lowering variance in the water quality parameters and that these reservoirs are not getting more or less nutrient-rich over time. We found no evidence of temporal changes in the yearly mean upstream and downstream discharges. The ratio upstream/downstream discharge was analyzed because it allowed us to assess how much contribution of additional unsampled tributaries may have biased our ability to calculate retention. Nutrient and sediment removal was less affected by hydraulic residence time than expected. Our study demonstrates that reservoirs can play a role in the removal and processing of nutrient and sediments, which has repercussions when valuing their ecological services and designing watershed management plans.     

Long-term monitoring and modeling of polychlorinated dibenzo-p-dioxins and dibenzofurans from municipal solid waste incinerators and surrounding area in northern Taiwan

Municipal solid waste incinerators (MSWIs) have long been the major contributors of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) to ambient air in Taiwan. After stringent MSWI emission standards were introduced in 2001, the long-term continuous monitoring of flue gas and ambient air quality became necessary to ensure the effectiveness of the related control strategies. Three MSWIs and the surrounding ambient air were investigated in the current study for PCDD/F characteristics during 2006 to 2011. The average concentrations in the flue gas ranged from 0.008?~?0.0488 ng I-TEQ/Nm³, which is much less than the emission standard in Taiwan (0.1 ng I-TEQ/Nm³) (I-TEQ is the abbreviation of International Toxic Equivalent). This led to extremely low levels in the ambient air, 0.0255 pg I-TEQ/Nm³, much less than the levels seen in most urban areas around the world. Additionally, the results obtained using the Industrial Source Complex Short-Term Dispersion Model (ISCST3) indicate that the PCDD/F contributions from the three MSWIs to the ambient air were only in the range from 0.164?~?0.723 %. Principal component analysis (PCA) showed that the PCDD/Fs in the air samples had very similar characteristics to those from mobile sources. The results thus show that stringent regulations have been an effective control strategy, especially for urban areas, such as Taipei City.     

Integration of novel hybrid composite discharge electrode with semi-pilot novel cross-flow electrostatic precipitator

ABSTRACT

Wet electrostatic precipitators (WESPs) are modern-era pollution control systems specifically designed to capture ultrafine particles as well as acid mist, highly resistive and sticky particles; however, this requires the use of expensive corrosion-resistant metal alloys. The work presented here is part of a continuing study at Ohio University aimed at reducing the cost of WESPs by using a novel combination of a polymer collector surfaces with a hybrid composite discharge electrode. In this study, a hybrid composite discharge electrode was tested, for the first time, inside a semi-pilot-scale experimental setup, with collection surfaces consists of a vertical array of strands. Particle laden gases were passed through this array of polymer ropes, which were kept wet by a small flow of water. The discharge electrodes were composite laminates of carbon fibers in a polymer matrix enclosing a metal mesh. The preliminary results showed that this new integrated system of composite discharge electrode and polymer collector surfaces can match or exceed the performance of a conventional metal alloy electrostatic precipitator (ESP) with metal discharge electrodes. There are additional advantages due to the system being compact, lightweight, and highly corrosion resistant.

Implications: This study focused on integrating and assessing performance of a novel hybrid composite electrode (HCE) inside semi-pilot novel cross-flow electrostatic precipitator at conditions typically observed in coal-fired power plant exhausts. The results were collected for particulate collection efficiencies and were compared with a rigid metal electrode. The HCE outperformed metal electrode by showing higher particulate collection efficiency. This result showcases substantial potential for these two new technologies (HCE and cross-flow system) as a substitute for conventional metal based wet ESPs.     

The Energy for Growing and Maintaining Cities

Herein we develop a means to differentiate between the energy required to expand and the energy required to maintain the economies of cities. A nonlinear model is tested against historical data for two cities, Hong Kong and Singapore. A robust fit is obtained for Hong Kong, with energy for maintenance close to that for growth, while Singapore, with a weaker fit, is growth dominated. The findings suggest that decreases in either of the per unit maintenance or growth demands can simultaneously cause gross domestic product (GDP) and total energy use to increase. Furthermore, increasing maintenance demands can significantly limit growth in energy demand and GDP. Thus, the low maintenance demands for Hong Kong, and especially Singapore, imply that, all other things being equal, GDP and energy use of these cities will continue to grow, though Singapore’s higher energy use for growth means it will require more energy than Hong Kong.     

Investigating the Uncertainties in the Simple Mass Balance Equation for Acidity Critical Loads for Terrestrial Ecosystems in the United Kingdom

The Simple Mass Balance (SMB)equation has been developed and used as one ofthe principal methods for calculating criticalloads of acidity for forest ecosystems. Criticalloads have formed the basis for informing policyrelated to the control and abatement of emissionsof acidifying pollutants. The SMB equationrelies on a variety of assumptions and dataderived from a variety of sources. Each of thesecomponent constituents has a potential source oferror depending on the method(s) used for theirderivation and the value(s) assigned. The resultis the possibility of generating a range ofcritical load values for a single ecosystem. This paper summarises the SMB equation, examinesthe uncertainties in deriving input values andreviews other works on the key assumptions.     

国际商会工商业可持续发展宪章及其它志愿举措:在一个正在全球化的世界上空前有关

任何一家公司,无论其规模、行业还是地点如何,都可以通过改善内部的环境、健康与安全管理而对可持续发展做出显著贡献.国际商会工商业可持续发展宪章强调在企业内部引进和发展环境管理实践与体系,作为对可持续发展的一种基本贡献.本文认为,志愿举措,包括像国际商会宪章这样以原则为基础的志愿举措,在全球化、活动家压力和公司环境管理进展等范畴内既是恰当的也是成功的.     

To duckweeds (Landoltia punctata), nanoparticulate copper oxide is more inhibitory than the soluble copper in the bulk solution

CuO nanoparticles (CuO-NP) were synthesized in a hydrogen diffusion flame. Particle size and morphology were characterized using scanning mobility particle sizing, Brunauer-Emmett-Teller analysis, dynamic light scattering, and transmission electron microscopy. The solubility of CuO-NP varied with both pH and presence of other ions. CuO-NP and comparable doses of soluble Cu were applied to duckweeds, Landoltia punctata. Growth was inhibited 50% by either 0.6 mg L⁻¹ soluble copper or by 1.0 mg L⁻¹ CuO-NP that released only 0.16 mg L⁻¹ soluble Cu into growth medium. A significant decrease of chlorophyll was observed in plants stressed by 1.0 mg L⁻¹ CuO-NP, but not in the comparable 0.2 mg L⁻¹ soluble Cu treatment. The Cu content of fronds exposed to CuO-NP is four times higher than in fronds exposed to an equivalent dose of soluble copper, and this is enough to explain the inhibitory effects on growth and chlorophyll content.     

The effect of vegetation on pesticide dissipation from ponded treatment wetlands: quantification using a simple model

Field data shows that plants accelerate pesticide dissipation from aquatic systems by increasing sedimentation, biofilm contact and photolysis. In this study, a graphical model was constructed and calibrated with site-specific and supplementary data to describe the loss of two pesticides, endosulfan and fluometuron, from a vegetated and a non-vegetated pond. In the model, the major processes responsible for endosulfan dissipation were alkaline hydrolysis and sedimentation, with the former process being reduced by vegetation and the latter enhanced. Fluometuron dissipation resulted primarily from biofilm reaction and photolysis, both of which were increased by vegetation. Here, greater photolysis under vegetation arose from faster sedimentation and increased light penetration, despite shading. Management options for employing constructed wetlands to polish pesticide-contaminated agricultural runoff are discussed. The lack of easily fulfilled sub-models and data describing the effect of aquatic vegetation on water chemistry and sedimentation is also highlighted.     

The clearinghouse concept: a model for geospatial data centralization and dissemination in a disaster

The disaster clearinghouse concept originates with the earthquake community as an effort to coordinate research and data collection activities. Though prior earthquake clearinghouses are small in comparison to what was needed in response to Hurricane Katrina, these seminal structures are germane to the establishment of our current model. On 3 September 2005, five days after Katrina wrought cataclysmic destruction along the Gulf Coast, FEMA and Louisiana State University personnel met to establish the LSU GIS Clearinghouse Cooperative (LGCC), a resource for centralization and dissemination of geospatial information related to Hurricane Katrina. Since its inception, the LGCC has developed into a working model for organization, dissemination, archiving and research regarding geospatial information in a disaster. This article outlines the formation of the LGCC, issues of data organization, and methods of data dissemination and archiving with an eye towards implementing the clearinghouse model as a standard resource for addressing geospatial data needs in disaster research and management.     

Parcelization in rural agricultural and forested landscapes in Wisconsin, 1972–2007: evaluating multiple dimensions of human decision-making over time

Many land-use change studies have relied on geographical explanatory factors. Unfortunately, they are but a single perspective in the multidimensional process of human decision-making. This project was designed to model the social, economic, geographic, and regulatory factors at the most appropriate unit of analysis, the landowner. By examining parcelization, a window is opened into the antecedent event of land-use change. A logistic regression model determined the likelihood a tax parcel would split in three time periods between 1953 and 2007. Geographic variables showed expected relationships to a parcelization event, while economic and regulatory variables illustrated some unexpected relationships. Social variables demonstrated scale issues that challenged their efficacy. A temporal analysis showed that historic parcelization was explained more robustly than more contemporary parcelization. The results could indicate that contemporary parcelization is driven by new and more complex factors not yet represented in similar models.