Air-substrate mercury exchange associated with landfill disposal of coal combustion products

Previous laboratory studies have shown that lignite-derived fly ash emitted mercury (Hg) to the atmosphere, whereas bituminous- and subbituminous-derived fly ash samples adsorbed Hg from the air. In addition, wet flue gas desulfurization (FGD) materials were found to have higher Hg emission rates than fly ash. This study investigated in situ Hg emissions at a blended bituminous-subbituminous ash landfill in the Great Lakes area and a lignite-derived ash and FGD solids landfill in the Midwestern United States using a dynamic field chamber. Fly ash and saturated FGD materials emitted Hg to atmosphere at low rates (-0.1 to 1.2 ng/ m2hr), whereas FGD material mixed with fly ash and pyrite exhibited higher emission rates (approximately 10 ng/m2hr) but were still comparable with natural background soils (-0.3 to 13 ng/ m2hr). Air temperature, solar radiation, and relative humidity were important factors correlated with measured Hg fluxes. Field study results were not consistent with corresponding laboratory observations in that fluxes measured in the latter were higher and more variable. This is hypothesized to be partially an artifact of the flux measurement methods.     

Postnatal management of prenatally diagnosed abdominal masses and anomalies

Rapid advancement in fetal diagnostic imaging has increased our ability to diagnose a multitude of anomalies in the prenatal period. The purpose of this chapter is to review our current understanding of prenatally diagnosed intra-abdominal lesions, and describe the current guidelines for the postnatal management and subsequent outcome for these lesions. Copyright © 2008 John Wiley & Sons, Ltd.     

Greenhouse gas mitigation options in the Forest sector of Russia: National and project level assessments

Greenhouse gas (GHG) mitigation options in the Russian forest sector include: afforestation and reforestation of unforested/degraded land area; enhanced forest productivity; incorporation of nondestructive methods of wood harvesting in the forest industry; establishment of land protective forest stands; increase in stand age of final harvest in the European part of Russia; increased fire control; increased disease and pest control; and preservation of old growth forests in the Russian Far-East, which are presently threatened. Considering the implementation of all of the options presented, the GHG mitigation potential within the forest and agroforestry sectors of Russia is approximately 0.6–0.7 Pg C/yr or one half of the industrial carbon emissions of the United States. The difference between the GHG mitigation potential and the actual level of GHGs mitigated in the Russian forest sector will depend to a great degree on external financing that may be available. One possibility for external financing is through joint implementation (JI). However, under the JI process, each project will be evaluated by considering a number of criteria including also the difference between the carbon emissions or sequestration for the baseline (or reference) and the project case, the permanence of the project, and leakage. Consequently, a project level assessment must appreciate the near-term constraints that will face practitioners who attempt to realize the GHG mitigation potential in the forest and agroforestry sectors of their countries.     

A LOOK AT THE HUDSON RIVER ESTUARY1

This paper provides background information on the effect of tide waves upon the movement of water in the Hudson River estuary. Computations based on records from three continuous stage recorders and current-meter discharge measurements made throughout a tidal cycle show that peak discharge rates in the estuary at Poughkeep-sie may be as great as 500,000 cubic feet per second and that total daily tidal volumes as great as 20 billion cubic feet move in the estuary. Computation of water movement in the estuary requires precise field data and continued efforts are needed to perfect the data-collection system and the computation procedure in order to adequately define water movement in the Hudson estuary.     

Microtox assay to determine the toxicity of degradation products from degradable plastics

Six types of starch-polyethylene degradable plastics were evaluated for the release of water-soluble toxic compounds under accelerated degradation conditions. A plastic strip (2.5×15.2 cm) was placed in a 250-ml Erlenmeyer flask with 100 ml of ASTM type I water with or without trace element solutions and shaken at 65°C and 110 rpm for 20 weeks in replicates of two. High temperature was used to accelerate the oxidative degradation of polyethylene. Plastic degradation was measured by loss of tensile strength, percentage elongation, strain energy, and weight-average molecular weight. The most rapid period of polyethylene thermal degradation was complete for most materials by day 28. Ten-milliliter aqueous samples were removed from each flask at days 1, 7, 28, 56, 84, and 140 (water volumes were maintained at 100 ml with fresh type I water), filtered through glass filters, then evaluated by using the Microtox Toxicity Analyzer (Microbics Corporation, Carlsbad, CA). No water-soluble toxic compounds were detected during the period of rapid film degradation. Toxicity was observed at day 28 for one film and at day 84 for all films, which could possibly correlate with the release of small oxidative compounds such as formaldehyde and acetaldehyde. Because of the sensitivity of this assay, positive results must be confirmed by otherin vitro studies.Journal Paper No. J-14851 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa. Projects No. 2889 and 0178.     

SEQUENT PEAK PROCEDURE: MINIMUM RESERVOIR CAPACITY SUBJECT TO CONSTRAINT ON FINAL STORAGE1

ABSTRACT: When the sequent peak procedure is used to size a reservoir, two cycles of inflows and drafts are analyzed. The use of two cycles results in the identification of the minimum reservoir capacity which, when simulated with the design inflows and drafts, will not only meet demands, but will also result in a final storage which equals or exceeds the initial storage. Demonstration of optimality follows from consideration of a method which is equivalent to the sequent peak procedure.     

RHODAMINE WT DYE LOSSES IN A MOUNTAIN STREAM ENVIRONMENT1

ABSTRACT: A significant fraction of rhodamine WT dye was lost during a short term multitracer injection experiment in a mountain stream environment. The conservative anion chloride and the sorbing cation lithium were concurrently injected. In-stream rhodamine WT concentrations were as low as 45 percent of that expected, based on chloride data. Concentration data were available from shallow‘wells’dug near the stream course and from a seep of suspected return flow. Both rhodamine WT dye and lithium were nonconservative with respect to the conservative chloride, with rhodamine WT dye closely following the behavior of the sorbing lithium. Nonsorption and sorption mechanisms for rhodamine WT loss in a mountain stream were evaluated in laboratory experiments. Experiments evaluating nonsorption losses indicated minimal losses by such mechanisms. Laboratory experiments using sand and gravel size streambed sediments show an appreciable capacity for rhodamine WT sorption. The detection of tracers in the shallow wells and seep indicates interaction between the stream and the flow in the surrounding subsurface, intergravel water, system. The injected tracers had ample opportunity for intimate contact with materials shown in the laboratory experiments to be potentially sorptive. It is suggested that in the study stream system, interaction with streambed gravel was a significant mechanism for the attenuation of rhodamine WT dye (relative to chloride).     

A FIELD EVALUATION OF THE EFFECTS OF HEATED DISCHARGES ON FISH DISTRIBUTION1

ABSTRACT. Studies were conducted to determine the distribution of fish in the New and East Rivers in relation to thermal discharges from Appalachian Power Company's fossil fuel plant at Glen Lyn, Virginia. Over 15,300 specimens representing 41 species were collected with seines, electrogear and rotenone at six sampling locations from February, 1973 to October 1973. Sampling frequency was designed to evaluate the effects of ambient temperature upon preferred temperature. Diversity indices were calculated for each location. There was a slight decrease in the diversity indices for those stations located in the thermal discharge. Condition coefficients calculated for Notropis albeolus Jordan, Notropis rubellus Aqasaiz, Notropis spilopterus Cope, Ictalurus punctatus Rafinesque, and Etheostoma blennioides Rafuesque were found to be significantly (p =.05) lower in the thermal discharge for all species tested except E. blennioides. Temperatures were plotted against frequency of capture to determine a particular species temperature selection from field data and indicated that: (1) Some species avoided high temperatures (i.e., Curnpostoma anomalum Rafuesque). (2) Some species were attracted to high temperatures (i.e., Ictalurus punctatus). (3) Some species distribution was not effected by temperatures (i.e., Notropis spilopterus).