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31.
The diet of cage-farmed Atlantic salmon contains a range of trace metals, some of which have toxic properties, e.g. zinc, copper and cadmium. A survey of metal concentrations (ICP-MS analysis) in surface sediments of ca. 70 stations was carried out in both May and December 2000 around a Scottish fish farm. Additionally, at 13 stations on 2 orthogonal transects centered on the farm, sediments were analysed at 1cm intervals to 8 cm depth. Maximum concentrations in surface sediments were 921, 805 and 3.5 microg g(-1) for Zn, Cu and Cd, respectively, and were found at stations near the fish farm. The calculated losses from the farm (feed input minus fish output) were 87.0%, 4.3% and 14.0% of the background-corrected inventories for Zn, Cu and Cd, respectively, indicating that for Cu and Cd at least, the feed is not the only source. 相似文献
32.
Chun Wai Lee Dennis G. Tabor Kenneth A. Cowen 《Journal of Material Cycles and Waste Management》2008,10(1):38-45
The performance of four dioxin emission monitors, including two long-term sampling devices, the Dioxin-MonitoringSystem (DMS)
and AMESA (the adsorption method for sampling dioxins and furans), and two semireal-time continuous monitors, the resonance
ionization with multimirror photon accumulation time-of-flight mass spectrometer (RIMMPA-TOFMS) and the jet resonance-enhanced
multiphoton ionization (jet-REMPI) system were tested. A package boiler burning a simulated chlorinated hazardous waste was
used for a total of nine tests. Reference samples were collected during each test and analyzed for polychlorinated dibenzodioxins
and dibenzofurans (PCDDs/Fs) using gas chromatography mass spectrometry. The PCDD/F concentrations of the reference samples
measured by EPA Method 23 ranged from 0.9 to 6.0 ng toxic equivalence (TEQ)/dry standard cubic meter. The relative accuracies
achieved by DMS, AMESA, and jet-REMPI varied from 22.6% to 78.2%, with 100% data completeness. The RIMMPA-TOFMS produced no
quantifiable results due to various difficulties associated with the instrument during the testing. The two long-term samplers
were easy to install and operate and provided a cumulative, averaged emission for the sampling period. The operations of the
two semi-real-time continuous monitors were relatively complex, but one of them provided on-site, real-time data for PCDD/F
emissions from measurement of a TEQ correlative indicator compound. This article summarizes results from the individual Environmental
Technology Verification reports for the four dioxin monitors.
This work was presented, in part, at the Fourth International Conference on Combustion, Incineration/Pyrolysis and Emission
Control (i-CIPEC) 相似文献
33.
Kenneth R. Krach Benjamin R. Burns Baikun Li Alison Shuler Charles Cole Yuefeng Xie 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):369-378
Over three million dry metric tons of biosolids produced in the United States are land applied as Class B. Lime stabilization
is employed for biosolids treatment at approximately 20% of the wastewater treatment plants because it is a simple and inexpensive
process. During lime stabilization, the pH of sewage sludge is raised above 12 for pathogen inactivation and odor reduction.
Lime dose and mixing have been found to greatly reduce odor generation from lime stabilized biosolids. A better quality biosolids
product is less likely to create public opposition to land application programs. In this study, land application tests using
Class B biosolids were conducted in order to determine whether better mixing can reduce odor generation during the land application
of lime stabilized biosolids. The mixing quality of a treatment plant’s lime stabilized biosolids was improved by relocating
the lime addition point, which prolonged the mixing time and produced a better mixed biosolids product. Based on field observations
of land application, the poorly mixed biosolids were more odorous and offensive prior to incorporation. However, once incorporated
into the soil, there was no appreciable odor difference between the biosolids. Another land application study was conducted
to assess the odor of unincorporated Class A biosolids and compare it with incorporated Class A biosolids with the soil. 相似文献
34.
Kenneth R. Sheehan Michael P. Strager Stuart A. Welsh 《Environmental Modeling and Assessment》2013,18(2):209-219
Stream habitat assessments are commonplace in fish management, and often involve nonspatial analysis methods for quantifying or predicting habitat, such as ordinary least squares regression (OLS). Spatial relationships, however, often exist among stream habitat variables. For example, water depth, water velocity, and benthic substrate sizes within streams are often spatially correlated and may exhibit spatial nonstationarity or inconsistency in geographic space. Thus, analysis methods should address spatial relationships within habitat datasets. In this study, OLS and a recently developed method, geographically weighted regression (GWR), were used to model benthic substrate from water depth and water velocity data at two stream sites within the Greater Yellowstone Ecosystem. For data collection, each site was represented by a grid of 0.1 m2 cells, where actual values of water depth, water velocity, and benthic substrate class were measured for each cell. Accuracies of regressed substrate class data by OLS and GWR methods were calculated by comparing maps, parameter estimates, and determination coefficient r 2. For analysis of data from both sites, Akaike’s Information Criterion corrected for sample size indicated the best approximating model for the data resulted from GWR and not from OLS. Adjusted r 2 values also supported GWR as a better approach than OLS for prediction of substrate. This study supports GWR (a spatial analysis approach) over nonspatial OLS methods for prediction of habitat for stream habitat assessments. 相似文献
35.
Lai VW Kanaki K Pergantis SA Cullen WR Reimer KJ 《Journal of environmental monitoring : JEM》2012,14(3):743-751
Terrestrial snails are consumed by humans occasionally and they are an important food source for many creatures including fish and birds. Little is known about arsenic speciation in these gastropods, let alone life cycle variations. Here we report on the arsenic speciation in freshwater snails from Pender Island and Vancouver Island, B.C., Canada, which was determined on methanol/water extracts (43-59% extraction efficiency) by using high performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS) and HPLC-electrospray tandem mass spectrometry. The tetramethylarsonium ion, oxo-arsenosugars and thio-arsenosugars are the main arsenic species encountered. Arsenobetaine, which is commonly found in the marine environment, is minor. Live bearing snails Viviparidae sp. from Pender Island were maintained in aquaria and the arsenic speciation in the unborn, newly born, and adult animals was monitored. Oxo-arsenosugars predominate in the adults, whereas thio-arsenosugars seem to predominate in juveniles, suggesting that these arsenicals are snail metabolites. 相似文献
36.
Demonstrating Contaminant Degradation at an MGP Site With Metabolic Gas Flux and Radio Carbon Dating 下载免费PDF全文
Sean M. Carroll Aaron D. Peacock Julio Zimbron Kenneth N. Alepidis Jeffrey A. Clock 《补救:环境净化治理成本、技术与工艺杂志》2017,27(2):51-64
Obtaining lines of evidence indicating that contamination in sediment environments is degrading and being transformed to less toxic forms is an important component of building support for a monitored natural recovery remedy for contaminated sediments. This project was a field demonstration of manufactured gas plant contaminant degradation in river sediments using metabolic gas flux and was performed in an urban area section of a river in northeastern Indiana. CO2 sorbent traps were deployed to measure CO2 flux from the river sediments. Sediment samples were collected and analyzed for polycyclic aromatic hydrocarbon (PAH) concentrations and for microbial community composition using molecular techniques. The results showed that the deployment was successful, measuring CO2 flux at all sediment locations and demonstrating that microbial contaminant degrading activity was occurring in the sediments. Radio carbon dating showed a significant portion of the CO2 being generated (approximately 19–27 percent) was the result of fossil fuel degradation. Molecular results showed that the microbial community consisted of phylotypes known to be associated with monocyclic aromatic and PAH degradation. ©2017 Wiley Periodicals, Inc. 相似文献
37.
Kharuk Viacheslav I. Im Sergei T. Petrov Ilya A. Dvinskaya Mariya L. Fedotova Elena V. Ranson Kenneth J. 《Regional Environmental Change》2017,17(3):803-812
Regional Environmental Change - Increased dieback and mortality of “dark needle conifer” (DNC) stands (composed of fir (Abies sibirica), Siberian pine (Pinus sibirica) and spruce (Picea... 相似文献
38.
Kenneth J. Tobin Marvin E. Bennett 《Journal of the American Water Resources Association》2017,53(3):593-604
Historically, many watershed studies have been based on using the streamflow flux, typically from a single gauge at the basin's outlet, to support calibration. In this setting, there is great potential for equifinality of parameters during the optimization process, especially for parameters that are not directly related to streamflow. Therefore, some of the optimal parameter values achieved during the autocalibration process may be physically unrealistic. In recent decades a vast array of data from land surface models and remote sensing platforms can help to constrain hydrologic fluxes such as evapotranspiration (ET). While the spatial resolution of these ancillary datasets varies, the continuous spatial coverage of these gridded datasets provides flux measurements across the entire basin, in stark contrast to point‐based streamflow data. This study uses Global Land Evaporation: the Amsterdam Model data to constrain Soil and Water Assessment Tool parameter values associated with ET to a more physically realistic range. The study area is the Little Washita River Experimental Watershed, in southern Oklahoma. Traditional objective metrics such as the Nash‐Sutcliffe coefficients record no performance improvement after application of this method. However, there is a dramatic increase in the number of days with receding flow where simulations match observed streamflow. 相似文献
39.
40.
Kenneth T. Fellows Michael J. Pilat 《Journal of the Air & Waste Management Association (1995)》2013,63(6):887-893
The sorption of hydrochloric acid (HCI) by thermally decomposed sodium bicarbonate (NaHCO3) was investigated using a fixed-bed reactor containing sorbent particles dispersed in a bed of spherical glass beads. The gas flow rate (68° F and 760 mm Hg) was 0.039 cfm (1.1 liter/min) and the bed had a cross-sectional area of 0.0055 sq. ft. (5.1 sq. cm). The influence of particle diameter (10, 45 and 163 μm), temperature (225, 275, 375, 455, and 550° F), superficial gas velocity (11 and 21 fpm at reactor conditions, 375° F), and Inlet HCI gas concentration (415 ppm and 760 ppm in N2, 275 and 455° F) were studied. Results showed that HCI sorption increased strongly with increasing temperature but was only weakly dependent on particle diameter, superficial gas velocity, and HCI gas concentration. 相似文献