The adsorption characteristics of heavy metals by various particle sizes of MSWI bottom ash

The incineration rate of municipal solid waste (MSW) has been increased because of difficulty in securing a proper disposal site for MSW in Korea. The advantage of incineration is reduction of the volume of waste; however, significant amounts of bottom ash and fly ash were generated in the incineration process. Their treatment has attracted growing interest because of the potential toxicity of hazardous heavy metals. Generally, heavy metals are less released from bottom ash than from fly ash. In this study the adsorption characteristics of heavy metals were investigated using various particle sizes of MSWI bottom ash. Since bottom ash has a broad particle size distribution, it was sieved to size classes of +20, -20, -48, -80, -100 mesh. Cation exchange capacity (CEC) was analyzed by the ammonium acetate method to evaluate the potential as an adsorbent. The CEC values and surface areas increase as the range of particle size becomes finer. The adsorption experiment was conducted using synthetic (Cu and Ni) and plating rinse water as a function of reaction time (10-180 min), liquid/solid ratio (2-100) and particle size (+20 to -100 mesh), respectively. The adsorption rate increased with decreasing particle size and with increasing liquid/solid ratio; however, the removal efficiency of Cu was higher than that of Ni. In the case of plating rinse water, the adsorption rate decreased sharply at high liquid/solid ratio, and it showed over 80% of adsorption rates for Cu and Ni at an initial pH of 3.     

Life cycle assessment of selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator

Selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator was investigated using LCA. The relationship between NO_x-cleaning and ammonia dosage was measured at the plant. Un-reacted ammonia - the ammonia slip - leaving the flue-gas cleaning system adsorbed to fly-ash or in the effluent of the acidic scrubber was quantified from the stoichiometric reaction of NO_x and ammonia assuming no other reaction products was formed. Of the ammonia slip, 37% was associated with the fly-ash and 63% was in the effluent of the acidic scrubber. Based on NO_x-cleaning efficiency, the fate of the ammonia slip as well as the environmental impact from ammonia production, the potential acidification and nutrient enrichment from NO_x-cleaning was calculated as a function of ammonia dosage. Since the exact fate of the ammonia slip could not be measured directly, a number of scenarios were set up ranging from “best case” with no ammonia from the slip ending up in the environment to “worst case” where all the ammonia slip eventually ended up in the environment and contributed to environmental pollution. In the “best case” scenario the highest ammonia dosage was most beneficial demonstrating that the environmental load associated with ammonia production is of minor importance. In contrast, in a “worst case” scenario” NO_x-cleaning using SNCR is not recommendable at all, since the impacts from the ammonia slip exceed the saved impacts from the NO_x removal. Increased dosage of ammonia for removal of NO_x is recommendable as long as less than 10-20% of the ammonia slip to the effluent of the acidic scrubber ends up in the environment and less than 40% of the slip to the fly-ash ends up in the environment. The study suggests that the actual fate of the ammonia slip is crucial, but since the release of the ammonia may take place during transport and at the facilities that treat the wastewater and treat the fly-ash this factor depends strongly on local conditions and may be hard to determine. Thus, LCA-modeling proved useful in assessing the balance between ammonia dosage and NO_x-removal in flue-gas cleaning from waste incineration.     

Evaluation of food waste disposal options by LCC analysis from the perspective of global warming: Jungnang case, South Korea

The costs associated with eight food waste disposal options, dry feeding, wet feeding, composting, anaerobic digestion, co-digestion with sewage sludge, food waste disposer, incineration, and landfilling, were evaluated in the perspective of global warming and energy and/or resource recovery. An expanded system boundary was employed to compare by-products. Life cycle cost was analyzed through the entire disposal process, which included discharge, separate collection, transportation, treatment, and final disposal stages, all of which were included in the system boundary. Costs and benefits were estimated by an avoided impact. Environmental benefits of each system per 1 tonne of food waste management were estimated using carbon prices resulting from CO(2) reduction by avoided impact, as well as the prices of by-products such as animal feed, compost, and electricity. We found that the cost of landfilling was the lowest, followed by co-digestion. The benefits of wet feeding systems were the highest and landfilling the lowest.     

Evaluation of the potential methane yield of industrial wastewaters used in bioreactor landfills

To increase the moisture content of waste disposed in a bioreactor landfill, it is critical to secure the moisture source. In this study, industrial wastewater was evaluated as a potential moisture source for a bioreactor landfill with respect to the impact on methane generation. Industrial wastewater samples were collected from fishery, brewery and dairy industries. These samples were tested for basic water chemistry parameters, heavy metals, and methane generation using the regular and modified biochemical methane potential (BMP) assays. Despite high sodium and total phosphate concentrations in the fishery wastewater, a significant methane yield was observed (0.313?m³ CH₄/kg COD). However, a relatively large amount of fishery wastewater added at the phase of methane generation acceleration adversely affected microbial activity. Samples from the brewery and dairy wastewater did not indicate significant inhibitory effects on methane generation in either the regular or the modified BMP assay. This study demonstrates the utility of wastewater as an alternative to traditional moisture sources when used to enhance methane production in a bioreactor landfill.     

Degradation of lignocellulosic materials under sulfidogenic and methanogenic conditions

Biochemical methane potential (BMP) assays, typically used to assess anaerobic biodegradability of liquid wastes with added nutrients and bacteria, were adapted to compare hydrolysis of lignocellulosic material under sulfidogenic and methanogenic environments. A method based on selective inhibition of microorganism activity, by 3% toluene, was used to measure the hydrolysis rate of lignocellulosic material and the accumulation of sugar. The neutral sugars, galactose, glucose, and xylose, which were released from lignocellulosic material such as office paper and newspaper in the presence 3% toluene, clearly accumulated over time under sulfidogenic conditions. The accumulation rates of sugars, glucose, and xylose, were higher in the sulfidogenic condition than in the methanogenic condition, indicating a faster degradation of lignocellulosic materials under the sulfidogenic condition.     

The characteristics of fatal occupational injuries in Korea’s construction industry, 1997–2004

This study is aimed at exploring the characteristics of fatal occupational injuries in Korea’s construction industry and comparing the causes in various occupations within that industry. There were 10,276 fatal occupational injury victims in Korea over 8 years (1997–2004). The mortality risk due to injuries in construction and non-construction industries was calculated, and their causes were compared. The number of victims of fatal occupational injuries in the construction industry was 4333 (42.2% of the total fatal occupational injuries), and the 1 year mortality risk was higher (23.7/100,000 persons) than in non-construction industries (10.4). Falling was the most frequent (52.7%) cause of fatal injuries. In addition, deaths due to structural collapse and electric shock were significantly higher than in other industries. When the distribution of the causal factors in various occupations within the construction industry was investigated, some factors appeared more frequently in certain occupations than in others. As the construction industry encompasses a large proportion of occupational injuries, a reduction in this field alone will substantially contribute to an overall reduction of occupational injuries in Korea. Further research for effective prevention is needed.     

Arsenite oxidation by <Emphasis Type="Italic">Alcaligenes</Emphasis> sp. strain RS-19 isolated from arsenic-contaminated mines in the Republic of Korea

Arsenite [As(III)]-oxidizing bacteria play important roles in reducing arsenic [As] toxicity and mobility in As-contaminated areas. As-resistant bacteria were isolated from the soils of two abandoned mines in the Republic of Korea. The isolated bacteria showed relatively high resistances to As(III) up to 26 mM. The PCR-based 16S rRNA analysis revealed that the isolated As-resistant bacteria were close relatives to Serratia marcescensa, Pseudomonas putida, Pantoea agglomerans, and Alcaligenes sp. Among the five As-resistant bacterial isolates, Alcaligenes sp. strain RS-19 showed the highest As(III)-oxidizing activity in batch tests, completely oxidizing 1 mM of As(III) to As(V) within 40 h during heterotrophic growth. This study suggests that the indigenous bacteria have evolved to retain the ability to resist toxic As in the As-contaminated environments and moreover to convert the species to a less toxic form [e.g., from As(III) to As(V)] and also contribute the biogeochemical cycling of As by being involved in speciation of As.     

Unraveling the impact of workforce age diversity on labor productivity: The moderating role of firm size and job security

Previous literature has suggested both positive and negative effects of age diversity on labor productivity: positive because of the potential knowledge complementarities between employees of different ages and negative because of the age‐related value differences that might reduce cohesion and cooperation, hampering firm performance. Using a Belgian sample of 5892 organizational observations (2008–2011), we unraveled these countervailing effects in two ways. First, we built on prior studies to suggest that the effect of age diversity depends on the particular shape of the age distribution: positive when it is heterogeneous (i.e., variety) and negative when it is polarized (i.e., polarization). This was supported by our findings. Second, we explored the moderating impact of two contextual contingencies, firm size and job security. As expected, the positive effect of age variety is reinforced in large firms and in firms where job security is high. Although firm size also emphasizes the negative effect of age polarization on productivity, job security, unexpectedly, does not moderate this relationship. Our study offers a valuable contribution to the literature as it reveals the boundary conditions of the competing implications of age diversity and, thus, allows one to account for the inconclusive findings reported in previous literature. Copyright © 2015 John Wiley & Sons, Ltd.     

含多种分布式电源的微电网分层控制策略

随着分布式电源接入微电网数量的增加,微电网系统的稳定性受到了很大的影响;微电源的运行特性及控制方法、微电源的接人点和容量、微电网运行方式和控制方法、电力电子装置、储能设备和负荷特性等都会影响到电能质量。为了改善微电网的电能质量,提出了包括上层中心控制器及下层分布式电源信息交互的微电网分层控制策略。微电网中的分布式电源控制由下垂控制、功率控制、电压和电流控制组成。通过Matlab/simulink仿真,对微电网运行中各分布式电源的功率、电压和频率的变化规律进行了分析。仿真结果表明:分层控制策略能使各分布式电源之间较好地协调,满足了改善电能质量的要求。     

Effects of Information on Perceived Crowding and Encounter Norms

People receive information about visiting places from a variety of sources, and it is important to understand how information affects recreation experiences. This study examines how different information treatments describing a recreation place influence perceived crowding and encounter norms. The study location was the Jungmoeri area of Mudeungsan Provincial Park (MPP) in Korea. Data were collected from 50 college students utilizing a series of simulated moving pictures in a laboratory setting. Respondents were given information describing three different types of conditions and experiences (nature preserve, transition/buffer, and developed area), plus a no information control. Results showed that information influenced perceived crowding and encounter norms. For the range of encounter numbers depicted in the photos, the nature preserve treatment produced higher crowding ratings and lower tolerances for encounters, the developed area treatment produced lower crowding ratings and higher tolerances, and the transition/buffer and the control were in between. Information treatments also influence the perceived importance of encounter numbers, and importance was highest for the nature preserve. Management implications are discussed.