Comparative studies on toluene removal and pressure drop in biofilters using different packing materials

To select the best available packing material for malodorous organic gases such as toluene and benzene, biofilter performance was compared in biofilters employed different packing materials including porous ceramic (celite), Jeju scoria (lava), a mixture of granular activated carbon (GAC) and celite (GAC/celite), and cubic polyurethane foam (PU). A toluene-degrading bacterium, Stenotrophomonas maltophilia T3-c, was used as the inoculum. The maximum elimination capacities in the celite, lava, and GAC/celite biofilters were 100, 130, and 110 gm(-3) hr(-1), respectively. The elimination capacity for the PU biofilter was approximately 350 g m(-3) hr(-1) at an inlet loading of approximately 430 g m(-3) hr(-1), which was 2 to 3.5 times higher than for the other biofilters. The pressure drop gradually increased in the GAC/ celite, celite and lava biofilters after 23 day due to bacterial over-growth, and the toluene removal efficiency remarkably decreased with increasing pressure drop. Backwashing method was not effective for the control of biomass in these biofilters. In the PU biofilter however, backwashing allowed maintenance of a pressure drop of 1 to 3 mm H2O m(-1) and a removal efficiency of > 80%, indicating that the PU was the best packing material for toluene removal among the packing materials tested.     

Reductive dechlorination and biodegradation of 2,4,6-trichlorophenol using sequential permeable reactive barriers: laboratory studies

The reductive dechlorination and biodegradation of 2,4,6-trichlorophenol (2,4,6-TCP) was investigated in a laboratory-scale sequential barrier system consisting of a chemical and biological reactive barrier. Palladium coated iron (Pd/Fe) was used as a reactive barrier medium for the chemical degradation of 2,4,6-TCP, and a sand column seeded with anaerobic microbes was used as a biobarrier following the chemical reactive barrier in this study. Only phenol was detected in the effluent from the Pd/Fe column reactor, indicating that the complete dechlorination of 2,4,6-TCP was achieved. The residence time of 30.2-21.2h was required for the complete dechlorination of 2,4,6-TCP of 100 mg l(-1) in the column reactor. The surface area-normalized rate constant (k(SA)) is 3.84 (+/-0.48)x10(-5)lm(-2)h(-1). The reaction rate in the column tests was one order of magnitude slower than that in the batch test. In the operation of the biobarrier, about 100 microM of phenol was completely removed with a residence time of 7-8d. Consequently, the dechlorination prior to biodegradation turns out to increase the overall treatability. Moreover, the sequential permeable reactive barriers, consisting of iron barrier and biobarrier, could be recommended for groundwater contaminated with toxic organic compounds such as chlorophenols.     

Assessment of water quality and trace metal contaminations in Mondolkiri province in the Northeastern part of Cambodia

Environmental Geochemistry and Health - The aim of the present study is to investigate water quality and potential trace metal contaminations in the Northeastern part of Cambodia. Tube well...     

Drying characteristics of thickened sewage sludge in oil vacuum evaporation system

Journal of Material Cycles and Waste Management - In the current work, drying characteristics of thickened sludge was investigated with respect to drying conditions in oil vacuum evaporation...     

First-trimester screening for Down syndrome; the role of nasal bone assessment in the Korean population

Objectives The aim of this study was to evaluate the role of nasal bone assessment in first-trimester screening for Down syndrome (DS) in the Korean population. Methods From July 2004 to March 2006, we prospectively evaluated the fetal nasal bones at 11–14 weeks' gestation in the Korean population. Results A successful evaluation was possible in 6490 of 6787 fetuses (95.6%). Absent, hypoechoic, and short nasal bones were seen in 4 (26.7%), 4 (26.7%), and 1 (6.7%) of 15 fetuses with DS, respectively, whereas in 5 (0.1%), 11 (0.2%), and 246 (3.8%) of 6456 normal fetuses. The incidence of absent and hypoechoic nasal bone showed significant differences between normal fetuses and fetuses with DS (P < 0.0005, both). Screening for DS using an absent or hypoechoic nasal bone resulted in a sensitivity of 53.3%, a specificity of 99.8%, a positive likelihood ratio of 215.2, and a negative likelihood ratio of 0.5. Conclusion Our study showed that nasal bone abnormality at 11–14 weeks of gestation had a high association with DS in the Korean population. This suggests that nasal bone assessment can be used to supplement the current first-trimester screening for DS in the Korean population. Copyright © 2007 John Wiley & Sons, Ltd.     

US Energy Conservation and Efficiency: Benefits and Costs

With increased energy conservation plus the adoption of diverse energy efficient technologies, the US economy could save about 32 quads or about 33% of its current energy consumption, if sound conservation energy use policies were implemented over approximately 10 years. This potential of 32 quads is slightly greater than the current US oil imports. The systems that have the greatest potential to provide major energy savings are transportation, residential energy use, and the food system. Not only saving energy has merit in itself, but it would save US citizens approximately $438 billion per year, helping support the US economy, a high standard of living, and energy security. In addition, this analysis suggests that reducing the $40 billion in taxpayer money spent on subsidies of the energy industries would further increase conservation.     

Soil- and surfactant-enhanced reductive dechlorination of carbon tetrachloride in the presence of Shewanella putrefaciens 200

Sorption of organic contaminants to soils has been shown to limit bioavailability and biodegradation in some systems. Use of surfactants has been proposed to reverse this effect. In this study, the effects of a high organic carbon content soil and a nonionic surfactant (Triton X-100) on the reductive dechlorination of carbon tetrachloride (CCl₄) were examined in anaerobic systems containing Shewanella putrefaciens. Although more than 70% of the added CCl₄ was sorbed to the soil phase in these systems, the reductive dechlorination of CCl₄ was not diminished. Rather, rates of CCl₄ dechlorination in systems containing soil were enhanced relative to systems containing non-sorptive sand slurries. This enhancement was also observed in sterile soil slurries to which a chemical reductant, dithiothreitol was added. It appears that the organic soil used in these experiments contains some catalytic factor capable of transforming CCl₄ in the presence of an appropriate chemical or microbial reductant. The addition of Triton X-100 to sand and soil slurries containing S. putrefaciens resulted in increased CCl₄ degradation in both systems. The effect of Triton could not be explained by: (i) surfactant induced changes in the distribution of CCl₄, (i.e. decreased sorption) or the rate of CCl₄ desorption; (ii) a direct reaction between Triton and CCl₄; or (iii) increased cell numbers resulting from use of the surfactant as a substrate. Rather, it appears that Triton X-100 addition resulted in lysis of bacterial cells, a release of biochemical reductant, and enhanced reductive transformation of CCl₄. These results provide insights to guide the development of more effective direct or indirect bioremediation strategies.     

Decision-tree and rule-induction approach to integration of remotely sensed and GIS data in mapping vegetation in disturbed or hilly environments

The integration of Landsat TM and environmental GIS data sets using artificial intelligence rule-induction and decision-tree analysis is shown to facilitate the production of vegetation maps with both floristic and structural information. This technique is particularly suited to vegetation mapping in disturbed or hilly environments that are unsuited to either conventional remote sensing methods or GIS modeling using environmental data bases.     

A DISTRIBUTED DYNAMIC WATERSHED MODEL1

ABSTRACT: A distributed watershed model was developed to mathematically simulate overland and channel flow for a single-event storm. The modeled watersheds in the study were subdivided into rectangular grid elements. All hydrologically significant parameters, such as land slope, rainfall and precipitation excess, were assumed to be uniform within each element. The Green-Ampt method was adopted to generate precipitation excess for each element during the simulation period. A two-dimensional diffusion wave model was used for overland flow routing and an iterative Alternative Direction Implicit scheme was used to solve the simultaneous overland flow equations. Once the overland flow became inflow to the channel, a one-dimensional dynamic wave flood routing technique, based on a four-point, implicit, non-linear finite difference solution of the St. Venant equation of unsteady flow, was applied. A limited number of comparisons were made between simulated and observed hydrographs for areas of about one square mile. Given the appropriate parameters, the model was able to accurately simulate runoff for single-event storms. This paper describes a distributed watershed model developed to simulate overland and channel flow. Comparisons were made between simulated and observed hydrographs for three watersheds. The model was able to accurately simulate the runoff for single-event storms using 61-m by 61-m (200 ft by 200 ft) watershed grid elements.