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991.
Sang-Won Park Sung-Kuk Kim Jeong-Bae Kim Sung-Woo Choi Hilary I. Inyang Shuzo Tokunaga 《Water, Air, & Soil Pollution: Focus》2006,6(1-2):97-110
Halogenated aliphatic compounds (HACs) can be reduced by iron sulfides in aqueous systems. Generally, the thermodynamics and
kinetics of dehalogenation reactions are controlled by the mineralogical and particle surface characteristics of the iron
sulfide, the composition of the HAC and reaction conditions such as component concentrations, pH and Eh. In this theoretical
and experimental investigation of CCl4 and C2Cl6 reduction by FeS and FeS2, the roles of hydrophobic and hydrophilic sites on the iron sulfides were analyzed. Experimental data obtained through zeta
potential measurements, were used along with the Gouy-Chapman model and the simple two-layer surface complexation model to
relate iron sulfide surface hydroxyl densities to the degree of HAC dehalogenation. The surface hydroxyl site densities of
FeS and FeS2 were found to be 0.11 sites/nm2 and 0.21 sites/nm2, respectively. During the dehalogenation reaction process, CCl4 was found to decrease to its first intermediate product CHCl3 within the first 20 hours followed by a slower process of conversion to CH2Cl2. The results also show that FeS is less hydrated (more hydrophobic) than FeS2. For CCl4 and C2Cl6, FeS is a better dehalogenator than FeS2. These results imply that particle surface hydrophobicity is a critical factor in surface-mediated dehalogenation of chlorinated
compounds. 相似文献
992.
Low-level liquid borate wastes have been immobilized with paraffin wax using a concentrate waste drying system (CWDS) in Korean nuclear power plants. The possibility for improving chemical durability of paraffin waste form was suggested in this study. A small amount of low density polyethylene (LDPE) was added to increase the leaching resistance of the existing paraffin waste form. The influence of LDPE on the leaching behavior of waste form was investigated by performing leaching test according to ANSI/ANS-16.1 procedure during 325 days. It was observed that the leaching of nuclides immobilized within paraffin waste form made a marked reduction although little content of LDPE was added to waste form. The acceptance criteria of paraffin waste form associated with leachability index (LI) and compressive strength after the leaching test were fully satisfied with the help of LDPE. 相似文献
993.
Kim N. Dirks Murray D. Johns John E. Hay Andrew P. Sturman 《Atmospheric environment (Oxford, England : 1994)》2002,36(39-40)
Carbon monoxide monitoring using continuous samplers is carried out in most major urban centres in the world and generally forms the basis for air quality assessments. Such assessments become less reliable as the proportion of data missing due to equipment failure and periods of calibration increases. This paper presents a semi-empirical model for the prediction of atmospheric carbon monoxide concentrations near roads for the purpose of interpolating missing data without the need for any traffic or emissions information. The model produces reliable predictions while remaining computationally simple by being site-specifically optimized. The model was developed for, and evaluated at, both a suburban site and an inner city site in Hamilton, New Zealand. Model performance statistics were found to be significantly better than other simple methods of interpolation with little additional computational complexity. 相似文献
994.
Pienkoß Fabian Abis Marco Bruno Martina Grönholm Raul Hoppe Michel Kuchta Kerstin Fiore Silvia Simon Franz-Georg 《Journal of Material Cycles and Waste Management》2022,24(1):364-377
Journal of Material Cycles and Waste Management - This work is aimed at exploring the recovery of heavy metals from the fine fraction of solid waste incineration bottom ash. For this study,... 相似文献
995.
Hanedar Asude Çifçi Deniz İzlen Zafer Nur Görgün Erdem 《Journal of Material Cycles and Waste Management》2022,24(5):1760-1767
Journal of Material Cycles and Waste Management - In this study, the amount of medical waste generated in a high-populated city in Turkey between January 2018 and August 2021 was evaluated, and the... 相似文献
996.
Allan Gomez-Flores Gukhwa Hwang Sadia Ilyas Hyunjung Kim 《Frontiers of Environmental Science & Engineering》2022,16(3):31
997.
Gardia-Parège Caroline Kim Tiam Sandra Budzinski Hélène Mazzella Nicolas Devier Marie-Hélène Morin Soizic 《Environmental science and pollution research international》2022,29(20):29368-29381
Environmental Science and Pollution Research - Effect-directed analysis (EDA) aims at identifying the compound(s) responsible for toxicity in a complex environmental sample where several dozens of... 相似文献
998.
Lwin Chaw Su Kim Young-Nam Lee Mina Kim Kwon-Rae 《Environmental science and pollution research international》2022,29(42):62807-62821
Environmental Science and Pollution Research - In anthropogenic soils, there have been relatively limited studies focusing on Cr and Ni contaminants because they exhibit less toxic effects to... 相似文献
999.
Kim Young-Nam Lee Keum-Ah Lee Mina Kim Kwon-Rae 《Environmental science and pollution research international》2022,29(58):87555-87567
Environmental Science and Pollution Research - Globally, various types of soil amendments have been used to improve the fertility and quality of soils in agricultural lands. In heavy metal(loid)... 相似文献
1000.
Partial migration is a common phenomenon among many animals and occurs in many types of ecosystems. Understanding the mechanisms behind partial migration is of major importance for the understanding of population dynamics and, eventually, ecosystem processes. We studied the effects of food availability on the seasonal partial migration of cyprinid fish from a lake to connected streams during winter by the use of passive telemetry. Fish with increased access to food were found to migrate in higher proportion, earlier in the season, and to reside in the streams for a longer period compared to fish with decreased access to food. Furthermore, fewer unfed migrants returned to the lake, indicating higher overwinter mortality. Our results suggest that individual fish trade off safety from predation and access to food differently depending on their body condition, which results in a condition-dependent partial migration. Hence, our main conclusion is that individual decision-making is based on assessment of own condition which offers a mechanistic explanation to partial migration. Moreover, this may be of high importance for understanding population responses to environmental variation as well as ecosystem dynamics and stability. 相似文献