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61.
Analysis of chlorinated paraffins in cutting fluids and sealing materials by carbon skeleton reaction gas chromatography 总被引:2,自引:0,他引:2
Chlorinated paraffins (CPs) pose a major risk in the environment, due to their wide application, to their persistence, to their carcinogenic potential, and in view of the fact, that they cannot be easily identified. Various commercial cutting fluids and sealing materials were analysed for CPs with carbon skeleton reaction gas chromatography (GC) and flame ionization detection. CPs are simultaneously dechlorinated and hydrogenated to the corresponding alkanes with Pd catalyst material in the GC injector. With this method, the carbon chain length of commercial technical CPs was determined. In six of sixteen sealing materials we found five short and one medium chain length polychlorinated paraffins in percentages of 9-16% (w/w). In five cutting fluids we found predominantly medium to long chain length chloroparaffins with percentages of 2.5-31% (w/w), only one fluid contained short chain CPs. 相似文献
62.
Jeong-Ha Yoo Sung-Woo Shin Jong Soo Kim Chang-Bae Kim Jong-Sung Kim Sung-Cheol Koh 《Journal of environmental science and health. Part. B》2013,48(4):373-379
A new differential display-polymerase chain reaction (PCR) method based on annealing control primers was used to screen and identify potential biomarkers from differentially expressed genes (DEGs) in medaka exposed to sub-lethal concentration of diazinon (100 ppb). Among the differentially expressed genes identified, the majority were in functional categories of protein biosynthesis, transport and metabolism according to the gene ontology classification. The differential expression of ribosomal protein genes was quantified by real time PCR. The genes encoding ribosomal proteins including L3 and S17 were selected as potential biomarkers for diazinon exposure in medaka fish. 相似文献
63.
Santosh Kumar Mohmmad Y. Wani Joonseok Koh João M. Gil Abilio J.F.N. Sobral 《环境科学学报(英文版)》2018,30(7):77-84
One of today's major challenges is to provide green materials for a cleaner environment. We have conducted studies on carbon dioxide(CO2) adsorption and conversion to valuable products by an ecofriendly approach based in chitosan/graphene oxide(CSGO) nanocomposite film. Rheological behavior indicates that the CSGO has a better solvation property than the pure chitosan. An adsorption capacity of 1.0152 mmol CO_2/g of CSGO nanocomposite at4.6 bar was observed. The catalytic behavior of the CSGO nanocomposite in the presence of tetra-n-butylammonium iodide(n-Bu4 NI) as co-catalyst was evaluated for the cycloaddition of CO_2 to epoxides, to give cyclic carbonates, in the absence of any solvent. These results strongly suggest that the CSGO nanocomposite may open new vistas towards the development of ecofriendly material for catalytic conversion and adsorption of CO_2 on industrial scale. 相似文献
64.
Birds defend oil palms from herbivorous insects. 总被引:3,自引:0,他引:3
Lian Pin Koh 《Ecological applications》2008,18(4):821-825
Top-down forces are expected to be important in regulating herbivore populations in most agricultural systems where primary productivity is high and species diversity is low. Under such conditions, trophic cascades are predicted to occur when predator populations are reduced or removed. Studies on how predator removal indirectly affects herbivory rates in agricultural systems are lacking. Through a bird-exclosure experiment, I test the hypothesis that insectivorous birds indirectly defend oil palms (Elaeis guineensis) from herbivorous insects. Results show that bird exclusion significantly increased herbivory damage to oil palms, and that the size of this exclusion effect increased with bird density, although the latter result was not statistically significant. These findings suggest that insectivorous birds deliver a natural pest control service for oil palm agriculture, which is important not only for the direct benefits it delivers for human welfare, but also in strengthening the economic justifications for conserving the remaining natural habitats and biodiversity in agricultural landscapes. 相似文献
65.
——中印合作可以降低生物多样性损失、减轻气候变化并减少森林砍伐。中国和印度这两个新兴的世界经济大国将对21世纪世界环境发挥重要甚至主导作用。在未来几年内,两国的经济增长率预期将维持8%~9%。在世界很多国家出现经济危机情况下,中印两国2009年仍实现了国内生产总值高增长(中国:8.4%,印度:6.2%,世 相似文献
66.
Distribution of organochlorine pesticides in sediments from Kyeonggi Bay and nearby areas, Korea 总被引:13,自引:0,他引:13
The residues of oragnochlorine pesticides (OCPs) in 62 sediments from Kyeonggi Bay and nearby areas in the west coast of Korea were determined. The concentrations of chlordanes (CHLs) and DDTs showed a distinctive gradient of contamination between inner and outer sites of Incheon North Harbor (INH), whereas hexachlorocyclohexanes (HCHs) were uniformly distributed at most sites studied. The distribution of CHLs and DDTs was strongly correlated with total organic carbon contents in sediments while HCH residue levels were independent. Relationship between contaminant's concentration and environmental factors was analyzed by principal component analysis. Distribution patterns of T-CHLs, T-DDTs, and TOC were similar while those of T-HCHs, mud content, and grain size were similar. The notable contamination by CHLs and DDTs was found in INH where these levels were one or two orders of magnitude higher than other sites. The dominant OCPs in sediments were beta-HCH among HCH compounds, trans-chlordane among CHL compounds, and p,p'-DDD among DDT compounds. The higher concentrations and compositional pattern of OCPs in INH sediments indicate that INH is in the vicinity of the source. 相似文献
67.
Leong Seng-Yi Lee Siang-Yin Koh Thiam-Young Ang Desmond Teck-Chye 《Journal of Material Cycles and Waste Management》2023,25(1):37-51
Journal of Material Cycles and Waste Management - Excessive accumulation of rubber waste necessitates the need to revisit the effectiveness of the existing rubber waste management system. This... 相似文献