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21.
Patrícia Moraes Sinohara Souza Ana Rita Morales Maria Aparecida Marin-Morales Lucia Helena Innocentini Mei 《Journal of Polymers and the Environment》2013,21(3):738-759
The concern related to solid waste increases efforts to develop products based on biodegradable materials. At present, PLA has one of the highest potentials among biopolyesters, particularly for packaging. However, its application is limited in some fields. In order to optimize PLA properties, organo-modified montmorilonites have been extensively used to obtain nanocomposites. Although PLA nanocomposites studies are widely reported in the literature, there is still few information about the influence of organoclays on de biodegradation process, which is a relevant information, since one of the main purposals related to the final disposal of biopolymers as PLA is composting. Besides, in the last years some research has been conducted in order to evaluate the potential toxicity of montmorilonite, unmodified or organo-modified. Since the use of montmorilonite is expanding in different applications, human exposure and risk assessment are important issues to be investigated. In this context, this review intends to compile available information related to common organoclays used for PLA nanocomposites, its properties, biodegradation analysis and potential toxicity evaluation of nanocomposites, focused on montmorilonite as filler. Two issues of relevance were pointed out. The first is food safety and quality, and the second consideration is the environmental effect. 相似文献
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The Power of Innovation and Strategic Sustainability Positioning: A Survey of the Mining Sector in Brazil 下载免费PDF全文
Luciana Aparecida Barbieri da Rosa Clandia Maffini Gomes Jordana Marques Kneipp Ana Paula Perlin 《环境质量管理》2015,25(2):47-62
This study investigates the relationship between the power of innovation and the sustainability strategies of companies involved in the minerals extraction sector in Brazil. The study included companies associated with the Brazilian Mining Institute, and it used research surveys to gather data. Analysis of the survey data revealed that companies with highly intensive characteristics in regard to innovation and environmental activities (environmental management activities) also display offensive, or proactive, strategies for pursuing sustainability. 相似文献
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Silva Neicí Cáceres Poetini Márcia Rósula Bianchini Matheus Chimelo Almeida Francielli Polet Dahle Mustafá Munir Mustafa Araujo Stífani Machado Bortolotto Vandreza Cardoso Musachio Elize Aparecida Santos Ramborger Bruna Piaia Novo Diogo La Rosa Roehrs Rafael Mesko Marcia Foster Prigol Marina Puntel Robson Luiz 《Environmental science and pollution research international》2021,28(14):17519-17531
Environmental Science and Pollution Research - Manganese (Mn) is an essential element that, in excess, seems to be involved in the development of different neurodegenerative conditions.... 相似文献
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Fidelis Michel Zampieri Abreu Eduardo Josué Tatiana Gulminie de Almeida Lariana Negrão Beraldo Lenzi Giane Gonçalves Santos Onelia Aparecida Andreo Dos 《Environmental science and pollution research international》2021,28(19):23675-23683
Environmental Science and Pollution Research - This study describes the use of a prototype for the continuous photocatalytic reaction process using Fe/Nb2O5-immobilized catalyst for triclosan and... 相似文献
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Celso Markowitsch Jose Luce M. Brandão Torres Marco Aurélio Mata Gonçalves Torres Regina Tomoko Shirasuna Daniela Aparecida Farias Nelson Augusto dos SantosJr. Maria Tereza Grombone-Guaratini 《Chemoecology》2016,26(6):235-246
Merostachys riedeliana Rupr. is a native and overabundant bamboo species in the Brazilian Atlantic Forest. Moderate to strong allelopathic activity may be one mechanism that explains this super-dominance and the changes in structure and composition of forest areas occupied by bamboo. This study evaluated the phytotoxic effect of M. riedeliana extracts and fractions and identified their putative allelochemicals. We investigated the presence of allelochemicals in soil collected from stands occupied by M. riedeliana. Furthermore, we evaluated the putative effect of tree allelochemicals, individually and combined, on germination and growth. The aqueous extract of leaves and its ethyl acetate fraction presented the highest inhibitory effects on seed germination and seedling growth. The effect of the extracts and fractions on the target species was species-specific. Neither the individual nor the combined phenolic acids significantly inhibited seed germination; however, a pronounced growth inhibition was observed in M. bimucronata seedlings treated with vanillic acid and in E. verna and M. bimucronata seedlings treated with combined phenolic acids. Isovitexin, vitexin, isoorientin, orientin, and their O-glycoside derivatives, the lactonic dimer of the p-hydroxybenzoic acid and 3,4-methylenedioxymandelic acid were identified in the aqueous extracts and ethyl acetate fraction by Liquid Chromatography-Diode Array Dectector/Electrospray Ionization/Mass Spectrometry (LC-DAD/ESI–MS/MS). The Gas Chromatography-Mass Spectrometer (GC–MS) profile of the same extract and fraction showed the presence of benzoic, benzeneacetic, salicylic, p-hydroxybenzoic, p-hydroxyphenylacetic, vanillic, p-coumaric, protocatechuic, syringic, gallic, m-coumaric vanillylmandelic, 4-methylmandelic, 3,4-methylenedioxymandelic and trans-ferulic acids. The p-benzoic acid and the apigenin 6-C-glucoside (isovitexin) were identified in the soil extract collected from under bamboo-growing areas. Even though laboratory bioassays are not completely predictive of the allelopathic effects that occur in nature, the results of this study provide preliminary evidence of allelopathy as a possible species-specific inhibition mechanism of native species that explain the impoverishment of floristic richness and the functional groups in areas where M. riedeliana is overabundant. 相似文献
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Jaqueline Bianchi Mario Sérgio Mantovani Maria Aparecida Marin-Morales 《环境科学学报(英文版)》2015,36(10):102-111
Based on the concentration of Malathion used in the field, we evaluated the genotoxic potential of low concentrations of this insecticide on meristematic and F1 cells of Allium cepa and on rat hepatoma tissue culture (HTC cells). In the A. cepa, chromosomal aberrations (CAs), micronuclei (MN), and mitotic index (MI) were evaluated by exposing the cells at 1.5, 0.75, 0.37, and 0.18 mg/mL of Malathion for 24 and 48 hr of exposure and 48 hr of recovery time. The results showed that all concentrations were genotoxic to A. cepa cells. However, the analysis of the MI has showed non-relevant effects. Chromosomal bridges were the CA more frequently induced, indicating the clastogenic action of Malathion. After the recovery period, the higher concentrations continued to induce genotoxic effects, unlike the observed for the lowest concentrations tested. In HTC cells, the genotoxicity of Malathion was evaluated by the MN test and the comet assay by exposing the cells at 0.09, 0.009, and 0.0009 mg/5 mL culture medium, for 24 hr of exposure. In the comet assay, all the concentrations induced genotoxicity in the HTC cells. In the MN test, no significant induction of MN was observed. The genotoxicity induced by the low concentrations of Malathion presented in this work highlights the importance of studying the effects of low concentrations of this pesticide and demonstrates the efficiency of these two test systems for the detection of genetic damage promoted by Malathion. 相似文献
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Caritá Renata Mazzeo Dânia Elisa Christofoletti Marin-Morales Maria Aparecida 《Environmental science and pollution research international》2019,26(21):21475-21483
Environmental Science and Pollution Research - A problem that has been dragging in recent decades is the final disposal of the waste produced in the wastewater treatment process. In addition to its... 相似文献
29.
Optimization of Fenton's oxidation of chemical laboratory wastewaters using the response surface methodology 总被引:6,自引:0,他引:6
Establishing a treatment process for practical and economic disposal of laboratory wastewaters has become an urgent environmental concern of the Department of Chemical Engineering of the Universidade Estadual de Maringá (State University of Maringá), Brazil. Fenton and related reactions are potentially useful oxidation processes for destroying toxic organic compounds in water. In these reactions, hydrogen peroxide is combined with ferrous or ferric iron in the presence or absence of light to generate hydroxyl radicals (.OH). The feasibility of Fenton's reagent to treat waste chemicals from an academic research laboratory was investigated in this study. A response surface methodology was applied to optimize the Fenton oxidation process conditions using chemical oxygen demand (COD) removal as the target parameter to optimize, and the reagent concentrations, as related to the initial concentration of organic matter in the effluent, and pH as the control factors to be optimized. Maximal COD removal (92.3%) was achieved when wastewater samples were treated at pH 4 in the presence of hydrogen peroxide and iron in the ratios [COD]:[H2O2]=1:9 and [H2O2]:[Fe2+]=4.5:1. Under these conditions, it was possible to obtain simultaneously maximal COD removal and minimal chemical sludge after treatment, which is a residue that needs further processing. 相似文献
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Ramos Marcio Antonio Gomes Bueno de Oliveira Eduardo Schneider Pião Antonio Carlos Simões Nalin de Oliveira Leite Dilza Aparecida de Franceschi de Angelis Dejanira 《Environmental monitoring and assessment》2016,188(5):1-14
Environmental Monitoring and Assessment - Due to the concern with the quality of hydric resources, the monitoring is essential to evaluate and identify the anthropogenic and environmental... 相似文献