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1.
Poly(-caprolactone) (PCL) was blended with diatomaceous earth (diatomite) and irradiated with -rays to introduce cross-linking between PCL molecules or both components. The unwashed diatomite containing a little of a volatile component showed high efficiency of introduction of cross-linking, whereas that with no volatile component showed low efficiency of introduction of cross-linking. Elongational viscosity, melt viscosity, and modulus of PCL/diatomite blend irradiated at various doses were significantly improved. Enzymatic degradation of the PCL/diatomite blend became faster than that of the PCL, though that of the blend irradiated became slower.  相似文献   
2.
OBJECTIVE: Child crash dummies are conventionally used for safety performance evaluations of the child restraint system (CRS) in vehicle crash tests. To investigate injuries to various body regions of a child in detail, mathematical models are useful, and provide information that cannot be analyzed by crash dummies. Therefore, in the present research, a finite element (FE) model of a 3-year-old child has been developed by model-based scaling from the AM50 human FE model, THUMS (Total HUman body for Safety). METHODS: The dimensions of each body region were based on the anthropometry data of United States children, and material properties of child bone were estimated from data reported in the literature. Neck flexion, thorax impact responses, and torso flexion were validated against the response corridor of the 3-year-old Hybrid III dummy in calibration tests. A test of lap belt loading to the abdomen was also conducted. FE models of two different types of CRS, a 5-point harness and a tray shield CRS, were also made, and ECE R44 sled impact test simulations were conducted using the child FE model. RESULTS: The characteristics of the child FE model proved to be close to the Hybrid III and child volunteer corridor. In the ECE R44 sled test simulations using the child FE model, the head movement down and head rotation were large in the 5-point harness CRS, and chest deflection was large in the tray shield CRS. In both CRS types, the whole spine flexed in the child FE model. This behavior is different from that of the Hybrid III, where the thorax spine is stiff and only the cervical spine and lumbar spine flex. CONCLUSIONS: Although this child FE model has several limitations in areas such as the anatomical shapes and material properties of a child, this model can be a useful tool to examine the behavior of a child in impacts, which may be difficult to predict by using the Hybrid III dummy with its stiff thorax spine box.  相似文献   
3.
    
For an effective decomposition and removal of organic halogenated compounds, a packed-bed non-thermal plasma reactor with in situ absorption of the resulting halogenated products by alkaline sorbent incorporated was proposed. In the plasma reactor, α-Al2O3 particles of 1 and 3 mm (mean particle diameter) were packed as solid dielectric medium to enhance the plasma power density in the reactor. Further, alkaline sorbent of Ca(OH)2 was doped onto the surface of α-Al2O3 particles, in order to remove halogenated products by in situ absorption with Ca(OH)2. A high-voltage and high-frequency pulsed power of −15 to 15 kV and 1 kHz was applied to the wire electrode of the plasma reactor by means of a DC power source. In the present study, as the sample of an organic halogenated compound that is most popularly used, we selected dichloromethane (CH2Cl2), and 500 ppm of the initial concentration of CH2Cl2 was fed into the reactor accompanied by air at a fixed flow rate of 500 × 10−6 m3 min−1 at room temperature. As a result, it was recognized that the amount of CH2Cl2 decomposed by non-thermal plasma in an α-Al2O3 particle bed increased with an increase in plasma input power. The ratio of decomposition of CH2Cl2 was almost 100% at 13 kV of electric power and 1 kHz frequency, and CO2, CH3Cl, COCl2, HCl, and Cl2 were observed as the major reaction products. On the other hand, when CH2Cl2 was introduced into the plasma reactor where α-Al2O3 particles doped with Ca(OH)2 were packed, the ratio of decomposition of CH2Cl2 became higher, compared to the case that α-Al2O3 particles were not doped with Ca(OH)2. Moreover, there were no halogenated by-product gases detected in the outlet gas from the reactor. As the solid reaction products, CaClOH and Ca(ClO)2·4H2O were detected on Ca(OH)2 by X-ray diffraction. From these findings, it was recognized that CH2Cl2 was decomposed more effectively without producing unwanted harmful halogenated by-products in the proposed non-thermal plasma reactor where α-Al2O3 particles doped with Ca(OH)2 sorbent were packed.  相似文献   
4.
Ash produced from the combustion of livestock manure contains large amounts of phosphorus (P), which is an important resource as a fertilizer. Some studies have extracted and recovered P from incinerated biomass ash using inorganic acid or alkaline agents, which produce wastewater that requires treatment and is expensive due to the cost of chemicals. Livestock manure ash contains not only P, but also water soluble salts, which could be a negative influence on plant growth and shall be preferably removed from the recovered fertilizer. In this study, we removed salinity from cattle manure incineration ash by simple aqueous leaching, while retaining the P content. The optimal condition was a 20 min leaching time at a liquid/solid (L/S) ratio of 10 mL g-ash?1. Under this condition, over 90 % of Cl and 20 % of Na in the original ash was removed, while over 99 % of the P was retained in the leached residue. The leached residue met the fertilizer standard in Japan in terms of citrate soluble fertilizer components and contained few heavy metals. X-ray analyses of the ash indicated that Cl was mainly present as KCl in the original ash, while P was mainly present as Ca compounds in the ash.  相似文献   
5.
Removal of Cr(VI) from contaminated soil by electrokinetic remediation   总被引:2,自引:0,他引:2  
A new process for the removal of hexavalent chromium [Cr(VI)] contaminated soil is described. The process provides for an efficient removal of anionic chemicals from contaminated soils. Chromate anions were removed from the soil to the anodic reservoir by the moving force of electromigration. In this process, the chromate anions that accumulate in the anodic reservoir are simultaneously eliminated by using a column packed adsorbent. The adsorbent (immobilized tannin) used was chemically incorporated into cellulose. Cr(VI) was found to be adsorbed to this adsorbent efficiently. In the electrokinetic process, the pH of the aqueous solution in the anodic reservoir was decreased by the electrolysis of water. In the present study, the pH of the solution in the anodic reservoir is maintained at pH 6 by the addition of an aqueous alkaline solution during the electrokinetic process. The advantage of pH control is that it promotes the release of Cr(VI) from the soil by electromigration, thus permitting the maximum adsorption of Cr(VI) on the immobilized tannin. Simultaneous collection of Cr(VI) from the anodic reservoir leads to the protection from secondary contamination with Cr(VI).  相似文献   
6.
Previously, we developed a model to predict lean flammability limit L and flame propagation velocity Sb for pulverized coal. In the present paper, we have extended the model to apply it in development of oxy-fuel combustion systems. The basic model consists of two particles. One of the two particles burns first, then, the other particle is ignited by the heat of combustion of the one burning particle. We analyzed at what distance the first burning particle could ignite the next particle, and how fast the first burning particle could ignite the next particle. The model was verified both for air and oxy-fuel combustion conditions. Next, a method to support burner development was examined by using the model. Local Sb and L near the ignition points of the burner could be analyzed from the concentration and temperature profiles of CFD results. Flame stability was judged by the calculated Sb and L profiles, and past results of blow-off limits obtained with actual- and pilot-scale experiments. A DS®T-burner was developed by Hitachi Power Europe, and installed at the Schwarze Pumpe pilot plant. Combination of the technique and large eddy simulation was applied to confirmation of the system.  相似文献   
7.
依据中日合作项目《加强中国安全生产科学技术能力计划》成果,对比分析了中日对企业安全培训相关法规要求,明确了各自的优点、缺点,提出通过开展企业内安全培训负责人培训可增强企业内安全培训能力,并在宁波进行了试点。提出应当重视企业内安全培训工作,对生产经营单位安全培训规定进行修改,制定配套实施细则和办法,开展企业内安全培训负责人培训、把班组长培训制度化、充分利用外部培训机构等增强企业内安全培训能力的对策和建议。  相似文献   
8.
    
Journal of Material Cycles and Waste Management - The chemical states of arsenic contained in 4 kinds of sewage sludge incineration ash and insolubilized materials are analyzed using a leaching...  相似文献   
9.
The present work focuses on investigation of the effective recovery of heavy metals from molten fly ash by applying chloride-induced volatilization. In particular, the effect of unburned carbon on the chloride-induced volatilization of lead, zinc, and copper from model and real molten fly ashes was investigated in the temperature range 873–1173 K under a N2 atmosphere. As a result, almost 100% of lead and a significant proportion of zinc were volatilized from the real molten fly ash samples at 1173 K. In contrast, for the model fly ash, volatilization ratios of lead and zinc at 1173 K were only 85% and 25%, respectively. Further, the results of X-ray diffraction analysis suggested that PbO in molten fly ash was converted either to Pb2OCl2 or Pb by respective chlorination and reduction reactions. Meanwhile ZnO and CuO in the molten fly ash were reduced to Zn and Cu by reaction with unburned carbon. Subsequently, Pb, Zn, and Pb2OCl2 were volatilized, but Cu remained in the solid residue. Finally, the volatilization ratio of zinc increased with the addition of carbon, and more than 98% of zinc was volatilized at 1173 K from a fly ash with a carbon content of 20%.  相似文献   
10.
    
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