Accumulation and translocation of heavy metals in soil and plants from fly ash contaminated area

The present investigation deals with the accumulation of heavy metals in fields contaminated with fly ash from a thermal power plant and subsequent uptake in different parts of naturally grown plants. Results revealed that in the contaminated site, the mean level of all the metals (Cd, Zn, Cr, Pb, Cu, Ni, Mn and Fe) in soil and different parts (root and shoots) of plant species were found to be significantly (p<0.01) higher than the uncontaminated site. The enrichment factor (EF) of these metals in contaminated soil was found to be in the sequence of Cd (2.33) > Fe (1.88) > Ni (1.58) > Pb (1.42) > Zn (1.31) > Mn (1.27) > Cr (1.11) > Cu (1.10). Whereas, enrichment factor of metals in root and shoot parts, were found to be in the order of Cd (7.56) > Fe (4.75) > Zn (2.79) > Ni (2.22) > Cu (1.69) > Mn (1.53) > Pb (1.31) > Cr (1.02) and Cd (6.06) approximately equal Fe (6.06) > Zn (2.65) > Ni (2.57) > Mn (2.19) > Cu (1.58) > Pb (1.37) > Cr (1.01) respectively. In contaminated site, translocation factor (TF) of metals from root to shoot was found to be in the order of Mn (1.38) > Fe (1.27) > Pb (1.03) > Ni (0.94) > Zn (0.85) > Cd (0.82) > Cr (0.73) and that of the metals Cd with Cr, Cu, Mn, Fe; Cr with Pb, Mn, Fe and Pb with Fe were found to be significantly correlated. The present findings provide us a clue for the selection of plant species, which show natural resistance against toxic metals and are efficient metal accumulators.     

Studies on the utility of plant cellulose waste for the bioadsorption of crystal violet dye

Several synthetic dyes employed in textile and food industries are discharged into aquatic environment. These visible pollutants in water damage environment, as they are carcinogenic and toxic to humans. The use of cost effective and ecofriendly plant cellulose based adsorbents have been studied in batch experiments as an alternative and effective substitution of activated carbon for the removal of toxic dyes from waste water. Adsorbents prepared from sugarcane baggase, were successfully used to remove certain textile dye such as crystal violet from an aqueous solution. The present investigation potentiate the use of sugarcane baggase, pretreated with formaldehyde (referred as Raw Baggase) and sulphuric acid (referred as Chemically Activated Baggase), for the removal of crystal violet dye from simulated waste water. Experiments were carried out at neutral pH with various parameters like dye concentration, temperature, contact time and adsorbent dosage. Efficiency of raw baggase was found better than chemically activated baggase for adsorption of crystal violet dye. The data obtained perfectly fits in the Freundlich adsorption isotherm.     

Achieving sustainable development goals through participatory forest management: Examples from South-Eastern Bangladesh

Forests managed through peoples' participation can help to achieve a number of sustainable development goals (SDGs). This paper, drawing data from four participatory forest management (PFM) projects in south-eastern Bangladesh, explored: (a) the factors that influenced the outcomes of PFM; and (b) contribution of PFM towards achieving selected SDGs. The research used observation, semi-structured household interviews, group discussions, vegetation survey and Ostromʼs design principles for data collection, Divergent forest conditions and factors in four PFM sites have had differential contribution to SDGs. Heterogeneity of user groups, insufficient coordination, absence of motivation, and land tenure conflicts had affected the attainment of SDGs. The PFM helped to achieve 9–11 SDGs comprising poverty reduction (Goal 1), improving food security (Goal 2), maintaining health and well-being (Goal 3), enhancing childrensʼ education (Goal 4), fair access to jobs and committees (Goals 5 and 10), sources of clean drinking water (Goal 6), affordable energy for cooking (Goal 7), increased household economy (Goal 8), climate change through carbon sequestration (Goal 13), forest conservation (Goal 15), and partnerships with relevant institutions (Goal 16). In order to achieve SDGs, PFM could be viewed as an integral part of government development strategies, which needs sectoral coordination and integration of relevant policies.     

Scientometric analysis: identification of research trends for ozone as an air pollutant for 2011–2019

Environmental Science and Pollution Research - Ground level ozone is a major air pollutant with known toxic effects on humans. The research field is well established with many scientists from...     

A new apparatus to enhance the rate of gas hydrate formation: Application to capture of carbon dioxide

A new apparatus employing a modular, mechanically agitated gas-inducing crystallizer is used to demonstrate the capture of CO₂ via hydrate crystallization. The crystallizer enhances the contact of hydrate forming gases with water and thus the rate of hydrate crystallization increases. Flue gas (CO₂/N₂) and fuel gas (CO₂/H₂) mixtures were used to represent post- and precombustion capture. A comparison between the rates of hydrate formation in different crystallizers is presented by defining a metric called the normalized rate of hydrate formation. The gas uptake and the separation efficiency for the fuel and flue gas mixtures were found to be greater compared to the results obtained in a smaller scale stirred tank reactor (Kumar et al., 2009c, Linga et al., 2008). The gas uptake and CO₂ recovery for flue gas mixture in the presence of THF obtained in this work was higher than that reported in the literature with tetra-n-butyl ammonium bromide and tetra-n-butyl ammonium fluoride (Fan et al., 2009, Li et al., 2009). Although hydrate crystallization is able to capture CO₂, the power required for mechanical agitation was found to be very significant. If the hydrate process is to be used industrially then hydrate crystallization must be carried out without mechanical agitation.     

Isolation and Characterization of a <Emphasis Type="Italic">Burkholderia</Emphasis> sp. USM (JCM15050) Capable of Producing Polyhydroxyalkanoate (PHA) from Triglycerides,Fatty Acids and Glycerols

A consortium of microorganisms from oil polluted wastewater sample was cultivated to promote polyhydroxyalkanoate (PHA) accumulation before subjecting the mixed cultures to sucrose density gradient ultracentrifugation. This resulted in the fractionation of the bacterial cells according to their physical features such as size, morphology and/or densities. An isolate was identified as Burkholderia sp. USM (JCM15050), which was capable of converting palm oil products [crude palm kernel oil (CPKO), palm olein (PO), palm kernel acid oil (PKAO), palm stearin (PS), crude palm oil (CPO), palm acid oil (PAO) and palm fatty acid distillate (PFAD)], fatty acids and various glycerol by-products into poly(3-hydroxybutyrate) [P(3HB)]. Up to 70 and 60 wt% of P(3HB) could be obtained when 0.5%(v/v) CPKO and glycerol was fed, respectively. Among the various fatty acids tested, lauric acid followed by oleic acid and myristic acid gave the best cell growth and PHA accumulation. Compared to Cupriavidus necator H16, the present isolate showed better ability to grow on and produce PHA from various glycerol by-products generated by the palm oil industry. This study demonstrated for the first time an isolate that has the potential to utilize palm oil and glycerol derivatives for the biosynthesis of PHA.     

Management of Fly Ash Through Vermicomposting: A Rational Approach

Fly ash is a by‐product of coal combustion in thermal power plants. Its generation poses several environmental problems, the most important ones being its capacity for causing pollution and the need for large storage areas to keep it out of the environment. Fly ash management remains a major concern in the 21st century; however, despite these challenges, the material has great potential for beneficial use in agriculture due to its efficacy in modifying and improving soil health and improving crop performance. Vermicomposting is an excellent technique for reducing the toxic heavy metals in fly ash through the introduction of earthworms. The activities of several earthworm species minimize the solubility of heavy metals and increase the bioavailability of major nutrient elements such as phosphorous (P) and nitrogen (N). This article provides a comprehensive review of the scope and benefits of vermiremediating fly ash, demonstrating the abilities of different species of earthworms to accumulate heavy metals and increase the availability of plant nutrients. On the basis of a literature survey, the authors have concluded that adopting vermicomposting technology promises increased, effective fly ash utilization for agricultural benefits.     

Olivine dissolution from Indian dunite in saline water

The rate and mechanism of olivine dissolution was studied using naturally weathered dunite FO_98.21(Mg_1.884Fe_0.391SiO₄) from an Indian source, that also contains serpentine mineral lizardite. A series of batch dissolution experiments were carried out to check the influence of temperature (30–75 ^°C), initial dunite concentration (0.5 and 20 g/L), and salinity (0–35 g/L NaCl) under fixed head space CO₂ pressure (P\(_{\text {CO}_{2}}\) = 1 barg) on dunite dissolution. Dissolved Mg, Si, and Fe concentrations were determined by inductive coupled plasma atomic emission spectroscopy. End-product solids were characterized by scanning electron microscopy and X-ray diffraction. Initially, rates of dissolution of Si and Mg were observed to be in stoichiometric proportion. After 8 h, the dissolution rate was observed to decline. At the end of the experiment (504 h), an amorphous silica-rich layer was observed over the dunite surface. This results in decay of the dissolution rate. The operating conditions (i.e., salinity, temperature, and mineral loading) affect the dissolution kinetics in a very complex manner because of which the observed experimental trends do not exhibit a direct trend.     

Power and politics of social–ecological regime shifts in the Chilika lagoon,India and Tam Giang lagoon,Vietnam

Analyses of ecological regime shifts primarily focus on abrupt, long-term and significant changes that trigger fundamental reorganisation in ecosystem structure and function. There remains limited empirical work on the relationship between regime shifts and social inequities, power imbalances, and social and environmental injustices. Inadequate attention to this social context restricts our ability to predict and avert impending regime shifts, or to effectively navigate where thresholds have been crossed. In this paper, we offer an initial empirical assessment of politics and power in two coastal lagoons in India and Vietnam experiencing abrupt change. We adopt a realist view of power to: (1) assess the social relations structuring human–environment interactions in both lagoons; (2) characterise the dominant framings and narratives that influence if and how regime shifts are understood; (3) consider who wins and loses if and when regime shifts and other forms of rapid environmental change take place; and (4) reflect on the implications of power and politics for the governance of regime shifts in linked human–ocean settings.     

Coastal vulnerability assessment of the predicted sea level rise in the coastal zone of Krishna–Godavari delta region,Andhra Pradesh,east coast of India

The Krishna–Godavari coastal region in east coast of India has a 525.15-km-long coastline with low-lying tidal mudflats, beaches, mangrove swamp, creek and tidal channels. Recently, the increasing frequency of tropical cyclones in the Bay of Bengal, i.e., Phylin and Hudhud in Andhra Pradesh coast, and the devastating impact of the 2004 tsunami in India increased the significance in assessing the vulnerability of the coastal lands to inundation and flooding, notably in the context of climate change-induced sea level rise. This study aims to estimate a coastal vulnerability index (CVI) for the coastal subregion of Krishna–Godavari delta and to use the calculated index to evaluate the vulnerability of 14 coastal talukas of the Krishna–Godavari delta region. This CVI is calculated by using four geological and three physical parameters characterizing the vulnerability of the study coastal region, including regional slope, coastal elevation, geomorphology, significant wave height, mean tidal range and relative sea level using different conventional and remotely sensed data. Using a composite coastal vulnerability index based on the relative risk rating of those parameters, each of the 14 coastal talukas was classified according to their vulnerability. The CVI results depict that coasts are least and most vulnerable to inundation, flooding and erosion of coastal lands where geological parameters are more efficient to CVI. The paper alerts to decision makers and planners to mitigate the natural disaster and manage the coastal zone and is a primary step toward prioritizing coastal lands for climate change adaptation strategies in the view of increased storminess and projected sea level rise.