广西典型碳酸盐岩区农田土壤-作物系统重金属生物有效性及迁移富集特征

为揭示碳酸盐岩地质高背景区土壤重金属生态风险,选择广西典型的成土母岩为碳酸盐岩的土壤重金属高背景区,采集水稻籽实及对应根系土样品68套,在分析测试土壤、农作物籽实样品中砷(As)、镉(Cd)、铬(Cr)、铜(Cu)、汞(Hg)、镍(Ni)、铅(Pb)和锌(Zn)这8种重金属含量及土壤中重金属赋存形态的基础上,采用统计学、地累积指数、生物富集系数及相关性分析等方法开展土壤重金属生态风险研究.结果表明,研究区土壤中8种重金属平均含量明显高于全国和广西表层土壤的平均水平,其中Cd、As和Cr超过农用地土壤污染筛选值的比例分别达95. 6%、86. 8%和69. 1%,超过土壤污染管控值的比例分别为27. 9%、17. 6%和5. 9%.区内土壤中As、Cr、Cu、Ni、Pb和Zn主要以残渣态为主(残渣态占比 80%),显示出较低的生物活性; Cd的生物活性相对较高,生物有效态组分占20. 99%,但仍明显低于全国其它非碳酸盐岩地区的土壤; Hg的潜在生物有效态组分占44. 04%,然而土壤中Hg全量较低,因此其潜在生物有效态的绝对含量较低.与土壤相比,研究区水稻籽实中重金属超标率明显较低,仅部分样品中Cd、Cr、Pb超过国家食品限量标准,超标率分别为8. 8%、2. 9%和23. 5%.相关性分析显示,研究区土壤重金属全量与对应的水稻籽实中重金属含量不存在显著正相关关系.水稻籽实重金属生物富集能力普遍较低,8种重金属生物富集系数(BCF)的均值均小于0. 1,其中As、Cr、Hg、Ni和Pb的BCF均值小于0. 05.上述结果表明,对于碳酸盐岩等地质高背景区,相关部门在制定污染土壤管控政策时不能仅以土壤重金属全量作为衡量标准,应综合考虑金属赋存形态、生物活性及农作物超标率等因素.     

故障树法和改进PSO-PNN网络的电梯故障诊断模型

针对电梯故障问题,提出一种将故障树分析法、改进的粒子群优化算法和概率神经网络相结合的方法用于电梯的故障诊断。以电梯的安全回路系统为例,用故障树法对回路进行分析,获得训练样本与故障类型;使用粒子群算法对概率神经网络的平滑因子进行优化,在优化过程中,针对粒子群算法存在易陷入局部最优的缺陷,提出对惯性权重的改进策略;采用相对误差对诊断效果做出评估,并与传统的概率神经网络和基本粒子群算法优化的概率神经网络在各种故障类型输出和最大相对误差等方面进行比较,结果表明:该模型能够有效诊断电梯故障。     

Ammonia removal from low-strength municipal wastewater by powdered resin combined with simultaneous recovery as struvite

• Powdered resin was employed for ammonia recovery from municipal wastewater. • Powdered resin achievedefficient ammonia removal under various working conditions. • Co-existing cations indicated competitive adsorption of ammonia. • Ammonia was recoveredby two-stage crystallization coupled with ion exchange. Low-strength municipal wastewater is considered to be a recoverable nutrient resource with economic and environmental benefits. Thus, various technologies for nutrient removal and recovery have been developed. In this paper, powdered ion exchange resin was employed for ammonia removal and recovery from imitated low-strength municipal wastewater. The effects of various working conditions (powdered resin dosage, initial concentration, and pH value) were studied in batch experiments to investigate the feasibility of the approach and to achieve performance optimization. The maximum adsorption capacity determined by the Langmuir model was 44.39 mg/g, which is comparable to traditional ion exchange resin. Further, the effects of co-existing cations (Ca²⁺, Mg²⁺, K⁺) were studied. Based on the above experiments, recovery of ammonia as struvite was successfully achieved by a proposed two-stage crystallization process coupled with a powdered resin ion exchange process. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) results revealed that struvite crystals were successfully gained in alkaline conditions (pH= 10). This research demonstrates that a powdered resin and two-stage crystallization process provide an innovative and promising means for highly efficient and easy recovery from low-strength municipal wastewater.     

中国环境保护投资进展与展望

环保投资是环保工程项目实施的重要保障，为打好污染防治攻坚战、推进美丽中国和生态文明建设提供了有力支撑。本文回顾了近40多年来中国环保投资政策演进历程，将其划分为企业主体阶段（1979—2003年）、政企并重阶段（2004—2012年）、多元投资阶段（2013年至今）。从规模加大、构成丰富、渠道拓展及强化效益四个方面，总结了环保投资主要进展与成效。基于高质量发展不足、回报机制不健全、投资绩效待提高三个角度，识别当前环保投资存在的关键瓶颈。从强化气候投融资、鼓励投资机制创新、加大财政支出力度、促进多元投资、提高投资效益等五个方面，对未来环保投资政策优化方向进行了展望。     

Effect of SiO2 on immobilization of metals and encapsulation of a glass network in slag

The final disposal of ash from an incinerator is of special concern because of the possibility of its releasing toxic substances. Melting/vitrification has been regarded as a prospective technology of ash treatment. The object of this investigation was to evaluate the effect of silica (SiO2) addition on the immobilization of hazardous metals and the encapsulation of a glass network during the vitrification process. Four specimens with SiO2/fly ash mixing ratios of 0, 0.1, 0.2, and 0.3, respectively, were tested. The mobility of metals in slag was then estimated by a sequential extraction procedure. X-ray diffraction analysis indicates that SiO2 leads to the polymerization of silicates. The encapsulation of aluminum, calcium, and magnesium would not be observed unless adequate amount of SiO2 was added. It was also found that SiO2 addition enhances the formation of a compact and interconnected glass network structure and, thus, contributes to the chemical stability of metals in slag. After vitrification, the mobility of cadmium, copper, iron, chromium, nickel, lead, and zinc was significantly reduced. However, there is no significant correlation between the immobilization of these metals and the addition of SiO2.     

PLANNING OF URBAN BEST MANAGEMENT PRACTICES1

ABSTRACT: A “user-friendly” computer program has been developed for application in personal computers for preliminary design, evaluation, and cost effectiveness analysis of various best management practice (BMP) measures to control stormwater quantity and quality. The algorithms utilize the SCS TR-55 method for calculating runoff hydrographs for a single storm event and a first order pollutant washoff equation to generate pollutographs. Sensitivity analyses based on different policy scenarios is performed on a hypothetical watershed for the purpose of illustration. Three types of BMP measures, namely detention ponds (dry, wet, and extended wet ponds), infiltration trenches, and porous pavements are considered. It is found that the extended wet ponds have the best cost effective performance of the measures evaluated.     

OPTIMUM USE OF PADDY FIELDS FOR FLOOD MITIGATION1

In Taiwan, the continuously increasing levels of rice imports are likely to result in surplus paddy fields. Hence, the surplus paddy fields may be developed into wetlands to increase ground water recharge, provide appropriate environments for wildlife, and most importantly, store flood water. This study developed a hydrological model incorporating the distributed rainfall‐runoff model based on the kinematics wave approach and the distributed tank model for simulation, respectively, in mountainous and flat areas. The hydrological model was found to simulate the rainfall‐runoff behavior well in the study area. Furthermore, a decision method based on the genetic algorithm concepts was proposed to give policy makers the optimal location and area size of paddy fields to construct wetlands for flood mitigation.     

Quantifying energy use, carbon dioxide emission, and other environmental loads from island tourism based on a life cycle assessment approach

The main purpose of industrial ecology is to evaluate and minimize impacts from economic activities of human society. Tourism as one economic activity, results in a full range of environmental impacts, but few applications of industrial ecology to tourism management have previously been discussed. Life cycle assessment (LCA) is used in this research to explore environmental impacts of island tourism, and then the environmental loads per tourist per trip can be found. Penghu Island in Taiwan is taken as an example to examine this new approach. Various environmental loads in transportation, accommodation, and recreation activity sector are all inventoried and calculated here. In summary, per tourist per trip uses 1606 MJ of energy, 607 L of water, and emits 109,034 g of CO₂, 2660 g of CO, 597 g of HC, 70 g of NO_x. In addition, per tourist per trip also discharges 416 L of wastewater, 83.1 g of BOD, and 1.95 g of solid waste. In terms of energy use, the transportation consumes the largest energy (67%); in particular, the airplane sector. Moreover, per Penghu tourist results in more environmental loads than local people; for example, the amount of solid waste discharge per tourist is 1.95 kg per day, while that of per local people is 1.18 kg. Finally, the advantages and limitations of such LCA approach are also discussed.     

Comparison of RBCA and CalTOX for setting risk-based cleanup levels based on inhalation exposure

Risk-based corrective action (RBCA) and CalTOX (California EPA) are often used to develop risk-based soil cleanup levels. The determination of the entry parameters, including slope factors, degradation assumption, methodologies, and dispersion models for these two approaches greatly affect the onsite/offsite cleanup levels, risk distribution, and ranking of the influential factors. The subsurface soil-to-ambient air was considered as the only significant exposure pathway in this study. RBCA and CalTOX apply analytical equations and multimedia fugacity model, respectively, to simulate the transport of contaminants from subsurface soil to ambient air. Nine carcinogenic organic contaminants were selected as the target compounds. Environmental monitoring data collected from a contaminated site in southern Taiwan was used as model inputs. In this study, degradation assumption had greater influence on CalTOX evaluation than slope factors. The cleanup soil levels of all target chemicals developed by both models were close under the same slope factors and degradation assumptions, except for vinyl chloride and hexachlorobenzene. Furthermore, RBCA generally had larger offsite dispersion ratios than CalTOX, especially for long distances. The risk distribution obtained by RBCA was much board than by CalTOX. When 95th percentile was considered as the starting point, the SSTLs derived by RBCA were much stricter than by CalTOX. The ranking of influential factors in the onsite risk assessment for these two models were completely different because of their distinct model methodologies.