Desorption characteristics of kaolin clay contaminated with zinc from electrokinetic soil processing

A number of bench scale laboratory column tests were carried out using a newly designed and developed electrokinetic cell to investigate the fundamental behavior of zinc-spiked kaolin clay subjected to an electric field. Laboratory investigations focused on (i) zinc migration by the combined effects of electromigration and electro-osmosis and (ii) the electrically induced desorption characteristics of zinc-contaminated kaolin that occurred during processing. The correlations of the applied voltage gradient, electro-osmotic flow rate, and the development of a pH gradient were examined and evaluated. The results showed that the removal efficiency was high during the early stage of processing due to rapid desorption by electrokinetic effects in the cathode region. However, the majority of zinc migrating from the anode was precipitated due to the high pH environment in the cathode region.     

The Impact of Perceptual and Situational Factors on Environmental Communication: A Study of Citizen Engagement in China

This study applied a situational approach to understanding an environmental problem: PM2.5 (its resulted haze and smog air pollution) in China. Based on a national sample of 374 citizens living in China, it tested a situational model of problem solving and extended it by adding citizens’ environmental engagement behaviour as an immediate consequence of their communicative action. Results of a structural equation modelling analysis supported all the causal links in the conceptual model. Moreover, communicative action significantly mediated the relationship between referent criterion and environmental engagement. Problem recognition, constraint recognition, and involvement recognition did not influence environmental engagement directly, but exerted their significant indirect impact via two key mediators in the model: situational motivation in problem solving and communicative action in problem solving. Theoretical and practical implications of the present study were discussed.     

The role of local governments before and during chemical accidents,focusing on changes in hazardous chemical management systems

ABSTRACT

Disaster management spans actions before, during, and after disaster events. Changes in the roles and functions of local governments before a disaster can influence other stages of disaster management. After a chemical spill in 2012, South Korean hazardous chemical management tasks were returned to the central government and local governments’ roles and functions were reduced. To identify associated issues and enhance the hazardous chemical management system, this study analyzed changes in laws and policies and conducted interviews with stakeholders. While the changes helped with centralization, reinforcement, and specification, some loopholes were discovered. The information and human resource capacities of local governments and intra – and intergovernmental relations issues have hindered their active participation before and during chemical disasters. These loopholes can be addressed through institutional enhancements for local governments, such as including them in monitoring hazardous chemical handling facilities, developing codes articulating the division of tasks among departments within them, and providing adequate incentives for them to increase their personnel. This study provides empirical data that informs ongoing debates about the centralization and devolution of disaster management by linking local governments’ ordinary management systems to their disaster management activities.     

Application of biochar in advanced oxidation processes: supportive,adsorptive, and catalytic role

Environmental Science and Pollution Research - The advanced oxidation processes (AOPs), especially sulphate radical (SO4•−)–based AOPs (SR-AOPs), have been considered more...     

Assessments of natural and anthropogenic influences on water chemistry in the upper Nakdong River,South Korea

Abstract

The purpose of this study is to evaluate what sources principally affect the chemical compositions in the catchment of the upper Nakdong River, South Korea where bedrock mostly consists of silicates as a natural factor. From October 7^th to 9^th, 2015, thirty-three water samples were collected, including samples from tributaries which run alongside mines. We analyzed the major anions, cations, trace elements and water isotopes of the samples and the analyzed data are divided into four groups by principle component analysis (PCA). We determined that most of the water samples are influenced by water-rock interactions when we consider the PCA results and the chemical weathering equation line. However, six samples have excess concentrations of sulfate and plot below the equation line. These samples were mostly from streams beside a zinc-cadmium smelter, which was also consistent with the PCA results. Samples near populated area could also be separated into a group via domestic pollution. Based on the PCA and chemical results, the chemical compositions of the river can be affected by two anthropogenic inputs: mine wastes and domestic contaminants.     

Global and regional potential of wastewater as a water,nutrient and energy source

There is a proactive interest in recovering water, nutrients and energy from waste streams with the increase in municipal wastewater volumes and innovations in resource recovery. Based on the synthesis of wastewater data, this study provides insights into the global and regional “potential” of wastewater as water, nutrient and energy sources while acknowledging the limitations of current resource recovery opportunities and promoting efforts to fast-track high-efficiency returns. The study estimates suggest that, currently, 380 billion m³ (m³ = 1,000 L) of wastewater are produced annually across the world which is a volume five-fold the volume of water passing through Niagara Falls annually. Wastewater production globally is expected to increase by 24% by 2030 and 51% by 2050 over the current level. Among major nutrients, 16.6 Tg (Tg = million metric ton) of nitrogen are embedded in wastewater produced worldwide annually; phosphorus stands at 3.0 Tg and potassium at 6.3 Tg. The full nutrient recovery from wastewater would offset 13.4% of the global demand for these nutrients in agriculture. Beyond nutrient recovery and economic gains, there are critical environmental benefits, such as minimizing eutrophication. At the energy front, the energy embedded in wastewater would be enough to provide electricity to 158 million households. These estimates and projections are based on the maximum theoretical amounts of water, nutrients and energy that exist in the reported municipal wastewater produced worldwide annually. Supporting resource recovery from wastewater will need a step-wise approach to address a range of constraints to deliver a high rate of return in direct support of Sustainable Development Goals (SDG) 6, 7 and 12, but also other Goals, including adaptation to climate change and efforts in advancing “net-zero” energy processes towards a green economy.     

Biomarker responses of <Emphasis Type="Italic">Peromyscus leucopus</Emphasis> exposed to lead and cadmium in the Southeast Missouri Lead Mining District

Biomarker responses and histopathological lesions have been documented in laboratory mammals exposed to elevated concentrations of lead and cadmium. The exposure of white-footed mice (Peromyscus leucopus) to these metals and the potential associated toxic effects were examined at three contaminated sites in the Southeast Missouri Lead Mining District and at a reference site in MO, USA. Mice from the contaminated sites showed evidence of oxidative stress and reduced activity of red blood cell δ-aminolevulinic acid dehydratase (ALAD). Histological examinations of the liver and kidney, cytologic examination of blood smears, and biomarkers of lipid peroxidation and DNA damage failed to show indications of toxic effects from lead. The biomagnification factor of cadmium (hepatic concentration/soil concentration) at a site with a strongly acid soil was 44 times the average of the biomagnification factors at two sites with slightly alkaline soils. The elevated concentrations of cadmium in the mice did not cause observable toxicity, but were associated with about a 50% decrease in expected tissue lead concentrations and greater ALAD activity compared to the activity at the reference site. Lead was associated with a decrease in concentrations of hepatic glutathione and thiols, whereas cadmium was associated with an increase. In addition, to support risk assessment efforts, we developed linear regression models relating both tissue lead dosages (based on a previously published a laboratory study) and tissue lead concentrations in Peromyscus to soil lead concentrations.     

Market potential of biomethane as alternative transportation fuel in South Korea

This study estimated domestically available energy amount of biomethane including landfill gas (LFG) as a transportation fuel by 2035. The amount of available energy that could be supplied was predicted through four stages of ‘theoretical-’, ‘geographical-’, ‘technical-’, and ‘market potential’ by considering geographical, technical, economic conditions, etc. Energy efficiency and added value of biomethane are largely influenced by the site conditions and the neighboring infrastructures. So, how much of the natural gas used in transportation could be substituted with biomethane was examined by setting limits to the amount of organic wastes generated within urban areas. As a result, the market potential of biomethane including landfill gas was approximately 331 × 10⁶ Nm³/year, corresponding to 25% of the natural gas supply for transportation, which could be replaced by biomethane. Assuming that 2% of natural gas for transportation is replaced by biomethane, it corresponds to 29 × 10⁶ Nm³/year (approximately 9% of market potential of biomethane). However, RFS annual mixing rate may be increased upon introduction and the growth rate of the natural gas supply for transport would be higher than that of market potential of biomethane calculated in this study.     

Effect of substrate feeding frequencies on the methane production and microbial communities of laboratory-scale anaerobic digestion reactors

Even though full-scale digesters have been designed based on laboratory-scale tests, the substrate feeding modes of laboratory-scale tests might be different from those of full-scale digesters. The effect of substrate feeding frequencies on the performance and microbial community of laboratory-scale anaerobic digestion reactors was investigated. Feeding frequencies of twice a day, once a day, and every two days were tested in three 2-L reactors with an organic loading rate of 0.5 g-glucose/L/day under mesophilic condition. According to the results of this study, all the reactors showed similar methane production rates and SCOD removal efficiencies after sufficient time of acclimation, but frequently feeding promoted more stable digestion. Although there was no significant difference in microbial diversities from pyrosequencing analyses, the changes of archaeal community composition were observed. The decrease in feeding frequency appeared to cause shifts from acetoclastic methanogens affiliated with Methanosaeta to H₂-utilizing methanogens. The increase of Methanosaeta at a frequently feeding might contribute to the stability of reactor operation. Since this study uses glucose as the substrate, there is still possibility of different results for more complex substrates, such as sludge, food waste, etc.