The effect of changes in land use on nitrate concentration in water supply wells in southern Chester County, Pennsylvania

An analysis of private potable water well data was conducted for seven single family residential developments in southern Chester County, Pennsylvania. Background data were available for 165 wells within the communities when the wells were first drilled in the 1980s and early 1990s. Sampling of 75 wells within these same communities was performed in 2006 to determine whether conversion of the land to residential housing along with the use of conventional on-lot septic systems had resulted in elevated concentration of nitrate-nitrogen in the drinking water aquifer. The data indicate that prior land use influenced the occurrence of nitrate-nitrogen in the drinking water aquifer. The median nitrate-nitrogen concentration for the 165 wells in the background dataset was 2.9 mg/L. One hundred-seven of those wells were drilled on land previously used for active agricultural purposes. The median nitrate concentration in these wells was 3.8 mg/L. Of 48 wells drilled on forested land, the median nitrate concentration was 1.1 mg/L, approximately 3.5 times lower than those drilled on active agricultural land. The median nitrate concentration in the 2006 sampling dataset was 3.6 mg/L, an increase of 0.7 mg/L. The data indicate that conversion of the land has not resulted in contamination of the drinking water aquifer with respect to nitrate-nitrogen. Likewise, the data suggest that the conversion has not resulted in significant improvements to overall water quality.     

Computation of groundwater resources and recharge in Chithar River Basin, South India

Groundwater recharge and available groundwater resources in Chithar River basin, Tamil Nadu, India spread over an area of 1,722 km² have been estimated by considering various hydrological, geological, and hydrogeological parameters, such as rainfall infiltration, drainage, geomorphic units, land use, rock types, depth of weathered and fractured zones, nature of soil, water level fluctuation, saturated thickness of aquifer, and groundwater abstraction. The digital ground elevation models indicate that the regional slope of the basin is towards east. The Proterozoic (Post-Archaean) basement of the study area consists of quartzite, calc-granulite, crystalline limestone, charnockite, and biotite gneiss with or without garnet. Three major soil types were identified namely, black cotton, deep red, and red sandy soils. The rainfall intensity gradually decreases from west to east. Groundwater occurs under water table conditions in the weathered zone and fluctuates between 0 and 25 m. The water table gains maximum during January after northeast monsoon and attains low during October. Groundwater abstraction for domestic/stock and irrigational needs in Chithar River basin has been estimated as 148.84 MCM (million m³). Groundwater recharge due to monsoon rainfall infiltration has been estimated as 170.05 MCM based on the water level rise during monsoon period. It is also estimated as 173.9 MCM using rainfall infiltration factor. An amount of 53.8 MCM of water is contributed to groundwater from surface water bodies. Recharge of groundwater due to return flow from irrigation has been computed as 147.6 MCM. The static groundwater reserve in Chithar River basin is estimated as 466.66 MCM and the dynamic reserve is about 187.7 MCM. In the present scenario, the aquifer is under safe condition for extraction of groundwater for domestic and irrigation purposes. If the existing water bodies are maintained properly, the extraction rate can be increased in future about 10 % to 15 %.     

Water quality and health in northern Canada: stored drinking water and acute gastrointestinal illness in Labrador Inuit

One of the highest self-reported incidence rates of acute gastrointestinal illness (AGI) in the global peer-reviewed literature occurs in Inuit communities in the Canadian Arctic. This high incidence of illness could be due, in part, to the consumption of contaminated water, as many northern communities face challenges related to the quality of municipal drinking water. Furthermore, many Inuit store drinking water in containers in the home, which could increase the risk of contamination between source and point-of-use (i.e., water recontamination during storage). To examine this risk, this research characterized drinking water collection and storage practices, identified potential risk factors for water contamination between source and point-of-use, and examined possible associations between drinking water contamination and self-reported AGI in the Inuit community of Rigolet, Canada. The study included a cross-sectional census survey that captured data on types of drinking water used, household practices related to drinking water (e.g., how it was collected and stored), physical characteristics of water storage containers, and self-reported AGI. Additionally, water samples were collected from all identified drinking water containers in homes and analyzed for presence of Escherichia coli and total coliforms. Despite municipally treated tap water being available in all homes, 77.6% of households had alternative sources of drinking water stored in containers, and of these containers, 25.2% tested positive for total coliforms. The use of transfer devices and water dippers (i.e., smaller bowls or measuring cups) for the collection and retrieval of water from containers were both significantly associated with increased odds of total coliform presence in stored water (OR_{transfer device} = 3.4, 95% CI 1.2–11.7; OR_dipper = 13.4, 95% CI 3.8–47.1). Twenty-eight-day period prevalence of self-reported AGI during the month before the survey was 17.2% (95% CI 13.0–22.5), which yielded an annual incidence rate of 2.4 cases per person per year (95% CI 1.8–3.1); no water-related risk factors were significantly associated with AGI. Considering the high prevalence of, and risk factors associated with, indicator bacteria in drinking water stored in containers, potential exposure to waterborne pathogens may be minimized through interventions at the household level.     

Packed in-tube solid phase microextraction with graphene oxide supported on aminopropyl silica: Determination of target triazines in water samples

On-line in-tube solid phase microextraction (in-tube SPME) coupled to high performance liquid chromatography and tandem mass spectrometry (HPLC-MS/MS) was successfully applied to the determination of selected triazines in water samples. The method based on the employment of a packed column containing graphene oxide (GO) supported on aminopropyl silica (Si) showed that the extraction phase has a high potential for triazines extraction aiming to its physical-chemical properties including ultrahigh specific surface area, good mechanical and thermal stability and high fracture strength. Injection volume and loading time were both investigated and optimized. The method validation using Si-GO to extract and concentrate the analytes showed satisfactory results, good sensitivity, good linearity (0.2–4.0 µg L^?1) and low detection limits (1.1–2.9 ng L^?1). The high extraction efficiency was determined with enrichment factors ranging from 1.2–2.9 for the lowest level, 1.3–4.9 intermediate level and 1.2–3.0 highest level (n = 3). Although the analytes were not detected in the real samples evaluated, the method has demonstrated to be efficient through its application in the analysis of spiked triazines in ground and mineral water samples.     

Factors affecting the quantitative uncertainty of the estimated short-term intake. Part I—Calculation methods

ABSTRACT

The calculation of the combined uncertainty of the international estimated short-term intake (IESTI) of ethephon residues in apples is shown as an example. The ethephon residues in apples were reported by the Joint FAO (Food and Agriculture Organization of the United Nations)/WHO (World Health Organization) Meeting on Pesticide Residues (JMPR). The apple consumption data were taken from the IESTI (international short-term intake) calculation template used by the JMPR. The IESTI was calculated with the currently used method (case 2a) and a proposed one recommended by the EFSA (European Food Safety Authority)/RIVM (Dutch National Institute for Public Health) Scientific Workshop co-sponsored by FAO and WHO. In this example, the ratio of IESTI_proposed/IESTI_current and their combined relative uncertainty are about 2.8, and 1.7, respectively. The larger IESTI and uncertainty obtained with the proposed equation are the consequence of calculation only with the large portion (LP) instead of its combination with unit mass, and the MRL instead of the highest residue (HR). The LP is the major contributor to the combined uncertainty. Both the calculated IESTI and its combined uncertainty depend on the actual food – pesticide residue combination, and should be calculated for each case.     

Feasibility of coupling a thermal/optical carbon analyzer to a quadrupole mass spectrometer for enhanced PM2.5 speciation

A thermal/optical carbon analyzer (TOA), normally used for quantification of organic carbon (OC) and elemental carbon (EC) in PM_2.5 (fine particulate matter) speciation networks, was adapted to direct thermally evolved gases to an electron impact quadrupole mass spectrometer (QMS), creating a TOA-QMS. This approach produces spectra similar to those obtained by the Aerodyne aerosol mass spectrometer (AMS), but the ratios of the mass to charge (m/z) signals differ and must be remeasured using laboratory-generated standards. Linear relationships are found between TOA-QMS signals and ammonium (NH₄⁺), nitrate (NO₃^?), and sulfate (SO₄^2-) standards. For ambient samples, however, positive deviations are found for SO₄^2-, compensated by negative deviations for NO₃^?, at higher concentrations. This indicates the utility of mixed-compound standards for calibration or separate calibration curves for low and high ion concentrations. The sum of the QMS signals across all m/z after removal of the NH₄⁺, NO₃^?, and SO₄^2- signals was highly correlated with the carbon content of oxalic acid (C?H?O?) standards. For ambient samples, the OC derived from the TOA-QMS method was the same as the OC derived from the standard IMPROVE_A TOA method. This method has the potential to reduce complexity and costs for speciation networks, especially for highly polluted urban areas such as those in Asia and Africa.

Implications: Ammonium, nitrate, and sulfate can be quantified by the same thermal evolution analysis applied to organic and elemental carbon. This holds the potential to replace multiple parallel filter samples and separate laboratory analyses with a single filter and a single analysis to account for a large portion of the PM_2.5 mass concentration.     

Carbon and nitrogen mineralization in Vertisol as mediated by type and placement method of residue

Selection of appropriate residue application method is essential for better use of biomass for soil and environmental health improvement. A laboratory incubation experiment was conducted for 75 days to investigate C and N mineralization of residues of soybean (Glycine max L.), chickpea (Cicer arietinum L.), maize (Zea mays L.), and wheat (Triticum aestivum L.) placed on the soil surface and incorporated into the soil. The residue of soybean and chickpea had a greater decomposition rate than that of maize and wheat, despite of their placements. Higher rate of decomposition of the residue of soybean and chickpea was recorded when it was kept on the soil surface while soil incorporation of residue of wheat and maize resulted in faster decomposition. Therefore, these findings could be used as guidelines for management of crop residue application in farmland to improve soil and environmental quality.     

Monitoring of meteorological and hydrological droughts in the Vistula basin (Poland)

The article presents the course of meteorological droughts in Vistula subcatchments in years 1981–2010 and their influence on the occurrence of hydrological droughts. Using the Standardized Precipitation Index (SPI) as an indicator of meteorological drought on the one hand and the Standardized Water-level Index (SWI) and Standardized Runoff Index (SRI) as indicators of hydrological drought on the other, the mutual relationships between precipitation conditions and hydrological conditions were evaluated, as well as the relationships between the two drought types. Studies were conducted for three cumulative periods of these indices, of 12, 24, and 48 months. It was determined that meteorological droughts occurred earliest in the north-western and central part of the basin, and latest in areas lying above 300 m a.s.l. and in the south of Poland. Total duration, depending on the cumulative period, for SPI comprised from 38 to 41% of the analyzed period and for SWI (35–47%) and SRI (24–51%). The strongest relationships were identified in the central part of the Vistula (0.8?<?r?<?0.85), while the weakest relationships were recorded in the foothill region (r?<?0.5). There were also indicated non-climate-related factors influencing those relationships (underground reservoirs, diverse Vistula water resource usage for municipal and industrial intake).     

Impact of artificial lagoons on seawater quality: evidence from 7 years of physicochemical seawater monitoring

Seven years (2010–2016) of data on the basic physicochemical properties of seawater, temperature, salinity, dissolved oxygen (DO), nutrients, chlorophyll a (Chl a), and hydrocarbons from two lagoons were used to evaluate the impact of the anthropogenic activities inside the lagoon on the water quality and to explore the relationship of any impact from the lagoons’ design. Statistical analysis shows the modification in water quality inside the lagoon compared to the ambient seawater is particularly evident for nitrate, silicate, and Chl a. The modification is attributed to the extensive boat activities in the lagoons and the limited water exchange between the lagoons and ambient seawater. However, the impact to both lagoons is generally limited to inside the lagoons. The oligotrophic state of the two lagoons was evaluated and it was found that the most marked code violations were found in DIN inside both lagoons. In order to explore the design importance, the water exchange and overall water quality was compared between the two lagoons. This study highlights the importance of an environmental design study before the construction of any lagoon project. Proper design would maintain acceptable water quality inside the lagoons, critical for environmental health and supporting continued recreational activities.     

A review of regulations and guidelines related to winter manure application

Winter manure application elevates nutrient losses and impairment of water quality as compared to manure applications in other seasons. In conjunction with reviewing global distribution of animal densities, we reviewed worldwide mandatory regulations and voluntary guidelines on efforts to reduce off-site nutrient losses associated with winter manure applications. Most of the developed countries implement regulations or guidelines to restrict winter manure application, which range from a regulative ban to guidelines based upon weather and field management conditions. In contrast, developing countries lack such official directives, despite an increasing animal production industry and concern over water quality. An analysis of five case studies reveals that directives are derived from a common rationale to reduce off-site manure nutrient losses, but they are also affected by local socio-economic and biophysical considerations. Successful programs combine site-specific management strategies along with expansion of manure storage to offer farmers greater flexibility in winter manure management.