Biogenic polycyclic aromatic hydrocarbons in sediments of the San Joaquin River in California (USA), and current paradigms on their formation

Biogenic perylene and higher plant pentacyclic triterpenoid-derived alkylated and partially aromatized tetra- and pentacyclic derivatives of chrysene (3,4,7-trimethyl- and 3,3,7-trimethyl-1,2,3,4-tetrahydrochrysene, THC) and picene (1,2,9-trimethyl- and 2,2,9-trimethyl-1,2,3,4-tetrahydropicene, THP) were two- to four-fold more abundant than pyrogenic PAH in two sediment cores from the San Joaquin River in Northern California (USA). In a core from Venice Cut (VC), located in the river, PAH concentrations varied little downcore and the whole-core PAH concentration (biogenics?+?pyrogenics) was 250.6?±?73.7 ng g^?1 dw; biogenic PAH constituted 67?±?4 % of total PAH. THC were 26?±?9 % of total biogenic PAH, THP were 36?±?7 %, and perylene was 38?±?7 %. PAH distributions in a core from Franks Tract (FT), a former wetland that was converted to an agricultural tract in the late 1800s and flooded in 1938, were more variable. Surface sediments were dominated by pyrogenic PAH so that biogenic PAH were only ~30 % of total PAH. Deeper in the core, biogenic PAH constituted 60–93 % of total PAH; THC, THP and perylene were 31?±?28 %, 24?±?32 %, and 45?±?36 % of biogenic PAH. At 100–103 cm depth, THP constituted 80 % of biogenic PAH and at 120–123 cm perylene was 95 % of biogenic PAH. Current concepts related to precursors and transformation processes responsible for the diagenetic generation of perylene and triterpenoid-derived PAH are discussed. Distributions of biogenic PAH in VC and FT sediments suggest that they may not form diagenetically within these sediments but rather might be delivered pre-formed from the river’s watershed.     

Are seed and dispersal characteristics of plants capable of predicting colonization of post-mining sites?

Seed characteristics play an important role in the colonization and subsequent persistence of species during succession in disturbed sites and thus may contribute to being able to predict restoration success. In the present study, we investigated how various seed characteristics participated in 11 spontaneous successional series running in different mining sites (spoil heaps, extracted sand and sand-gravel pits, extracted peatlands, and stone quarries) in the Czech Republic, Central Europe. Using 1864 samples from 1- to 100-years-old successional stages, we tested whether species optimum along the succession gradient could be predicted using 10 basic species traits connected with diaspores and dispersal. Seed longevity, diaspore mass, endozoochory, and autochory appeared to be the best predictors. The results indicate that seed characteristics can predict to a certain degree spontaneous vegetation succession, i.e., passive restoration, in the mining sites. A screening of species available in the given landscape (regional and local species pools) may help to identify those species which would potentially colonize the disturbed sites. Extensive databases of species traits, nowadays available for the Central European flora, enable such screening.     

Impact of temperature on the dynamics of organic matter and on the soil-to-plant transfer of Cd,Zn and Pb in a contaminated agricultural soil

Predicting the soil-to-plant transfer of metals in the context of global warming has become a major issue for food safety. It requires a better understanding of how the temperature alters the bioavailability of metals in cultivated soils. This study focuses on one agricultural soil contaminated by Cd, Zn and Pb. DGT measurements were performed at 10, 20 and 30 °C to assess how the bioavailability of metals was affected by a rise in soil temperature. A lettuce crop was cultivated in the same conditions to determine if the soil-to-plant transfer of metals increased with a rise in soil temperature. A gradual decline in Cd and Zn bioavailability was observed from 10 to 30 °C, which was attributed to more intense complexation of metals in the pore water at higher temperatures. Together with its aromaticity, the affinity of dissolved organic matter (DOM) for metals was indeed suspected to increase with soil temperature. One main output of the present work is a model which satisfactorily explains the thermal-induced changes in the characteristics of DOM reported in Cornu et al. (Geoderma 162:65–70, 2011) by assuming that the mineralization of initial aliphatic compounds followed a first-order reaction, increased with soil temperature according to the Arrhenius law, and due to a priming effect, led to the appearance of aromatic molecules. The soil-to-plant transfer of Cd and Zn was promoted at higher soil temperatures despite a parallel decrease in Cd and Zn bioavailability. This suggests that plant processes affect the soil-to-plant transfer of Cd and Zn the most when the soil temperature rises.     

Use of modeling to protect,plan, and manage water resources in catchment areas

The degradation of water resources by diffuse pollution, mainly due to nitrate and pesticides, is an important matter for public health. Restoration of the quality of natural water catchments by focusing on their catchment areas is therefore a national priority in France. To consider catchment areas as homogeneous and to expend an equal effort on the entire area inevitably leads to a waste of time and money, and restorative actions may not be as efficient as intended. The variability of the pedological and geological properties of the area is actually an opportunity to invest effort on smaller areas, simply because every action is not equally efficient on every kind of pedological or geological surface. Using this approach, it is possible to invest in a few selected zones that will be efficient in terms of environmental results. The contributive hydraulic areas (CHA) concept is different from that of the catchment area. Because the transport of most of the mobile and persistent pollutants is primarily driven by water circulation, the concept of the CHA is based on the water pathway from the surface of the soil in the catchment area to the well. The method uses a three-dimensional hydrogeological model of surface and groundwater integrated with a geographic information system called Watermodel. The model calculates the contribution (m³/h or %) of each point of the soil to the total flow pumped in a well. Application of this model, partially funded by the Seine Normandy Basin Agency, to the catchment of the Dormelles Well in the Cretaceous chalk aquifer in the Orvanne valley, France (catchment area of 23,000 ha at Dormelles, county 77), shows that 95 % of the water pumped at the Dormelles Well comes from only 26 % of the total surface area of the catchment. Consequently, an action plan to protect the water resource will be targeted at the 93 farmers operating in this source area rather than the total number of farmers (250) across the entire 23,000 ha. Another model, developed from Epiclès© software, permits the calculation of the under-root nitrate concentrations for each field based on soil type, climate, and farming practices. When the Watermodel and Epiclès© are coupled, nitrate transfers from the soil to the catchment and the river can be modeled. In this study, the initial pollution due to the actual farming practices was simulated and we were also able to estimate the efficiency of the agronomic action plan by testing several scenarios and calculating the time needed to reach the target nitrate concentration in the well.     

Biodegradability of algal-derived organic matter in a large artificial lake by using stable isotope tracers

In order to understand the biodegradability of algal-derived organic matter, biodegradation experiments were conducted with ¹³C and ¹⁵N-labeled natural phytoplankton and periphytic algal populations in experimental conditions for 60 days. Qualitative changes in the dissolved organic matter were also determined using parallel factor analysis and the stable carbon isotopic composition of the hydrophobic dissolved organic matter through the experimental period. Although algal-derived organic matter is considered to be easily biodegradable, the initial amounts of total organic carbon newly produced by phytoplankton and periphytic algae remained approximately 16 and 44 % after 60 days, respectively, and about 22 and 43 % of newly produced particulate nitrogen remained. Further, the dissolved organic carbon derived from both algal populations increased significantly after 60 days. Although the dissolved organic matter gradually became refractory, the contributions of the algal-derived organic matter to the dissolved organic matter and hydrophobic dissolved organic matter increased. Our laboratory experimental results suggest that algal-derived organic matter produced by phytoplankton and periphytic algae could contribute significantly to the non-biodegradable organic matter through microbial transformations.     

Fluoride in weathered rock aquifers of southern India: Managed Aquifer Recharge for mitigation

Climatic condition, geology, and geochemical processes in an area play a major role on groundwater quality. Impact of these on the fluoride content of groundwater was studied in three regions—part of Nalgonda district in Telangana, Pambar River basin, and Vaniyar River basin in Tamil Nadu, southern India, which experience semi-arid climate and are predominantly made of Precambrian rocks. High concentration of fluoride in groundwater above 4 mg/l was recorded. Human exposure dose for fluoride through groundwater was higher in Nalgonda than the other areas. With evaporation and rainfall being one of the major contributors for high fluoride apart from the weathering of fluoride rich minerals from rocks, the effect of increase in groundwater level on fluoride concentration was studied. This study reveals that groundwater in shallow environment of all three regions shows dilution effect due to rainfall recharge. Suitable managed aquifer recharge (MAR) methods can be adopted to dilute the fluoride rich groundwater in such regions which is explained with two case studies. However, in deep groundwater, increase in fluoride concentration with increase in groundwater level due to leaching of fluoride rich salts from the unsaturated zone was observed. Occurrence of fluoride above 1.5 mg/l was more in areas with deeper groundwater environment. Hence, practicing MAR in these regions will increase the fluoride content in groundwater and so physical or chemical treatment has to be adopted. This study brought out the fact that MAR cannot be practiced in all regions for dilution of ions in groundwater and that it is essential to analyze the fluctuation in groundwater level and the fluoride content before suggesting it as a suitable solution. Also, this study emphasizes that long-term monitoring of these factors is an important criterion for choosing the recharge areas.     

Dry reforming of methane to syngas: a potential alternative process for value added chemicals—a techno-economic perspective

During the past decade, there has been increasing global concern over the rise of anthropogenic CO₂ emission into the Earth’s atmosphere (J Air Waste Manage Assoc 53:645–715, 2003). The utilization of CO₂ to produce any valuable product is need of the hour. The production of syngas from CO₂ and CH₄ seems to be one of the promising alternatives in terms of industrial utilization, as it offers several advantages: (a) mitigation of CO₂, (b) transformation of natural gas and CO₂ into valuable syngas, and (c) producing syngas with H₂/CO ratio 1 which may further be used for the production of valuable petrochemicals (J Air Waste Manage Assoc 53:645–715, 2003). A conceptual design for the production of synthesis gas by dry reforming of methane is presented here. An economic assessment of this process with an integrated methanol production section as a case was conceptualized and compared with the conventional steam methane reforming route to produce methanol. The economic study indicated that dry reforming of natural gas/methane is a competitive process with lower operating and capital costs in comparison with steam reforming assuming negligible cost of CO₂ import.     

Organic pollution of the Büyük Menderes River,Turkey and effects on aquaculture

Water quality was measured at eight stations on the Buyuk Menderes River in Turkey (Ad?güzel dam, Yenice regülator, Sarayköy bridge, Feslek regülator, Yenipazar bridge, Ayd?n bridge, Koçarl? bridge, Söke regülator) between 2000 and 2013 in February, April, June, August, October and December. The resulting data were evaluated in terms of biochemical oxygen demand (BOD), chemical oxygen demand (COD), dissolved oxygen (DO), ammoniac–nitrogen (NH₃–N), nitrite–nitrogen (NO₂–N), nitrate–nitrogen (NO₃–N) and orthophosphate (o-PO₄) aquaculture. According to the analysis, while river water pollution generally varied during each year, samples from certain measurement points demonstrated high pollution levels throughout the year. In this study, water parameters were classified according to the “Turkish water pollution control regulation.” The studied parameters are also compared with TS 266 and WHO guidelines. While levels at Sarayköy station were generally higher than other stations, values at Ad?güzel dam were the lowest, giving it the best water quality of the eight stations. The highest values on a yearly basis were obtained in 2007 due to the severe drought in the Menderes basin within which irrigation water levels fell to 4255 m³/ha. The BOD, COD levels are the lowest in 2009 and highest in 2007; the DO level is lowest in 2007 and highest in 2009; NH₃–N, NO₂–N, and NO₃–N parameters are the lowest in 2007 and highest in 2009; and the o-PO₄ are at the lowest level in 2004 and seen as the highest in 2007. Analysis of the data was performed by SPSS 21 statistics program. One direction ANOVA was applied to the data, which were also subject to Tukey multiple comparison tests. Differences between groups were evaluated at p?<?0.05. Box–plot graphs were used to demonstrate the data distribution. In the study, it was analyzed, the effect of fish species and pollution involved in the Büyük Menderes River so far on fish species.