全文获取类型
收费全文 | 641篇 |
免费 | 26篇 |
国内免费 | 151篇 |
专业分类
安全科学 | 117篇 |
废物处理 | 28篇 |
环保管理 | 57篇 |
综合类 | 286篇 |
基础理论 | 80篇 |
污染及防治 | 162篇 |
评价与监测 | 24篇 |
社会与环境 | 27篇 |
灾害及防治 | 37篇 |
出版年
2024年 | 4篇 |
2023年 | 7篇 |
2022年 | 28篇 |
2021年 | 25篇 |
2020年 | 23篇 |
2019年 | 25篇 |
2018年 | 19篇 |
2017年 | 31篇 |
2016年 | 28篇 |
2015年 | 24篇 |
2014年 | 31篇 |
2013年 | 44篇 |
2012年 | 40篇 |
2011年 | 46篇 |
2010年 | 50篇 |
2009年 | 49篇 |
2008年 | 49篇 |
2007年 | 44篇 |
2006年 | 36篇 |
2005年 | 22篇 |
2004年 | 19篇 |
2003年 | 19篇 |
2002年 | 21篇 |
2001年 | 21篇 |
2000年 | 24篇 |
1999年 | 15篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 11篇 |
1995年 | 4篇 |
1994年 | 10篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有818条查询结果,搜索用时 15 毫秒
51.
Shipeng Dong Liang Mao Siqiang Luo Lei Zhou Yiping Feng Shixiang Gao 《Environmental science and pollution research international》2014,21(3):2358-2366
Concentrations of aqueous-phase nonylphenol (NP), a well-known endocrine-disrupting chemical, are shown to be reduced effectively via reaction with lignin peroxidase (LiP) or horseradish peroxidase (HRP) and hydrogen peroxide. We systematically assessed their reaction efficiencies at varying conditions, and the results have confirmed that the catalytic performance of LiP toward NP was more efficient than that of HRP under experimental conditions. Mass spectrum analysis demonstrated that polymerization through radical–radical coupling mechanism was the pathway leading to NP transformation. Our molecular modeling with the assistance of ab initio suggested the coupling of NP likely proceeded via covalent bonding between two NP radicals at their unsubstituted carbons in phenolic rings. Data from acute immobilization tests with Daphnia confirm that NP toxicity is effectively eliminated by LiP/HRP-catalyzed NP removal. The findings in this study provide useful information for understanding LiP/HRP-mediated NP reactions, and comparison of enzymatic performance can present their advantages for up-scale applications in water/wastewater treatment. 相似文献
52.
Vegetation type and density exhibited a considerable patchy distribution at very local scales in the Yellow River Delta, due to the spatial variation of soil salinity and water scarcity. We proposed that soil respiration is affected by the spatial variations in vegetation type and soil chemical properties and tested this hypothesis in three different vegetation patches (Phragmites australis, Suaeda heteroptera and bare soil) in winter (from November 2010 to April 2011). At diurnal scale, soil respiration all displayed single-peak curves and asymmetric patterns in the three vegetation patches; At seasonal scale, soil respiration all declined steadily until February, and then increased to a peak in next April. But, the magnitude of soil respiration showed significant differences among the three sites. Mean soil respiration rates in winter were 0.60, 0.45 and 0.17 μmol CO(2) m(-2) s(-1) for the Phragmites australis, Suaeda heteroptera and bare soil, respectively. The combined effect of soil temperature and soil moisture accounted for 58-68 % of the seasonal variation of winter soil respiration. The mean soil respiration revealed positive and linear correlations with total N, total N and SOC storages at 0-20 cm depth, and plant biomass among the three sites. We conclude that the patchy distribution of plant biomass and soil chemical properties (total C, total N and SOC) may affect decomposition rate of soil organic matter in winter, thereby leading to spatial variations in soil respiration. 相似文献
53.
It is well known that model-building of chlorine decay in real water distribution systems is difficult because chlorine decay is influenced by many factors (e.g., bulk water demand, pipe-wall demand, piping material, flow velocity, and residence time). In this paper, experiments were run to investigate the kinetic model of chlorine decay and the formation model of trihalomethanes (THMs) in pilot-scale water distribution systems. Experimental results show that the rate constants of chlorine decay, including wall decay and bulk decay, increasing with temperature. Moreover, the kinetic model of chlorine decay and the formation model of THMs describe experiment data of pilot-scale water distribution systems. The effect of different piping material on chlorine decay and THMs formation were also investigated. The rate constants of chlorine decay are ranked in order: stainless steel pipe, ductile iron pipe, and last, polyethelene pipe because wall decay is the largest in stainless steel pipe than that in other piping material. Correspondingly, the rate of THMs formation follows the order of stainless steel pipe, ductile iron pipe, and last, polyethelene pipe because of less chlorine in bulk water reacting with the trihalomethane formation potential (THMFP). 相似文献
54.
西安市城市主干道路面径流初期冲刷效应 总被引:3,自引:0,他引:3
以西安市城市主干道南二环太白路高架桥为路面径流采样区域,采用人工等时间间隔采样方法,在桥梁排水立管对2010年9—11月的3场径流事件进行全程采样,测试径流过程SS、COD、溶解性COD、NH3-N、Pb、溶解性Pb、Zn和溶解性Zn的浓度变化,研究路面径流的初期冲刷效应及其影响因素。结果表明,西安市城市主干道路面径流污染严重,降雨数小时后的末期径流仍具有较高的污染水平;径流过程污染物浓度变化规律与其赋存形态有关,SS、COD、Pb等以颗粒态为主的污染物的浓度随雨强变化剧烈波动,NH3-N、溶解态COD、溶解态Zn等以溶解态为主的污染物浓度变化受雨强影响较小,随径流过程呈逐渐减小趋势;路面径流初期冲刷现象并非普遍存在,与污染物的赋存状态和场次降雨特征密切相关,溶解态污染物易于出现初期冲刷现象,颗粒态污染物是否出现初期冲刷与场次降雨特征有关;测试的3场径流事件初期30%的径流携带的SS、COD、溶解性COD、NH3-N、Pb、Zn和溶解性Zn的负荷占场次径流总负荷的比例分别为21.8%~50.0%、25.5%~49.3%、36.3%~52.6%、52.6%~66.7%、26.8%~45.0%、27.2%~63.4%和36.2%~62.6%,表明仅对初期径流进行治理无法实现对西安市路面径流污染的有效控制。 相似文献
55.
将一株产絮酵母菌(编号B-02号)发酵后的废菌体制成生物吸附剂,研究该生物吸附剂对废水中Cd2+的生物吸附特性。结果表明:(1)pH值对Cd2+会产生较大的影响,偏酸性(pH=4~6)条件利于吸附;该吸附剂对Cd2+吸附速率较快,8~10 min就可达到吸附平衡;(2)吸附剂的吸附动力学符合二级动力学模型,吸附Cd2+的实验数据对Langmuir等温式的拟合情况良好,吸附剂吸附Cd2+的最大吸附量为70.752 mg/g。用0.5 mol/L HNO3对吸附Cd2+的酵母菌进行解吸,解吸率可达89.7%。 相似文献
56.
57.
Afforestation of agricultural lands has been one of the major land use changes in China in recent decades. To better understand
the effect of such land use change on soil quality, we investigated selected soil physical, chemical and microbial properties
(0–15 cm depth) in marginal agricultural land and a chronosequence of poplar (Populus
euramericana cv. ‘N3016’) plantations (5-, 10-, 15- and 20-years old) in a semi-arid area of Northeast China. Soil bulk density significantly
declined after conversion of agricultural lands to poplar plantations. Soil total organic carbon (TOC) and nitrogen (TN) concentrations,
microbial biomass C (MBC) and potential N mineralization rate (PNM) decreased initially following afforestation of agricultural
lands, and then increased with stand development. However, soil metabolic quotient (qCO2) exhibited a reverse trend. In addition, soil particulate organic matter C (POM-C) and N (POM-N) concentrations showed no
significant changes in the first 10 years following afforestation, and then increased with stand age. These findings demonstrated
that soil quality declined initially following afforestation of agricultural lands in semi-arid regions, and then recovered
with stand development. Following 15 years of afforestation, many soil quality parameters recovered to the values found in
agricultural land. We propose that change in soil quality with stand age should be considered in determining optimum rotation
length of plantations and best management practices for afforestation programs. 相似文献
58.
电力行业的节能减排与低碳经济 总被引:1,自引:0,他引:1
中国能源结构以煤为主,火电行业是碳排放量的主体,面对低碳经济的发展模式,电力行业势必将成为CO2减排的主力军。目前,火电行业通过"上大压小"政策,实现结构减排;通过提高电力工业的烟气脱硫,实现工程减排;通过扩大清洁能源的比例,减少煤炭消耗总量,实现总量减排。使用清洁能源是实现碳减排的有效途径。指出了电力行业"节能减排"的现状和措施,分析了电力行业在"低碳经济"中所面临的新形势,并对低碳电力技术的研究与运用进行了展望,阐述了通过利用清洁能源促进碳减排的迫切性和必要性。 相似文献
59.
60.
Xiaojiao Chen Minjian Chen Bo Xu Rong Tang Xiumei Han Yufeng Qin Bin Xu Bo Hang Zhilei Mao Weiwei Huo Yankai Xia Zhengfeng Xu Xinru Wang 《Chemosphere》2013
Widespread use of phenols has led to ubiquitous exposure to phenols. In experimental animals, phenols increased resorptions, reduced live litter size and fetal body weights. However, there are limited epidemiological evidences of the relationships between exposure to phenols and pregnancy outcomes. We evaluated the associations between parental urinary levels of various phenols and spontaneous abortion in a Chinese population residing in the middle and lower reaches of the Yangtze River. A case-control study was conducted that included 70 case couples with medically unexplained spontaneous abortion and 180 control couples who did not have a history of spontaneous abortion and had at least one living child. Both parental urinary phenols were measured by ultra-high performance liquid chromatography-tandem mass spectrometry including bisphenol A (BPA), benzophenone-3 (BP-3), 2,3,4-trichlorophenol (2,3,4-TCP), pentachlorophenol (PCP), 4-n-octylphenol (4-n-OP) and 4-n-nonylphenol (4-n-NP). Compared with the low exposure group, there was an increased risk of spontaneous abortion with high paternal urinary PCP concentration [odds ratio (OR) = 2.09, 95% Confidence Interval (CI), 1.05–4.14], and maternal exposure to 4-n-OP and alkylphenol(s) also significantly increased the risk of spontaneous abortion (OR = 2.21, 95% CI, 1.02–4.80; OR = 2.81, 95% CI, 1.39–5.65, respectively). Our study firstly provides the evidence that paternal PCP exposure, maternal 4-n-OP and alkylphenol(s) exposure are associated with spontaneous abortion in humans. 相似文献