Decomposition analysis of PM2.5 emissions based on LMDI and Tapio decoupling model: study of Hunan and Guangdong

Environmental Science and Pollution Research - This paper takes energy consumption PM2.5 emission as research object, and quantitatively analyzes the PM2.5 emission level in Hunan and Guangdong...     

羧甲基纤维素抑尘剂的制备及其应用研究

以羧甲基纤维素、丙烯酸丁酯、甲基丙烯酸甲酯为原料,用溶液聚合法制备出一种环保软膜抑尘剂.探讨了添加甘油、辛癸基葡糖苷对抑尘剂吸水性能、润湿性能的变化以及m(甘油):m(辛癸基葡糖苷)以不同配比加入抑尘剂后对粉尘含水率的影响.经傅里叶红外光谱、X-射线衍射仪、扫描电子显微镜、透射电子显微镜对制备的产物进行结构表征和形貌的分析.对抑尘剂的性能:耐风蚀性、温度适应性进行了测试.结果表明:当m(甘油):m(辛癸基葡糖苷)为2:3,室温时粉尘含水率达15.8%、50℃粉尘含水率仍可达11.7%;经3 h(15 m/s)风速吹扫,粉尘损失率仅为2.3%.     

崇明岛小白鹭鸟卵中有机磷阻燃剂污染特征

鸟卵可用于环境质量的生物监测.从崇明岛东部若干林地采集小白鹭(Egretta garzetta)卵样品10个,用液相色谱-串联质谱联用仪(LC-MS/MS)测定了样品中10种常见有机磷阻燃剂(OPFRs)的含量,分析了其分布特征和来源.结果表明,除三辛基磷酸酯(TEHP)和三氯乙基磷酸酯(TCEP)外,其余8种OPFRs在小白鹭卵中均有检出,OPFRs的总含量为49.5～142.8 ng·g~(-1)(以湿重计,下同),均值为78.6 ng·g~(-1);其中,三丁基磷酸酯(TNBP)、三异丁基磷酸酯(TIBP)和三邻甲苯磷酸酯(TMPP)含量较为丰富,分别为(26.3±10.1)、(20.9±9.44)和(19.0±15.6) ng·g~(-1).不同鸟卵中OPFRs的赋存特征差异较大,主要受其环境含量水平、生物积累和放大能力及代谢能力的影响.崇明小白鹭卵样品中存在具有胚胎发育毒性的TMPP、三(1-氯-2-丙基)磷酸酯(TCIPP)、三丁氧基乙基磷酸酯(TBOEP)等,可能对其繁殖具有潜在影响,值得关注.     

An institutional theoretic investigation on the links between internationalization of Chinese manufacturers and their environmental supply chain management

Increased market internationalization with more and stricter environmental regulations in different countries has caused manufacturers to extend their environmental management practices to cover their supply chain partners. Thus, environmental supply chain management (ESCM) has become an important competitive and environmental strategy for manufacturers to pursue. China, as a global manufacturer, is also facing this balance of economic development with environmental protection. The literature remains unclear on whether internationalization is beneficial or costly when it comes to environmental management practices such as ESCM within China. Further insight into this issue will be useful for organizations in developing and emergent economies to more effectively prepare for internationalizing their operations and markets. Using internationalization drivers that propel the implementation of environmental management practices in the Chinese manufacturing industry, we applied cluster analysis to group a sample of 377 Chinese manufacturers surveyed in 2007 into three clusters: mature internationalization, emergent internationalization, and domestic-focused. Institutional theory within an internationalization context sets the theoretical foundation for evidence that the international environmentally oriented institutional drivers encountered are positively associated with the adoption of ESCM practices by Chinese manufacturers. We also find significant differences in the environmental, economic and operational performance outcomes across the three manufacturer clusters. We conclude that manufacturing organizations experiencing internationalization with a greater extent of adopting ESCM practices tend to perform better.     

Reliability of solid phase microextraction in estimating bioavailability of pyrene in soil

Solid phase microextraction (SPME) coupled with gas chromatography was employed to estimate bioavailability of pyrene in soils with different properties of textures, organic matter contents (SOM) and aging periods. Experimental results indicated that biodegradation rates increased from 0.10 (sandy loam) to 0.15 (silty loam) microg g-1 hr1. By contrast, biodegradation rate decreased from 0.10(1.3% SOM) to 0.04 (7.6% SOM) microg g-1hr1. The amounts of pyrene biodegraded decreased 27% when SOM was modified from 1.3 to 7.6%, indicating that distributions of pyrene in soils at biodegradation end points were affected by the SOM. Sequestration as measured by sonication extraction had evidently occurred in aged soil samples. SPME measurements slightly overestimated the amount of pyrene degraded by indigenous and seeded microorganisms, in soils with the different properties (correlation coefficient, R2= 0.74). The present study demonstrates that the SPME method can not replace biodegradation tests commonly used for predicting bioremediation efficacy.     

九岭幕阜山植物特有属的生物多样性保护研究

在实地调查和数量系统分析的基础上，论述了九岭幕阜山中国种子植物特有属的物各多样性，空间分布格局及其区系地理特征，探讨了本区与邻近地区中国种子植物特有属分布的联系及其重要地位，并对特有属的生物多样性保护提出了具体对策。     

流域跨界水污染纠纷对策研究

本文介绍了国内外广泛存在的严重流域跨界水污染纠纷问题，结合我国流域的实际情况，提出了污染物人工调控和污染物间接不影响等几个基本假定，构建了流域跨界水污染纠纷顺序决策模型，并用此模型解释了我国严重的流域跨界水污染纠纷问题；针对目前的状况，提出了改进污染物削减指令配额管理体制，建立合作协调管理体制的对策；通过对淮河流域跨界水污染纠纷的实证分析时比了两种管理体制的优劣，最后分析了影响合作协调管理体制的诸多因素。     

潮白河顺义段断流的生态损失评估

潮白河是北京市最重要的自然湿地之一。由于人类不合理的开发利用,河流生态系统严重退化,其中顺义段河道从1999年断流至今。在实地调研的基础上,建立了一套河道断流对区域社会-经济-自然复合生态系统发展造成的综合损失的定量评估方法体系,从社会-经济系统的年度产值损失、用于治理断流河道的年度恢复费用、断流河道非使用价值的年度损失三个方面,评价潮白河顺义段断流对研究区域造成的生态损失。研究结果表明,潮白河顺义段断流对研究区域复合生态系统造成的年度生态损失达8786．5万元,1995—2005年的十年间生态损失总值达87865万元。     

Emissions of C2 – C12 hydrocarbons in the Hsuehshan tunnel, Taiwan

The concentrations of 56 hydrocarbons from C2 to C12 were measured simultaneously in the southbound bore, the northbound bore and the exhaust air shafts of the Hsuehshan tunnel near Yilan, Taiwan for 12 days during 2007 and 2008. A total of 60 integrated air samples were collected using stainless steel canisters and analyzed using GC/FID and GC/MS. The five most abundant species in all samples were ethylene, acetylene, isopentane, propylene and toluene. The exit/entrance ratios of total non-methane hydrocarbons (NMHC) concentration were 7.8 and 4.8 for the southbound and northbound bores, respectively. Furthermore, the exhaust from the vertical shafts affects air quality in the neighborhood. The most abundant species of emission rate (ER) was toluene (21.93–42.89 mg/sec), followed by isopentane, ethylene, propylene and 1-butene, with ER ranging from 2.50 to 9.31 mg/sec. The species in the three exhaust air shafts showed that the reactivities of these emissions are similar to those of vehicle emissions. Notably, the control of emissions in the vertical shafts of the vehicle tunnel will be important in the future.     

Applying model simulation and photochemical indicators to evaluate ozone sensitivity in southern Taiwan

Ozone sensitivity was investigated using CAMx simulations and photochemical indicator ratios at three sites (Pingtung City, Chao- Chou Town, and Kenting Town) in Pingtung County in southern Taiwan during 2003 and 2004. The CAMx simulations compared fairly well with the hourly concentrations of ozone. Simulation results also showed that Pingtung City was mainly a volatile organic compounds (VOC)-sensitive regime, while Chao-Chou Town was either a VOC-sensitive or a NOx-sensitive regime, depending on the seasons. Measurements of three photochemical indicators (H2O2, HNO3, and NOy) were conducted, and simulated three transition ranges of H2O2/HNO3 (0.5–0.8), O3/HNO3 (10.3–16.2) and O3/NOy (5.7–10.8) were adopted to assess the ozone sensitive regime at the three sites. The results indicated that the three transition ranges yield consistent results with CAMx simulations at most times at Pingtung City. However, both VOC-sensitive and NOx-sensitive regimes were important at the rural site Chao-Chou Town. Kenting Town, a touring site at the southern end of Taiwan, was predominated by a NOx-sensitive regime in four seasons.