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901.
We determined the maximum amounts of added phenanthrene, chrysene, and 2,5-dichlorobiphenyl sorbed onto high-energy adsorption sites in a sediment on bi-solute experiments. The bi-solute pairs were phenanthrene/chrysene and phenanthrene/2,5-dichlorobiphenyl. On the bi-solute sorption experiments, one solute was introduced and equilibrated with sediment prior to addition of the second solute. The values for the maximum amounts adsorbed onto high-energy sites revealed that, after equilibration of the first solute, still some high-energy sites could be occupied by the second solute. Phenanthrene, chrysene, and 2,5-dichlorobiphenyl seem to share about 30% of the accessible high-energy adsorption sites in the sediment employed. 相似文献
902.
The temporal variability and bioaccumulation dynamics of individual PCBs were studied in a detritivorous fish (Sábalo: Prochilodus lineatus) collected from 1999 to 2005 in the polluted Buenos Aires coastal area. Fish muscles contain high concentrations of total PCBs (11+/-7.2, 4.6+/-3.4 or 19+/-13 microg g(-1), dry, fresh and lipid weight, respectively) reflecting chronic bioaccumulation from sewage-industrial particulates. On a temporal basis, lipid normalized PCBs concentrations peaked by the end of 2001-2002 coincident with the rainiest period over the last four decades and shortly after PCB prohibition in the country, reflecting massive discharges to the coastal ecosystem. PCB composition in fish muscles show a prevailing contribution of hexachlorobiphenyls (35+/-4.2%), followed by hepta (23+/-3.0%), penta (20+/-3.6%), tri-tetra (16+/-4.8%) and minor proportions of octa-decachlorobiphenyls (5.7+/-3.1%) similar to an Aroclor 1242-1254-1260 1:2:4 mixture. During 2001-2002 maxima fish showed an enrichment in tri-tetrachlorobiphenyls ( approximately 1242-1254-1260 1:1:1 mixture) denoting a fresher signature. Fish/settling material lipid-organic carbon accumulation factors (BSAFs: 2.4-46, average: 21+/-10) plotted against kow showed a parabolic trend (BSAFs=-0.38 log kow2 + 5.16 log kow -15.85; R2=0.46) maximizing at hexa, hepta and octachlorobiphenyl 203 with reduced bioaccumulation of a few hepta (170, 191) and most octa-decachlorobihenyls suggesting limited intestinal absorption. 相似文献
903.
Paz-Alberto AM Sigua GC Baui BG Prudente JA 《Environmental science and pollution research international》2007,14(7):498-504
Background, Aims and Scope The global problem concerning contamination of the environment as a consequence of human activities is increasing. Most of
the environmental contaminants are chemical by-products and heavy metals such as lead (Pb). Lead released into the environment
makes its way into the air, soil and water. Lead contributes to a variety of health effects such as decline in mental, cognitive
and physical health of the individual. An alternative way of reducing Pb concentration from the soil is through phytoremediation.
Phytoremediation is an alternative method that uses plants to clean up a contaminated area. The objectives of this study were:
(1) to determine the survival rate and vegetative characteristics of three grass species such as vetivergrass, cogongrass
and carabaograss grown in soils with different Pb levels; and (2) to determine and compare the ability of the three grass
species as potential phytoremediators in terms of Pb accumulation by plants.
Methods The three test plants: vetivergrass (Vetiveria zizanioides L.); cogongrass (Imperata cylindrica L.); and carabaograss (Paspalum conjugatum L.) were grown in individual plastic bags containing soils with 75 mg kg−1 (37.5 kg ha−1) and 150 mg kg−1 (75 kg ha−1) of Pb, respectively. The Pb contents of the test plants and the soil were analyzed before and after experimental treatments
using an atomic absorption spectrophotometer. This study was laid out following a 3 × 2 factorial experiment in a completely
randomized design.
Results On the vegetative characteristics of the test plants, vetivergrass registered the highest whole plant dry matter weight (33.85–39.39
Mg ha−1). Carabaograss had the lowest herbage mass production of 4.12 Mg ha−1 and 5.72 Mg ha−1 from soils added with 75 and 150 mg Pb kg−1, respectively. Vetivergrass also had the highest percent plant survival which meant it best tolerated the Pb contamination
in soils. Vetivergrass registered the highest rate of Pb absorption (10.16 ± 2.81 mg kg−1). This was followed by cogongrass (2.34 ± 0.52 mg kg−1) and carabaograss with a mean Pb level of 0.49 ± 0.56 mg kg−1. Levels of Pb among the three grasses (shoots + roots) did not vary significantly with the amount of Pb added (75 and 150
mg kg−1) to the soil.
Discussion Vetivergrass yielded the highest biomass; it also has the greatest amount of Pb absorbed (roots + shoots). This can be attributed
to the highly extensive root system of vetivergrass with the presence of an enormous amount of root hairs. Extensive root
system denotes more contact to nutrients in soils, therefore more likelihood of nutrient absorption and Pb uptake. The efficiency
of plants as phytoremediators could be correlated with the plants’ total biomass. This implies that the higher the biomass,
the greater the Pb uptake. Plants characteristically exhibit remarkable capacity to absorb what they need and exclude what
they do not need. Some plants utilize exclusion mechanisms, where there is a reduced uptake by the roots or a restricted transport
of the metals from root to shoots. Combination of high metal accumulation and high biomass production results in the most
metal removal from the soil.
Conclusions The present study indicated that vetivergrass possessed many beneficial characteristics to uptake Pb from contaminated soil.
It was the most tolerant and could grow in soil contaminated with high Pb concentration. Cogongrass and carabaograss are also
potential phytoremediators since they can absorb small amount of Pb in soils, although cogongrass is more tolerant to Pb-contaminated
soil compared with carabaograss. The important implication of our findings is that vetivergrass can be used for phytoextraction
on sites contaminated with high levels of heavy metals; particularly Pb.
Recommendations and Perspectives High levels of Pb in localized areas are still a concern especially in urban areas with high levels of traffic, near Pb smelters,
battery plants, or industrial facilities that burn fuel ending up in water and soils. The grasses used in the study, and particularly
vetivergrass, can be used to phytoremediate urban soil with various contaminations by planting these grasses in lawns and
public parks.
ESS-Submission Editor: Dr. Willie Peijnenburg (wjgm.peijnenburg@rivm.nl) 相似文献
904.
Thacker NP Nitnaware VC Das SK Devotta S 《Environmental science and pollution research international》2007,14(4):225-226
Samples of effluents, sludge, pulp, final products (paper) and soil were collected from the identified pulp and paper mills
in India. The samples were analysed for 2,3,7,8-tetrachloro-dibenzo-p-dioxin (2,3,7,8-TCDD) and other dioxin congeners and
precursors. Pulp and paper mills using chlorine for the bleaching process showed the presence of 2,3,7,8-TCDD in effluent
samples. In the effluent and pulp samples from mills where chlorine dioxide was used as a bleaching agent, the 2,3,7,8-TCDD
congener ranged from below the detection limit 0.05 to 0.12 ngL−1/ngg−1. The relative standard deviation of reproducibility and the percent recovery of 2,3,7,8-TCDD were 2.07 and 82.4% in pulp
and 2.8 and 92% in effluent, respectively. The 1,3,6,8-TCDD was the only other major dioxin congener found in the treated
and untreated effluent and sludge samples. However, dichlorobenzene, trichlorophenyl, and hexachlorobiphenyl were detected
in all samples. The formation of dioxins can be minimised by replacing chlorine with chlorine dioxide in bleaching processes
in pulp and paper mills. 相似文献
905.
906.
907.
Relation of waste generation and composition to socio-economic factors: a case study 总被引:3,自引:0,他引:3
Bandara NJ Hettiaratchi JP Wirasinghe SC Pilapiiya S 《Environmental monitoring and assessment》2007,135(1-3):31-39
To develop an effective waste management strategy for a given region, it is important to know the amount of waste generated
and the composition of the waste stream. Past research has shown that the amount of waste generated is proportional to the
population and the average mean living standards or the average income of the people. In addition, other factors may affect
the amount and composition of waste. These are climate, living habits, level of education, religious and cultural beliefs,
and social and public attitudes. This paper presents the findings of a study carried out in a suburban municipal area in Sri
Lanka to determine the solid waste generation rate and waste composition based on field surveys and to determine the related
socio-economic factors. A database was developed that included information on the quantity and composition of waste generated
in a sample of households in the study area over a time period. The collected data was analysed to relate waste generation
and composition data to various socio-economic factors. Over 400 sample households were selected for the study using a stratified
random sampling methodology based on municipal wards and property values. A technique that considers both the number of households
in a particular income group (property value range) and the standard deviation of property values within a given income group
was used to determine the appropriate sample size for each municipal ward. Through category and regression analyses, the quantities
of waste and waste composition were related to several socio-economic factors. The paper describes the basis for the sample
selection, the methodology adopted for data collection, the socio-economic parameters used for the analysis, and the relationships
developed from the analysis. 相似文献
908.
In recent years, suspended particle pollution has become a serious problem in Taiwan. The carbonaceous materials EC and OC
are play important roles in various atmospheric processes. The primary OC/EC ratio approach is applied to assess the contribution
of secondary organic aerosol (SOA) to the PM2.5 and PM10 mass at the Taichung harbor sampling site. The results indicated that the average EC and OC concentration were 1.06 and 6.50 μg
m−3, respectively, in fine particulate. And the average EC and OC concentration were 4.04 and 40.32 μg m−3, respectively, in coarse particulate at Taichung Harbor sampling site. In addition, and the average EC/OC rations was 8.72
in fine particle, respectively, at Taichung Harbor, Taiwan during summer and autumn period of 2005. The fine particle exhibited
high particulate concentrations in October, and lower concentration particulate occurred in August. And in this study OC and
EC concentrations in this study are compared with those in other cities. The results of EC and OC concentration in this study
are also compare with those other cities. 相似文献
909.
Previous work has shown that arsenic can accumulate in drinking water distribution system (DWDS) solids (Lytle et~al., 2004) when arsenic is present in the water. The release of arsenic back into the water through particulate transport and/or
chemical release (e.g. desorption, dissolution) could result in elevated arsenic levels at the consumers' tap. The primary
objective of this work was to examine the impact of pH and orthophosphate on the chemical release (i.e. desorption) of arsenic
from nine DWDS solids collected from utilities located in the Midwest. Arsenic release comparisons were based on the examination
of arsenic and other water quality parameters in leach water after contact with the solids over the course of 168~hours. Results
showed that arsenic was released from solids and suggested that arsenic release was a result of desorption rather than dissolution.
Arsenic release generally increased with increasing initial arsenic concentration in the solid and increasing pH levels (in
the test range of 7 to 9). Finally, orthophosphate (3 and 5 mg PO4/L) increased arsenic release at all pH values examined. Based on the study results, utilities with measurable levels of arsenic
present in their water should be aware that some water quality changes can cause arsenic release in the DWDS potentially resulting
in elevated levels at the consumer's tap. 相似文献
910.