Precipitation and river water chemistry of the Piracicaba River basin, southeast Brazil

Annual precipitation and river water volumes and chemistry were measured from 1995 to 1998 in a mesoscale agricultural area of southeast Brazil. Precipitation was mildly acidic and solute concentrations were higher in the west than in the east of the basin. Combustion products from biomass burning, automobile exhaust, and industry typically accumulate in the atmosphere from March until October and are responsible for seasonal differences observed in precipitation chemistry. In river waters, the volume-weighted mean (VWM) concentrations of major solutes at 10 sites across the basin were generally lower at upriver than at downriver sampling sites for most solutes. Mass balances for major solutes indicate that, as a regional entity, the Piracicaba River basin was a net sink of H+, PO4(3-), and NH4+, and a net source of other solutes. The main stem of the Piracicaba River had a general increase in solute concentrations from upriver to downriver sampling sites. In contrast, NO3- and NH4+ concentrations increased in the mid-reach sampling sites and decreased due to immobilization or utilization in the mid-reach reservoir, and there was denitrification immediately downriver of this reservoir. Compared with tributaries of the Chesapeake Bay estuary, the Piracicaba River is affected more by point-source inputs of raw sewage and industrial wastes than nonpoint agricultural runoff high in N and P. Inputs of N and C are responsible for a degradation of water quality at downriver sampling sites of the Piracicaba River drainage, and water quality could be considerably improved by augmenting sewage treatment.     

Plants as indicators of urban air pollution (ozone and trace elements) in Pisa, Italy

A biennial integrated survey, based on the use of vascular plants for the bioindication of the effects of tropospheric ozone, was performed in the area of Pisa (Tuscany, Central Italy). It also investigated the distribution of selected trace elements in plants and the data were compared with those obtained from the use of passive samplers, automatic analysers of ozone and lichen biodiversity. Photochemically produced ozone proved to be present during the warm season, with maximum hourly means surpassing 100 ppb: the use of supersensitive tobacco Bel-W3 confirmed the value of detailed, cost-effective, monitoring surveys. Trials with clover clones demonstrate that sensitive plants undergo severe biomass reduction in the current ozone regime. The mean NC-S (clover clone sensitive to ozone):NC-R (resistant) biomass ratio ranged from 0.7 (in 1999) to 0.5 (in 2000). The economic impact of these reductions deserves attention. The data obtained using passive ozone samplers exceeded those obtained using an automatic analyser. The mapping of epiphytic lichen biodiversity was not related to the geographical ozone distribution as can be seen from the tobacco's response. Lettuce plants grown under standardized conditions were used positively as bioaccumulators of trace elements: Pb was abundantly recovered, but a large portion of this element was removed by washing.     

Modeling the influence of climate change on the mass balance of polychlorinated biphenyls in the Adriatic Sea

Climate forcing is forecasted to influence the Adriatic Sea region in a variety of ways, including increasing temperature, and affecting wind speeds, marine currents, precipitation and water salinity. The Adriatic Sea is intensively developed with agriculture, industry, and port activities that introduce pollutants to the environment. Here, we developed and applied a Level III fugacity model for the Adriatic Sea to estimate the current mass balance of polychlorinated biphenyls in the Sea, and to examine the effects of a climate change scenario on the distribution of these pollutants. The model’s performance was evaluated for three PCB congeners against measured concentrations in the region using environmental parameters estimated from the 20th century climate scenario described in the Special Report on Emission Scenarios (SRES) by the IPCC, and using Monte Carlo uncertainty analysis. We find that modeled fugacities of PCBs in air, water and sediment of the Adriatic are in good agreement with observations. The model indicates that PCBs in the Adriatic Sea are closely coupled with the atmosphere, which acts as a net source to the water column. We used model experiments to assess the influence of changes in temperature, wind speed, precipitation, marine currents, particulate organic carbon and air inflow concentrations forecast in the IPCC A1B climate change scenario on the mass balance of PCBs in the Sea. Assuming an identical PCBs’ emission profile (e.g. use pattern, treatment/disposal of stockpiles, mode of entry), modeled fugacities of PCBs in the Adriatic Sea under the A1B climate scenario are higher because higher temperatures reduce the fugacity capacity of air, water and sediments, and because diffusive sources to the air are stronger.     

Two Measured Parameters Correlated to Participation Rates in Curbside Recycling Schemes in the UK

Local authorities in the United Kingdom are currently changing their approach towards recycling as they attempt to meet legislative targets. An important part of this drive is the provision of an effective curbside recycling service and it is vital to understand the parameters that influence the performance of the system offered. In this article, three primary datasets, collected from over 1400 households each, are examined for parameters correlated to participation rates. Two measured parameters were found that are not commonly identified in previous studies of curbside recycling schemes, and they are shown to merit further investigation as useful tools for planning purposes. One is the number of types of material collected; participation rates are greater for schemes collecting more materials. The second is the number of households situated on the same road; the lower the number, the higher the participation rate. In both cases, evidence of the measured correlation is presented, justifying their usefulness for planning. The multiple underlying factors causing the correlations are not identified here, but suggestions are made for further studies.     

Microbial Removal of Arsenic

Bangladesh is currently the subject of the world's largest mass arsenic poisoning in history. Groundwater throughout Bangladesh and West Bengal is contaminated with naturally occurring arsenic from the alluvial and deltaic sediments that form the region's aquifers. It has been estimated that 75 million people are at risk of developing health effects associated with the ingestion of arsenic. This project focuses on the use of microorganisms such as bacteria and algae to remove arsenic from water. Arsenic in the arsenite form was used in the studies. Experiments were conducted with a common alga and wastewater bacteria. A common green algae Scenedesmus abundans was used for determining arsenic uptake in batch experiments. Results of the experiments indicated that the algae biosorption could be modeled by the conventional Langmuir isotherm model. Algae morphology studies indicated that the algae cells were impacted due to the presence of arsenic as evidenced by clumping or loss of cell clusters. The wastewater bacteria also were capable of high percent of arsenic removal. Results indicate that microbial uptake of arsenic may be a viable method of pretreatment of arsenic contaminated water. However algae and sludge disposal would pose a problem and will have to be dealt with accordingly.     

波罗的海鳕鱼（Gadus morhua）中单氟和多氟烷基物质和总氟的时间变化趋势（1981-2013）

本文研究了1981~2013年间在波罗的海哥德兰东南部附近采集的鳕鱼（Gadus morhua）肝组织中28种单氟和多氟烷基物质（PFAS）的时间变化趋势。共检测到10种PFAS,其中∑28PFAS几何平均浓度范围为6.03~23.9 ng/g。全氟辛烷磺酸（PFOS）是PFAS的主要组成,且仍以每年3.4%的速度增长。大多数长链全氟烷基羧酸以每年3.9%~7.3%的速度增加,但全氟辛酸（PFOA）没有随着时间的推移而显著变化。全氟烃基酸前体——全氟辛烷磺酰胺（FOSA）和6:2氟端粒磺酸也被检出,其中前者以每年4.4%的速度下降,可能反映出其从2000年开始逐步淘汰。从2000年到2013年的交替时间趋势分析显示的趋势率略有不同。对于大多数化合物,其增长速度慢于其在整个时期的趋势。一个例外是全氟己烷磺酸盐（PFHxS）,从2000年开始以3.7%的速度增长,而从1981年开始以每年3.0%的速度增长。对样品总氟（TF）含量的分析揭示了大量未经鉴定的氟,但其组成（有机或无机）仍不清楚。个体PFAS浓度（PFOS除外）与肝脏体细胞指数呈显著负相关。此外,体长与PFOA和PFNA呈负相关,而与全氟癸酸盐（PFDoDA）和FOSA呈正相关。对海洋鱼类中PFAS的内分泌、免疫和代谢影响的进一步研究对于评估这些物质的环境风险至关重要。     

Impact of Construction Waste Disposal Charging Scheme on work practices at construction sites in Hong Kong

Waste management in the building industry in Hong Kong has become an important environmental issue. Particularly, an increasing amount of construction and demolition (C&D) waste is being disposed at landfill sites. In order to reduce waste generation and encourage reuse and recycling, the Hong Kong Government has implemented the Construction Waste Disposal Charging Scheme (CWDCS) to levy charges on C&D waste disposal to landfills. In order to provide information on the changes in reducing waste generation practice among construction participants in various work trades, a study was conducted after 3 years of implementation of the CWDCS via a structured questionnaire survey in the building industry in Hong Kong. The study result has revealed changes with work flows of the major trades as well as differentiating the levels of waste reduced. Three building projects in the public and private sectors were selected as case studies to demonstrate the changes in work flows and the reduction of waste achieved. The research findings reveal that a significant reduction of construction waste was achieved at the first 3 years (2006–2008) of CWDCS implementation. However, the reduction cannot be sustained. The major trades have been influenced to a certain extent by the implementation of the CWDCS. Slight improvement in waste management practices was observed, but reduction of construction waste in the wet-finishing and dry-finishing trades has undergone little improvement. Implementation of the CWDCS has not yet motivated subcontractors to change their methods of construction so as to reduce C&D waste.