A Comparison Study of Various Types of Ozone and Oxidant Detectors Which Are Used for Atmospheric Air Sampling

Four continuous automatic analyzers for measurement of atmospheric levels of ozone were used in a calibration and field study. These were (1) a colorimetric instrument based upon detection of iodine released from neutral potassium iodide reagent, {2) a coulometric instrument utilizing the polarization current as a measurement of iodine released by ozone in a cell contacted by potassium iodide reagent, (8) a galvanic cell measuring bromine release by ozone, and (4) an ultraviolet photometer. Some ozone determinations by the manual rubber cracking procedure were included. After calibration with ozone the average relative response to atmospheric ozone levels for each instrument was determined using the colorimetric oxidant analyzer as an arbitrary standard. These responses ranged from 77 percent for the galvanic cell 90 percent for the photometer. The instrument of choice for any given application would seem to be governed by requirements for precision specificity, portability, reliability, and ease of operation.     

Quantifying Diffuse Pollution Sources and Loads for Environmental Quality Standards in Urban Catchments

The paper explores the application of a unit area loading (UAL) approach to address the requirements of the US Clean Water Act (CWA) and the EU Water Framework Directive (WFD) for the identification and quantification of diffuse urban pollution sources. The UAL approach defines the spatial distribution of pollutant loadings within an urban catchment as a basis for the assessment of in-stream hazards and the implementation of source control BMP measures. Calculated annual outflow concentrations for a specific catchment for two pollutants, zinc and hydrocarbons, illustrate the different levels of dilution/control, which can be required to achieve receiving water quality standards and objectives. Methodological issues relating to traditional volume-concentration probabilistic modelling on which the UAL approach is based are discussed, and the application of the UAL approach to non-point diffuse pollution load management is reviewed.     

Concentrations of p,p'-DDE in plasma of nestling Wood Storks from Georgia

We determined the concentrations of organochlorine pesticides and total PCBs in plasma of nestling Wood Storks (Mycteria americana) from two colonies in Georgia in 2000. Of 20 compounds analyzed for, only p,p'-DDE was quantified in reportable concentrations, ranging from <2.0-174.0 ng/g wet weight (ww). Concentrations of p,p'-DDE were significantly greater (P<0.0001) in plasma of nestlings from an inland colony, Chew Mill (x 16.9 ng/g,ww) than a coastal colony, Harris Neck (x 1.2 ng/g,ww). Concentrations from nestlings from Chew Mill were significantly different among sampling weeks (P=0.01), with week 8 being significantly greater than weeks 1, 2, and 5. While the Chew Mill colony had much greater concentrations of p,p'-DDE in plasma of nestlings than the Harris Neck colony, reproduction was greater there (1.8+/-1.0 SD fledged young per nesting attempt) than Harris Neck (1.4+/-1.0 SD fledged young per nesting attempt). While concentrations of p,p'-DDE determined in plasma of nestling Wood Storks are an indirect measure of adult exposure to environmental toxicants, concentrations reported would not be considered detrimental to reproduction in these colonies.     

Creating safer workplaces: assessing the determinants and role of safety climate

PROBLEM: Although there has been considerable interest in safety climate, relatively little attention has been given to the factors that determine safety climate or to testing the hypothesized mediating role of safety climate with respect to safety-related outcomes. METHOD: Questionnaire responses were obtained from 2,208 employees of a large national retail chain in 21 different locations. RESULTS: After controlling for demographic variables, three factors: environmental conditions, safety-related policies and programs, and general organizational climate, accounted for 55% of the variance in perceived safety climate. Interestingly, organizational climate made a significant contribution to safety climate, even after controlling for the other more safety-relevant variables. Partial correlations showed that safety policies and programs had the largest observed correlation with safety climate, followed by two of the dimensions of organizational climate (communication and organizational support). Using Baron and Kenny's (J. Pers. Soc. Psychol. 51 (1986) 1173) procedures, the principal effects of the various work situation factors on perceived safety at work were found to be direct rather than mediated by safety climate. Safety climate influenced perceived safety at work, but its role as a mediator was limited. IMPACT ON INDUSTRY: These results are discussed in terms of other recent findings on safety climate and the growing interest in understanding management and organizational factors in the context of workplace safety.     

Regional engagement and spatial modelling for natural resource management planning

Changing unsustainable natural resource use in agricultural landscapes is a complex social–ecological challenge that cannot be addressed through traditional reductionist science. More holistic and inclusive (or transdisciplinary) processes are needed. This paper describes a transdisciplinary project for natural resource management planning in two regions (Eyre Peninsula and South Australian Murray-Darling Basin) of southern Australia. With regional staff, we reviewed previous planning to gain an understanding of the processes used and to identify possible improvement in plan development and its operation. We then used an envisioning process to develop a value-rich narrative of regional aspirations to assist stakeholder engagement and inform the development of a land use management option assessment tool called the landscape futures analysis tool (LFAT). Finally, we undertook an assessment of the effectiveness of the process through semi-structured stakeholder interviews. The planning process review highlighted the opinion that the regional plans were not well informed by available science, that they lacked flexibility, and were only intermittently used after publication. The envisioning process identified shared values—generally described as a trust, language that is easily understood, wise use of resources, collaboration and inclusiveness. LFAT was designed to bring the best available science together in a form that would have use in planning, during community consultation and in assessing regional management operations. The LFAT provided spatially detailed but simple models of agricultural yields and incomes, plant biodiversity, weed distribution, and carbon sequestration associated with future combinations of climate, commodity and carbon prices, and costs of production. Stakeholders were impressed by the presentation and demonstration results of the software. While there was anecdotal evidence that the project provided learning opportunities and increased understanding of potential land use change associated with management options under global change, the direct evidence of influence in the updated regional plan was limited. This project had elements required for success in transdisciplinary research, but penetration seems limited. Contributing factors appear to be a complexity of climate effects with economic uncertainty, lack of having the project embedded in the plan revision process, limited continuity and capacity of end users and limited after project support and promotion. Strategies are required to minimise the controlling influence that these limitations can have.     

Vegetation fire emissions and their impact on air pollution and climate

Gaseous and particulate emissions from vegetation fires substantially modify the atmospheric chemical composition, degrade air quality and can alter weather and climate. The impact of vegetation fire emissions on air pollution and climate has been recognised in the late 1970s. The application of satellite data for fire-related studies in the beginning of the 21th century represented a major break through in our understanding of the global importance of fires. Today the location and extent of vegetation fires, burned area and emissions released from fires are determined from satellite products even though many uncertainties persist. Numerous dedicated experimental and modeling studies contributed to improve the current knowledge of the atmospheric impact of vegetation fires. The motivation of this paper is to give an overview of vegetation fire emissions, their environmental and climate impact, and what improvements can be expected in the near future.     

Estimating rainforest biomass stocks and carbon loss from deforestation and degradation in Papua New Guinea 1972–2002: Best estimates,uncertainties and research needs

Reduction of carbon emissions from tropical deforestation and forest degradation is being considered a cost-effective way of mitigating the impacts of global warming. If such reductions are to be implemented, accurate and repeatable measurements of forest cover change and biomass will be required. In Papua New Guinea (PNG), which has one of the world's largest remaining areas of tropical forest, we used the best available data to estimate rainforest carbon stocks, and emissions from deforestation and degradation. We collated all available PNG field measurements which could be used to estimate carbon stocks in logged and unlogged forest. We extrapolated these plot-level estimates across the forested landscape using high-resolution forest mapping. We found the best estimate of forest carbon stocks contained in logged and unlogged forest in 2002 to be 4770 Mt (±13%). Our best estimate of gross forest carbon released through deforestation and degradation between 1972 and 2002 was 1178 Mt (±18%). By applying a long-term forest change model, we estimated that the carbon loss resulting from deforestation and degradation in 2001 was 53 Mt (±18%), rising from 24 Mt (±15%) in 1972. Forty-one percent of 2001 emissions resulted from logging, rising from 21% in 1972. Reducing emissions from logging is therefore a priority for PNG. The large uncertainty in our estimates of carbon stocks and fluxes is primarily due to the dearth of field measurements in both logged and unlogged forest, and the lack of PNG logging damage studies. Research priorities for PNG to increase the accuracy of forest carbon stock assessments are the collection of field measurements in unlogged forest and more spatially explicit logging damage studies.     

Do Postfire Mulching Treatments Affect Plant Community Recovery in California Coastal Sage Scrub Lands?

In recent years, the use of postfire mulch treatments to stabilize slopes and reduce soil erosion in shrubland ecosystems has increased; however, the potential effects on plant recovery have not been examined. To evaluate the effects of mulching treatments on postfire plant recovery in southern California coastal sage scrub, we conducted a field experiment with three experimental treatments, consisting of two hydromulch products and an erosion control blanket, plus a control treatment. The area burned in 2007, and treatments were applied to six plot blocks before the 2008 growing season. Treatment effects on plant community recovery were analyzed with a mixed effects ANOVA analysis using a univariate repeated measures approach. Absolute plant cover increased from 13 to 90% by the end of the second growing season, and the mean relative cover of exotic species was 32%. The two hydromulch treatments had no effect on any plant community recovery response variable measured. For the erosion control blanket treatment, the amount of bare ground cover at the end of the second growing season was significantly lower (P = 0.01), and greater shrub height was observed (P < 0.01). We conclude that postfire mulch treatments did not provide either a major benefit or negative impact to coastal sage scrub recovery on the study area.     

RAINGAGE NETWORK DESIGN USING NEXRAD PRECIPITATION ESTIMATES1

ABSTRACT: A general framework is proposed for using precipitation estimates from NEXRAD weather radars in raingage network design. NEXRAD precipitation products are used to represent space time rainfall fields, which can be sampled by hypothetical raingage networks. A stochastic model is used to simulate gage observations based on the areal average precipitation for radar grid cells. The stochastic model accounts for subgrid variability of precipitation within the cell and gage measurement errors. The approach is ideally suited to raingage network design in regions with strong climatic variations in rainfall where conventional methods are sometimes lacking. A case study example involving the estimation of areal average precipitation for catchments in the Catskill Mountains illustrates the approach. The case study shows how the simulation approach can be used to quantify the effects of gage density, basin size, spatial variation of precipitation, and gage measurement error, on network estimates of areal average precipitation. Although the quality of NEXRAD precipitation products imposes limitations on their use in network design, weather radars can provide valuable information for empirical assessment of rain‐gage network estimation errors. Still, the biggest challenge in quantifying estimation errors is understanding subgrid spatial variability. The results from the case study show that the spatial correlation of precipitation at subgrid scales (4 km and less) is difficult to quantify, especially for short sampling durations. Network estimation errors for hourly precipitation are extremely sensitive to the uncertainty in subgrid spatial variability, although for storm total accumulation, they are much less sensitive.     

Use of toxicity identification evaluations to determine the pesticide mitigation effectiveness of on-farm vegetated treatment systems

Evidence of ecological impacts from pesticide runoff has prompted installation of vegetated treatment systems (VTS) along the central coast of California, USA. During five surveys of two on-farm VTS ponds, 88% of inlet and outlet water samples were toxic to Ceriodaphnia dubia. Toxicity identification evaluations (TIEs) indicated water toxicity was caused by diazinon at VTS-1, and chlorpyrifos at VTS-2. Diazinon levels in VTS-1 were variable, but high pulse inflow concentrations were reduced through dilution. At VTS-2, chlorpyrifos concentrations averaged 52% lower at the VTS outlet than at the inlet. Water concentrations of most other pesticides averaged 20-90% lower at VTS outlets. All VTS sediment samples were toxic to amphipods (Hyalella azteca). Sediment TIEs indicated toxicity was caused by cypermethrin and lambda-cyhalothrin at VTS-1, and chlorpyrifos and permethrin at VTS-2. As with water, sediment concentrations were lower at VTS outlets, indicating substantial reductions in farm runoff pesticide concentrations.