Insights on the solubilization products after combined alkaline and ultrasonic pre-treatment of sewage sludge

This work provides insights on the solubilization products after a simultaneous combination of alkaline and ultrasonic (ALK + ULS) pre-treatment of sewage sludge. Soluble chemical oxygen demand (SCOD) increased from 1200 to 11,000 mg/L after such treatment. Organics with molecular weight around 5.6 kDa were solubilized because of the synergistic effect of ultrasound and alkali. Organics with molecular weight larger than 300 kDa increased from 7.8% to 60%, 16% and 42.3% after ULS, ALK and ALK + ULS treatment, respectively. Excitation emission matrix fluorescence spectroscopy analysis identified soluble microbial product-like and humic acid-like matters as the main solubilization products. Sludge anaerobic biodegradability was significantly enhanced with the simultaneous application of ALK + ULS pre-treatment. ALK + ULS pre-treatment resulted in 37.8% biodegradability increase compared to the untreated sludge. This value was higher compared to the biodegradability increase induced by individual ALK pre-treatment (5.7%) or individual ULS pre-treatment (20.7%) under the same conditions applied.     

Where Did the Agricultural Nonpoint Source Trades Go? Lessons from Virginia Water Quality Trading Programs

Governmental agencies, nongovernmental organizations, and agricultural organizations promote water quality trading programs as an innovative policy to engage agricultural producers in conservation activities. Cost analyses suggest regulated sources can reduce compliance costs by purchasing agricultural nonpoint source credits. Yet, such “point‐nonpoint” trades are rare. This article assesses the demand for agricultural nonpoint sources in well‐developed nutrient trading programs in Virginia for industrial and municipal wastewater treatment plants, municipal stormwater programs, and land developers. Evidence suggests nutrient trading programs in Virginia will not stimulate investments in pollutant reduction practices on working agricultural lands. The lack of demand for agricultural nonpoint source credits can be attributed to a substantial degree to the design features and incentives present in multiple overlapping regulatory programs. The legal setting that dampens regulated source demand for nonpoint source credits in Virginia is broadly representative of conditions found elsewhere in the United States.     

Is there a need to re-examine the approval of bismuth shotshell as a non-toxic alternative to lead based on the precautionary principle?

In 1997, the Canadian Wildlife Service (CWS) approved bismuth shotshell as an alternative to lead. We assessed whether there is a need to re-examine the toxicity of bismuth issue using the initial CWS toxicity guideline criteria. Review of the literature suggests that in the context of the precautionary principle, a re-examination of the approval of bismuth shotshell should be undertaken based on animal health issues, associated deficiencies in the analytical data used in the original assessment, and to a lesser extent, human health concerns.     

Lead transport into Bayou Trepagnier wetlands in Louisiana, USA

Establishment of a petroleum refinery in 1916 near the headwaters of Bayou Trepagnier with subsequent dredging of the bayou resulted in spoil banks containing high levels of Pb. A large swamp abuts the eastern bank of the bayou. Cores were taken from 15 baldcypress [Taxodium distichum (L.) Richard] trees growing in the swamp along a 610-m transect (nine trees) and a 183-m transect (six trees) running perpendicular from the spoil bank. The cores were crossdated, annual rings were measured, and 5-yr segments of the cores were prepared and analyzed for heavy metals. Soil samples were collected along one transect and analyzed for metals. Levels of Pb in Bayou Trepagnier swamp trees were compared to levels in nine baldcypress trees growing along Stinking Bayou, a reference area. During the last 100 yr, Pb in growth rings of swamp baldcypress trees averaged 8.6 mg/kg (SD 4.88) along one transect and 7.9 mg/kg (SD 5.39) along the other. Lead in the soil along the first transect dropped from >2700 mg/kg (spoil bank) to 10 mg/kg at 420 m into the swamp. Baldcypress trees growing near the refinery on the spoil bank along Bayou Trepagnier (covered in an earlier study) averaged 4.5 mg/kg Pb, and trees along Stinking Bayou averaged 2.1 mg/kg. Trees in the swamp soil with 10 to 425 mg/kg Pb concentrated much more Pb than trees growing on the heavily polluted bank. Greater uptake of Pb by trees in the swamp is discussed in terms of soil dynamics and Pb sources.     

Fate and toxicity of endosulfan in Namoi River water and bottom sediment

Endosulfan (6,7,8,9,10,10,-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepine-3-oxide) sorption (standardized to 1% total organic carbon and dry weight) was significantly (P < 0.05) more concentrated on the large (>63 microm) particle fraction compared with smaller size fractions (<5 microm and 5-24 microm) of bottom sediments from the Namoi River, Australia. Following completion of the particle size fractionation (6 to 12 wk) and a sediment toxicity assessment (2 wk), the sediments showed large decreases in concentrations of alpha-endosulfan that coincided with an increase in endosulfan sulfate concentrations and minimal changes in beta-endosulfan concentrations. In the Namoi River, similar patterns were observed in the composition of total endosulfan in monthly measurements of bottom sediments and in passive samplers placed in the water column following runoff from cotton (Gossypium hirsutum L.) fields. The toxicity of endosulfan sulfate in river water indicated by the nymphs of the epibenthic mayfly Jappa kutera, was more persistent than the alpha- and beta-endosulfan parent isomers due to its longer half-life. This suggests that endosulfan sulfate would contribute most to previously observed changes in population densities of aquatic biota. Measured concentrations of total endosulfan in river water of up to 4 microg L(-1) following storm runoff, exceed the range of the 96-h median lethal concentration (LC50) values in river water for both alpha-endosulfan (LC50 = 0.7 microg L(-1); 95% confidence interval [CI] = 0.5 to 1.1) and endosulfan sulfate (LC50 = 1.2 microg L(-1); 95% CI = 0.4 to 3.3). In contrast, the 10-d LC50 value for total endosulfan in the sediment toxicity test (LC50 = 162 microg kg(-1); 95% CI = 120 to 218 microg kg(-1)) was more than threefold higher than the highest measured concentration of total endosulfan in field samples of bottom sediment (48 microg kg(-1)). This suggests that pulse exposures of endosulfan in the water column following storm runoff may be more acutely toxic to riverine biota than in contaminated bottom sediment.     

Response of Red-Backed Voles to Recent Patch Cutting in Subalpine Forest

We examined the response of southern red-backed voles ( Clethrionomys gapperi ) to patch cutting in a forested landscape in which 23% of the forest cover had been removed by timber harvest. We live trapped voles in and around 18 patchcuts in one watershed of southern Wyoming. Although we found a significant difference in capture rates between patchcut interior and forest habitats in 1 of 2 years, voles did not strongly avoid the interior of patchcuts. This result contrasts with results from most studies of voles in clearcut ecosystems, which report that red-backed voles are generally rare or absent from clearcuts. Capture rates were highest on both sides of the patchcut edge, which also contrasts with studies of voles at the edges of forest remnants. The use of patchcut interior and edge habitats could not be explained as a consequence of juvenile voles dispersing to those habitats or males moving through the habitat in search of mates. We suggest that, despite similar physiognomy in patchcut and clearcut sites, the differences in landscape structure in perforated versus fragmented landscapes lead to very different patterns of vole movement. Understanding the scales at which voles perceive landscapes as coarse- or fine-grained will be key to developing predictive models to aid managers in designing timber sales that maintain high vole populations. Our results emphasize the importance of the spatial pattern and scale of disturbance in determining the response of vertebrates to landscape change and the need for more refined investigations of the consequences of deforestation.     

Hydraulic performance of a proposed in situ photocatalytic reactor for degradation of MTBE in water

Methyl tert-butyl ether (MTBE) groundwater remediation projects often require a combination of technologies resulting in increasing the project costs. A cost-effective in situ photocatalytic reactor design, Honeycomb II, is proposed and tested for its efficiency in MTBE degradation at various flows. This study is an intermediate phase of the research in developing an in situ photocatalytic reactor for groundwater remediation. It examines the effect of the operating variables: air and water flow and double passages through Honeycomb II, on the MTBE removal. MTBE vaporisation is affected by not only temperature, Henry’s law constant and air flow to volume ratio but also reactor geometry. The column reactor achieved more than 84% MTBE removal after 8 h at flows equivalent to horizontal groundwater velocities slower than 21.2 cm d⁻¹. Despite the contrasting properties between a photocatalytic indicator methylene blue and MTBE, the reactor efficiency in degrading both compounds showed similar responses towards flow (equivalent groundwater velocity and hydraulic residence time (HRT)). The critical HRT for both compounds was approximately 1 d, which corresponded to a velocity of 21.2 cm d⁻¹. A double pass through both new and used catalysts achieved more than 95% MTBE removal after two passes in 48 h. It also verified that the removal efficiency can be estimated via the sequential order of the removal efficiency of one pass obtained in the laboratory. This study reinforces the potential of this reactor design for in situ groundwater remediation.     

The Development of Open Pit Incinerators for Solid Waste Disposal

A discussion is presented of a newly developed incinerator for the disposal of solid wastes. It is distinguished from conventional types by its open top, and features a system of closely spaced nozzles admitting a screen of high-velocity air over the burning zone. Results, with a variety of solid industrial wastes, show high burning rates, leading to complete combustion and high flame temperature.     

Identifying potential receptors and routes of contaminant exposure in the traditional territory of the Ouje-Bougoumou Cree: Land use and a geographical information system

Great concern has been raised with respect to the 13 traplines that constitute the traditional territory of the Ouje-Bougoumou Cree located in the James Bay region of northern Quebec, Canada, with respect to mine wastes originating from three local mines. As a result, an “Integrative Risk Assessment” was initiated consisting of three interrelated components: a comprehensive human health study, an assessment of the existing ecological/environmental database, and a land use/potential sites of concern study. In this paper, we document past and present land use in the traditional territory of the Ouje-Bougoumou Cree for 72 heads of households, including 13 tallymen, and use a Geographic Information System (GIS) to layer harvest/hunting and gathering/collecting data over known mining areas and potential sites of concern. In this way, potential receptors of contamination and routes of human exposure were identified. Areas of overlap with respect to land use activity and mining operations were relatively extensive for certain harvesting activities (e.g., beaver, Castor canadensis and various species of game birds), less so for fish harvesting (all species) and water collection, and relatively restrictive for large mammal harvesting and collection of firewood (and other collection activities). Potential receptors of contaminants associated with mining activity (e.g., fish and small mammals) and potential routes of exposure (e.g., ingestion of contaminated game and drinking of contaminated water) were identified.