Genotoxicity assessment of human peripheral Lymphocytes induced by thallium(I) and thallium(III)

Thallium is a non-essential metal with a wide range of industrial uses. However, thallium is also a potential pollutant with high potential toxicity to humans. In the present study, we analyzed and compared the cellular and genotoxic effects of thallium in two main oxidation states by applying chromosome aberration assays to human peripheral lymphocytes. We observed that thallium(I) sulfate reduced the mitotic index at all tested concentrations (0.5, 1, 5, 50 and 100 μg/mL), whereas thallium(III) chloride was toxic at concentrations ≥1 μg/mL. Thallium(I) and thallium(III) treatment significantly increased structural chromosomal aberrations, with and without gaps, and increased the percentage of aberrant cells without gaps. Furthermore, satellite associations and numerical chromosomal aberration tests showed significant differences at a few of the tested concentrations. The satellite association test is related to aneuploidy. Thallium salts increased satellite associations when hyperploid cells were observed. Our results indicated that the two oxidation states of thallium induced toxicity in vitro – i.e. cyto/genotoxic (clastogenic and aneuploidogenic) effects.     

Double genetically modified symbiotic system for improved Cu phytostabilization in legume roots

Environmental Science and Pollution Research - Excess copper (Cu) in soils has deleterious effects on plant growth and can pose a risk to human health. In the last decade, legume-rhizobium...     

Ashes from fluidized bed combustion of residual forest biomass: recycling to soil as a viable management option

Although bottom ash (BA) [or mixtures of bottom and fly ash (FA)] from clean biomass fuels is currently used as liming agent, additive for compost, and fertilizer on agricultural and forest soils in certain European countries, in several other countries most of the ashes are currently disposed in landfills. This is due to both a lack of a proper classification of the materials and of regulatory barriers.Chemical characterization including analysis of an array of potentially toxic elements (PTEs) proved that over 100,000 tons of BA currently landfilled every year in Portugal actually complied with legal limits for PTEs for soil fertilizers applied in other countries. Pot experiments were conducted, testing three dosages of BA and FA (1, 2.5, and 5%, in weight) in three mining soils with different properties. Additions of ash materials to soils led to an increase in the pore water pH relative to control pots (0% of ash added) and had a clear impact on DOC and on the solubilization of both macro- and micronutrients (notably Cu).The results from the case study using BA and FA from a Portuguese biomass thermal power plant demonstrate that it is imperative to further develop a regulatory framework to alleviate technological and environmental barriers for biomass ash utilization as raw material for fertilizers and/or soil liming agent, in accordance with the goals of the circular economy. A more harmonized view on how to assess the merits and risks of the re-use of these materials is also needed.     

Phytoextraction of Pb,Cr, Ni,and Zn using the aquatic plant Limnobium laevigatum and its potential use in the treatment of wastewater

In order to study the bioaccumulation of Pb, Cr, Ni, and Zn and the stress response, the floating aquatic plant Limnobium laevigatum was exposed to increasing concentrations of a mixture of these metals for 28 days, and its potential use in the treatment of wastewater was evaluated. The metal concentrations of the treatment 1 (T1) were Pb 1 μg L⁻¹, Cr 4 μg L⁻¹, Ni 25 μg L⁻¹, and Zn 30 μg L⁻¹; of treatment 2 (T2) were Pb 70 μg L⁻¹, Cr 70 μg L⁻¹, Ni 70 μg L⁻¹, and Zn 70 μg L⁻¹; and of treatment 3 (T3) were Pb 1000 μg L⁻¹, Cr 1000 μg L⁻¹, Ni 500 μg L⁻¹, and Zn 100 μg L⁻¹, and there was also a control group (without added metal). The accumulation of Pb, Cr, Ni, and Zn in roots was higher than in leaves of L. laevigatum, and the bioconcentration factor revealed that the concentrations of Ni and Zn in the leaf and root exceeded by over a thousand times the concentrations of those in the culture medium (2000 in leaf and 6800 in root for Ni; 3300 in leaf and 11,500 in root for Zn). Thus, this species can be considered as a hyperaccumulator of these metals. In general, the changes observed in the morphological and physiological parameters and the formation of products of lipid peroxidation of membranes during the exposure to moderate concentrations (T2) of the mixture of metals did not cause harmful effects to the survival of the species within the first 14 days of exposure. Taking into account the accumulation capacity and tolerance to heavy metals, L. laevigatum is suitable for phytoremediation in aquatic environments contaminated with moderated concentrations of Cr, Ni, Pb, and Zn in the early stages of exposure.

     

Technical and economic evaluation of biogas capture and treatment for the Piedras Blancas landfill in Córdoba,Argentina

Landfill gas (LFG) management is one of the most important tasks for landfill operation and closure because of its impact in potential global warming. The aim of this work is to present a case history evaluating an LFG capture and treatment system for the present landfill facility in Córdoba, Argentina. The results may be relevant for many developing countries around the world where landfill gas is not being properly managed. The LFG generation is evaluated by modeling gas production applying the zero-order model, Landfill Gas Emissions Model (LandGEM; U.S. Environmental Protection Agency [EPA]), Scholl Canyon model, and triangular model. Variability in waste properties, weather, and landfill management conditions are analyzed in order to evaluate the feasibility of implementing different treatment systems. The results show the advantages of capturing and treating LFG in order to reduce the emissions of gases responsible for global warming and to determine the revenue rate needed for the project’s financial requirements. This particular project reduces by half the emission of equivalent tons of carbon dioxide (CO₂) compared with the situation where there is no gas treatment. In addition, the study highlights the need for a change in the electricity prices if it is to be economically feasible to implement the project in the current Argentinean electrical market.

Implications: Methane has 21 times more greenhouse gas potential than carbon dioxide. Because of that, it is of great importance to adequately manage biogas emissions from landfills. In addition, it is environmentally convenient to use this product as an alternative energy source, since it prevents methane emissions while preventing fossil fuel consumption, minimizing carbon dioxide emissions. Performed analysis indicated that biogas capturing and energy generation implies 3 times less equivalent carbon dioxide emissions; however, a change in the Argentinean electrical market fees are required to guarantee the financial feasibility of the project.     

Assessing equity and sustainability of water allocation in Colombia

Based on the national database of 28,104 water rights (concessions) granted in Colombia, this paper presents an analysis of how the principles of equity and sustainability are reflected in water allocation. Concessions appear to be an exclusionary mechanism since only a minority of small water users have concessions and the distribution of water volumes among those who have them is extremely inequitable. The 2009 Gini coefficient calculated for water concessions granted for agriculture was 0.90 compared with the rural land Gini of 0.88 (both indicators grouping holdings under the same entity). More than half of the Colombian departments have a higher Gini coefficient for water than for land, suggesting that water rights are at least as unequally distributed as land, in one of the most inequitable countries in Latin America. Water allocated to domestic, agriculture and hydropower use indicates a lack of consistency of water allocation criteria across regions. The volumetric and administrative attributes of water allocation in Colombia do not account for environmental flows or the concerns of marginalised groups of society that have limited access to the mechanism. Water allocation as a technical task, with limited transparency and secluded from public scrutiny, does not contribute to the solution of increasing water-related conflicts.     

Farm Animal Welfare Influences on Markets and Consumer Attitudes in Latin America: The Cases of Mexico,Chile and Brazil

In recent years, animal welfare has become an important element of sustainable production that has evolved along with the transformation of animal production systems. Consumer attitudes towards farm animal welfare are changing around the world, especially at emerging markets of Asia, Africa and Latin America. Survey-based research on consumer attitudes towards farm animal welfare has increased. However, the geographical coverage of studies on consumer attitudes and perceptions about farm animal welfare has mostly been limited to Europe, and North America. Until now, Latin American consumers’ attitudes towards animal welfare have not been well studied. Despite the fact that Mexico, Chile and Brazil belong to the same region (according to international organizations), there are marked differences between these countries in terms of their economical and geographical characteristics among other factors. Those differences potentially have an impact on consumer attitudes towards animal welfare and livestock production systems in general. Given the evidence from the literature review, it seems advisable that Latin American producers and food industry who engage in animal welfare-enhancing practices should clearly label their products with information on the type of husbandry system to reach those consumers who want to make an informed choice. Therefore, there are some aspects that need to be studied and cannot be worked separately in order to promote and understand consumer attitudes towards dairy and beef systems, such as geography, economic development, and politics.     

Physical Characterization of Biodegradable Films Based on Chitosan,Polyvinyl Alcohol and <Emphasis Type="Italic">Opuntia</Emphasis> Mucilage

This study aimed to develop and characterize biodegradable films containing mucilage, chitosan and polyvinyl alcohol (PVA) in different concentrations. The films were prepared by casting on glass plates using glycerol as plasticizer. Mechanical properties, water vapor and oxygen barrier, as well as the interaction with water, were measured. The compatibility of the film-forming components and the uniformity of the films were determined by zeta potential and SEM, respectively. The glycerol and mucilage allowed obtaining more hydrophilic films. The barrier properties of the films made from 100 % chitosan were similar to composed films containing PVA up to 40 %. The results of this study suggest that the interaction between chitosan and mucilage could increase water vapor permeability. The films prepared from either 100 % chitosan or PVA showed a more hydrophobic behavior as compared to the composed films. The films were homogenous since no boundary or separation of components was observed, indicating a good compatibility of the components in the films.     

Testing a tridimensional model of sustainable behavior: self-care,caring for others,and caring for the planet

This paper investigates the dimensions of sustainable behavior, with a particular focus on the aspects of self-care, caring for others, and caring for the environment. Its aim was to test the assumption that sustainable behavior not only encompasses pro-social and pro-environmental actions, as the current research acknowledges, but also behaviors that are directed toward self-preservation and care. A subscale of self-care specifically developed for this research was added to a series of previously validated instruments assessing altruistic, equitable, pro-ecological, and frugal behaviors to examine the personal, social, and physical environmental aspects of sustainable behavior. Responses from a sample of 290 participants confirmed the three-dimensional structure of sustainable behavior. Results suggest sustainability, understood as a chain of interdependences between the individual, society, and nature, begins with self-care and continues with caring for others, and with caring for the biosphere, which, in turn, affords for a more sustainable environment for the individual.

     

Wind energy in the Isthmus of Tehuantepec: conflicts and social implications

Social acceptance is fundamental, and directly affects the installation of wind farms. In this paper, the factors that have had the greatest influence on the development of wind energy in the Itsmo region of Tehuantepec, Mexico are identified. The data were collected face to face through a semi-structured questionnaire of 31 people: owners, municipal authorities, opposition groups, and academic members. The results of the interview highlight the social impact, the lack of application, and concerning ILO Convention 169, the abuse of community rights. As a result, people interviewed perceive that the environmental impact of the installation, and operation of wind farms has been ambivalent: positive due to the intrinsic benefits that wind energy generates compared to other energy sources, and negative in terms of affectation by the noise, and the landscape. However, the income received by the owners of land in which wind facilities are located is lower compared to other parts of the world. In general, the facts show a disintegration between the authorities (federal, state, and municipal), universities are isolated from wind projects, communities are not consulted in projects, and large companies are the main beneficiaries.