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Environment, Development and Sustainability - Renewable energy (RE) plays an increasingly important role in the economy of almost every country in the world. In order to examine the state of...  相似文献   
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Concerns over data quality have raised many questions related to sampling soils for volatile organic compounds (VOCs). This paper was prepared in response to some of these questions and concerns expressed by Remedial Project Managers (RPMs) and On-Scene Coordinators (OSCs). The following questions are frequently asked:
  1. Is there a specific device suggested for sampling soils for VOCs?
  2. Are there significant losses of VOCs when transferring a soil sample from a sampling device (e.g., split spoon) into the sample container?
  3. What is the best method for getting the sample from the split spoon (or other device) into the sample container?
  4. Are there smaller devices such as subcore samplers available for collecting aliquots from the larger core and efficiently transferring the sample into the sample container?
  5. Are certain containers better than others for shipping and storing soil samples for VOC analysis?
  6. Are there any reliable preservation procedures for reducing VOC losses from soil samples and for extending holding times?
Guidance is provided for selecting the most effective sampling device for collecting samples from soil matrices. The techniques for sample collection, sample handling, containerizing, shipment, and storage described in this paper reduce VOC losses and generally provide more representative samples for volatile organic analyses (VOA) than techniques in current use. For a discussion on the proper use of sampling equipment the reader should refer to other sources (Acker, 1974; U.S. EPA, 1983; U.S. EPA, 1986a). Soil, as referred to in this report, encompasses the mass (surface and subsurface) of unconsolidated mantle of weathered rock and loose material lying above solid rock. Further, a distinction must be made as to what fraction of the unconsolidated material is soil and what fraction is not. The soil component here is defined as all mineral and naturally occurring organic material that is 2 mm or less in size. This is the size normally used to differentiate between soils (consisting of sands, silts, and clays) and gravels. Although numerous sampling situations may be encountered, this paper focuses on three broad categories of sites that might be sampled for VOCs:
  1. Open test pit or trench.
  2. Surface soils (<5 ft in depth).
  3. Subsurface soils (>5 ft in depth).
  相似文献   
14.
McMurdo Station is the largest research station in Antarctica, with a population that ranges each year from 250 to 1200 people. Because of its size and 40-year history of use, a number of locations around the station have become contaminated with wastes. Soils and sediments in these areas have been shown to contain elevated levels of petroleum-related products, PCBs, other organics, and metals. While some remedial investigations have been conducted, background levels of metals in soils have not been determined. This paper reports on background levels of metals in a natural basalt-derived soil (gray soil) and scoria (soft porous rock used as fill, red soil) near McMurdo Station using two fundamentally different analytical procedures, concentrated acid extraction/analysis and total metals. These data facilitate determining the extent and levels of metal contamination near McMurdo Station and provide reference levels of metals for comparison with existing and future remediation data. There were statistically significant differences between metals concentrations in both gray and red soils, and no correlations between the level of extracted versus total metal. Generally, only a small fraction of a metal was extractable.  相似文献   
15.
Solvent extraction and evaporative concentration steps are often used in procedures for the measurement of butyltins in environmental samples. As part of a larger study utilizing radiolabeled butyltins, the loss and fractionation of butyltins during sample preparation was investigated. TBT, DBT, and MBT were extracted from acidified seawater by hexane with efficiencies of about 95–99, 50–60 and 11% respectively. In addition, losses of about 70% of DBT were found during evaporative concentration of hexane. A variety of sediment extraction procedures were tested and none were found to be highly efficient for total butyltin extraction.  相似文献   
16.
李小兵  钟铁 《环境科技》2002,15(4):33-34
通过对姑山矿生产现状的调查研究,确定审计重点为选矿车间,分析了选矿车间存在的问题,提出了清洁生产方案,对方案实施后的经济效益作了分析。  相似文献   
17.
Forchhammer  K.  Böck  A. 《Die Naturwissenschaften》1991,78(11):497-504
The importance of selenium as an essential trace element has progressively emerged during the last years due to the analysis of selenium deficiency diseases and to the identification and characterization of a number of selenoenzymes. Selenium is incorporated in the catalytic site of the enzymes as an integral selenocysteine residue. The pathway of selenocysteine biosynthesis and incorporation has been elucidated recently for Escherichia coli. This article presents an overview on these subjects and describes the mechanisms which confer selenocysteine specificity in the framework of protein biosynthesis. In addition, some considerations concerning the phylogeny of selenocysteine incorporation are presented and a model for the evolution of the selenocysteine pathway is proposed.  相似文献   
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刘莉 《环境科学导刊》2007,26(B06):55-57
主要就污染物对动物、植物及人体健康的危害,以及在污染条件下生物的适应与进化作一综述。  相似文献   
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