全文获取类型
收费全文 | 3406篇 |
免费 | 229篇 |
国内免费 | 1265篇 |
专业分类
安全科学 | 242篇 |
废物处理 | 210篇 |
环保管理 | 250篇 |
综合类 | 1998篇 |
基础理论 | 577篇 |
环境理论 | 2篇 |
污染及防治 | 1146篇 |
评价与监测 | 159篇 |
社会与环境 | 171篇 |
灾害及防治 | 145篇 |
出版年
2024年 | 12篇 |
2023年 | 84篇 |
2022年 | 192篇 |
2021年 | 204篇 |
2020年 | 155篇 |
2019年 | 98篇 |
2018年 | 159篇 |
2017年 | 171篇 |
2016年 | 217篇 |
2015年 | 219篇 |
2014年 | 298篇 |
2013年 | 338篇 |
2012年 | 289篇 |
2011年 | 302篇 |
2010年 | 207篇 |
2009年 | 210篇 |
2008年 | 241篇 |
2007年 | 158篇 |
2006年 | 186篇 |
2005年 | 148篇 |
2004年 | 89篇 |
2003年 | 111篇 |
2002年 | 81篇 |
2001年 | 85篇 |
2000年 | 102篇 |
1999年 | 86篇 |
1998年 | 87篇 |
1997年 | 76篇 |
1996年 | 72篇 |
1995年 | 57篇 |
1994年 | 44篇 |
1993年 | 32篇 |
1992年 | 43篇 |
1991年 | 13篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1966年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有4900条查询结果,搜索用时 18 毫秒
981.
Li CR Lee SH Kim SS Kim A Lee KW Lu M Kim HE Kwak IJ Lee YJ Kim DK Lee JS Kang SW Huh MD Chung KH Park JS 《Environmental monitoring and assessment》2009,150(1-4):397-404
Serum vitellogenin (VTG) contents of wild goldfish (Carassius auratus) were investigated as a sensitive biomarker for artificial estrogenic compounds in aquatic environments. Goldfish was sampled from a pristine area, a river situated 5 km downstream from a sewage treatment works (STW), and also from the Young-San River in Korea. The female yolk precursor protein VTG was not detected when gonadosomatic index (GSI) was less than 0.85%, while VTG levels of >10 microg/ml were found in males whose GSI was less than 1.53%. In male goldfish sampled from STW and the Young-San River, the higher VTG corresponded to lower GSI. This study suggested a trend that gonad development was connected to VTG levels in both sexes, and the application of GSI and histological analysis provide an attractive possibility that it could be included in the panel of markers used for estrogenic activity investigation of aquatic environments. 相似文献
982.
Luo W Lu Y Wang B Tong X Wang G Shi Y Wang T Giesy JP 《Environmental monitoring and assessment》2009,158(1-4):507-517
Fifty-seven typical surface soils and 108 deeper soils were collected from five former industrial sites in Beijing and concentrations of total Hg (SigmaHg) as well as pH, total carbon (TC), total nitrogen (TN), total sulfur, and dissolved organic carbon concentrations determined. The mean concentration of SigmaHg in surface soils was significantly greater than background concentrations in the vicinity of Beijing. Forty-eight percent of the samples exceeded the "critical" concentration of 1.0 mg Hg/kg, dry weight in soils, which has been established by the Chinese government. At depths of 0-80 cm in the soil, profile concentrations of SigmaHg also exceeded the background value. There were significant correlations between concentrations of SigmaHg, TC, and TN in the industrial soils. The greater concentration of SigmaHg in most soils could have been due in part to combustion of coal and leakage from industrial processes. 相似文献
983.
984.
The concentration of sixteen individual polycyclic aromatic hydrocarbons (PAHs) was measured in the clam Ruditapes decussatus whole soft tissues from several places of the Ria Formosa lagoon (Portugal). Total PAH (tPAH) concentrations were higher in the summer (August) and winter (January) than in the other months and the distribution pattern of the individual PAHs was generally dominated by the 4 aromatic ring PAHs, followed by the 2 + 3 aromatic rings PAHs. Benzo[a]anthracene and acenaphthene were the most representative PAHs of the two fractions. Principal components analysis (PCA) revealed that, in the Ria Formosa, seasonal variations are more important than spatial variations, due to changes in PAH source. These sources ranged from petrogenic to pyrolytic or a mixture of both. The origin of clam PAHs was also assessed by partial least squares (PLS) analysis using nineteen different PAH signatures, taken from the literature. It was possible to identify boat traffic, especially in the summer, as one of the most relevant PAH sources to the Ria Formosa. The influence of boat traffic was revealed by several signatures including diesel soot, oil and weathered oil and a mixture of different individual PAHs usually found in harbour sediments. Other relevant sources included combustion of organic matter such as forest fires and diverse domestic activities, occurring mainly in the summer. Most of the clams were considered safe for human consumption, except for some point samples, which presented unusually high PAH concentrations, suggesting the need for a regular survey of PAHs in clam tissues. 相似文献
985.
选取了6种有代表性的挥发性有机化合物(VOCs),异丙醇、二氯甲烷、乙酸乙烯酯、正己烷、苯和四氯化碳,实测了这些VOCs在气体采样罐(SUMMA罐)中的存储稳定性。结果表明:苯、正己烷和二氯甲烷在采样罐中均较稳定,其含量在84 d的存储期内基本无变化;乙酸乙烯酯在6个VOCs中最不稳定,在普通和惰性采样罐中含量均明显下降;异丙醇和四氯化碳的稳定性与采样罐的类型有关,在普通采样罐内含量下降明显,而在惰性采样罐内则相对稳定。实际监测工作中,为提高VOCs分析的准确性,如目标分析物有含氧类(醇,酮,酯等)或含卤素类VOCs,则采样后需尽快分析,同时尽量选择惰性采样罐为采样容器。 相似文献
986.
Sihua Lu Ying Liu Min Shao Shan Huang 《Frontiers of Environmental Science & Engineering》2007,1(2):147-152
Volatile organic compounds (VOCs) were measured at six sites in Beijing in August, 2004. Up to 148 VOC species, including C3 to C12 alkanes, C3 to C11 alkenes, C6 to C12 aromatics, and halogenated hydrocarbons, were quantified. Although the concentrations differed at the sites, the chemical compositions were similar, except for the Tongzhou site where aromatics were significantly high in the air. Based on the source profiles measured from previous studies, the source apportionment of ambient VOCs was preformed by deploying the chemical mass balance (CMB) model. The results show that urban VOCs are predominant from mobile source emissions, which contribute more than 50% of the VOCs (in mass concentrations) to ambient air at most sites. Other important sources are gasoline evaporation, painting, and solvents. The exception is at the Tongzhou site where vehicle exhaust, painting, and solvents have about equal contribution, around 35% of the ambient VOC concentration. As the receptor model is not valid for deriving the sources of reactive species, such as isoprene and 1,3-butadiene, other methodologies need to be further explored. 相似文献
987.
基于盲数的水体沉积物潜在生态风险评价方法 总被引:2,自引:0,他引:2
基于生态风险评价系统中多种不确定性共存或交叉存在的特性,将盲数理论应用于水体沉积物潜在生态风险的评价研究。在将Hakanson潜在生态风险指数模型参数定义为盲参数的基础上,建立了沉积物潜在生态风险评价的盲数模型,并提出了污染程度和潜在生态风险等级识别盲数可靠性计算模型。根据上述盲数模型,不仅可以得到沉积物污染程度和潜在生态风险的可能取值区间,也可以得到各区间相应的可信度水平,进而定量计算待评价对象隶属于各评价等级的主观可能性大小。作为案例,将上述模型应用于巢湖十五里河河口沉积物中重金属潜在生态风险评价的研究。在得到沉积物中单个重金属污染物(Hg,Cd,Pb,Cu,Cr)隶属于污染程度各等级和潜在生态风险各等级可信度水平的基础上,得出十五里河河口处于较高生态风险水平的结论,相应的可信度为0.626。实例研究表明,以盲数理论评价沉积物的潜在生态风险,理论上可行,评价结论可信。 相似文献
988.
Fifty-six representative samples of topsoil were collected around Guanting Reservoir, which is an important water source for
Beijing. Concentrations of the insecticides HCH, DDT, and their metabolites were quantified by use of gas chromatography (GC)
with electron capture detection (ECD). Organochlorine pesticides (OCPs) are still present in surface soils in the Guanting
area. DDT accounts for about 93% of the total OCP content. Concentrations of α/γ, β/γ, and DDT/DDE are the result not only
of historical use, but also of more recent depositions. Statistical analyses, including principal component analysis (PCA)
and cluster analysis (CA), revealed associations between concentrations of OCPs and major soil characteristics. Geographical
information system (GIS) technology was used to develop maps of the distributions of OCP concentrations. The areas of greatest
contamination were primarily in the central part of the study area and were correlated with greater population density, heavier
traffic, and more industrial activity. 相似文献
989.
990.
Effects of land use on concentrations of metals in surface soils and ecological risk around Guanting Reservoir,China 总被引:7,自引:0,他引:7
Luo W Lu Y Giesy JP Wang T Shi Y Wang G Xing Y 《Environmental geochemistry and health》2007,29(6):459-471
It is accepted that the historical routine use of agrochemicals may have resulted in undesirable concentrations of metals
in the environment. To investigate and assess the effects of land use on concentrations of heavy metals around the Guanting
Reservoir in China, 52 surface soil samples (depth of 2–10 cm) were taken from areas where four types of land use were practiced
(including arable land, woodland, bare land, orchard land). The metals and metalloids (As, Cr, Ni, Cu, Zn, Cd, and Pb) were
analyzed using inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Significant accumulation of As, Cd, and
Cr was found in soils of arable land. Based on correlation and cluster analysis, it can be concluded that Cd and Zn originate
mainly from phosphate fertilizer, Pb from the use of insecticides, fertilizers, and sewage sludge as well as air deposition,
and Cu from copper-based fungicides, while As, Ni and Cr might come from parent soil material. According to an ecological
risk analysis of metals based on the ecological index suggested by Hakanson, the four types of land can be ranked by severity
of ecological risk as follows: arable land > woodland > bare land > orchard land, with a high ecological risk of Cd for all
four types. Management measures for land use planners for avoiding water, soil, and sediment pollution caused by metals around
the Guanting Reservoir are presented. 相似文献