核电站事故后去除土壤处置方法研究

文中综述了国际国内放射性污染土壤处置方法研究进展,结合中国放射性废物处置法律法规,针对中国核电站站堆型,研究分析核电站事故后去除土壤的处置方法,并建议给出了适合于中国核电站事故后去除土壤的处置策略,为中国核电站事故后污染场地的清理方法、土壤去污处理方法的选择明确方向,为修复活动的监管提供技术支持,实现废物最小化。     

THK引气气浮系统的研制与应用

在引进美国THK系统基础上，通过对THK系统的研究，消化和吸收，已实现THK的国产化生产，目前，国产化水平已达到80％－90％。工业废处理应用表明，THK是一种简单，节能和高效的气浮设备，非常适合在我国推广应用。     

Antimicrobial activity of silver loaded MnO2 nanomaterials with different crystal phases against Escherichia coli

Silver-loaded MnO_2 nanomaterials(Ag/MnO_2),including Ag/α-MnO_2,Ag/β-MnO_2,Ag/γ-MnO_2and Ag/δ-MnO_2 nanorods,were prepared with hydrothermal and impregnation methods.The bactericidal activities of four types of Ag/MnO_2 nanomaterials against Escherichia coli were investigated and an inactivation mechanism involving Ag~+ and reactive oxygen species(ROS)was also proposed.The bactericidal activities of Ag/MnO_2 depended on the MnO_2 crystal phase.Among these nanomaterials,Ag/β~-MnO_2 showed the highest bactericidal activity.There was a 6-log decrease in E.coli survival number after treatment with Ag/β~-MnO_2 for120 min.The results of 5,5-dimethyl-l-pyrroline-N-oxide spin-trapping measurements by electron spin resonance indicate OH and O_2~- formation with addition of Ag/β-MnO_2,Ag/γ-MnO_2 or Ag/δ-MnO_2.The strongest peak of OH appeared for Ag/β-MnO_2,while no OH or ·O_2~-signal was found over Ag/α-MnO_2.Through analysis of electron spin resonance(ESR) and Ag+elution results,it could be deduced that the toxicity of Ag~+ eluted from Ag/MnO_2 nanomaterials and ROS played the main roles during the bactericidal process.Silver showed the highest dispersion on the surface of β-MnO_2,which promoted ROS formation and the increase of bactericidal activity.Experimental results also indicated that Ag/MnO_2 induced the production of intracellular ROS and disruption of the cell wall and cell membrane.     

Profiling kidney microRNAs from juvenile grass carp (Ctenopharyngodon idella) after 56 days of oral exposure to decabromodiphenyl ethane

Grass carp(Ctenopharyngodon idella) is one of the most important species in China.Decabromodiphenyl ethane(DBDPE) is a brominated flame retardant that has been used widely in industry, and has been observed to accumulate in the tissues of fish from South China. Evidence has shown that DBDPE is toxic to aquatic animals, but the molecular response has been unclear. MicroRNAs(miRNAs) are small noncoding and negative regulatory RNAs that are 20–24 nucleotides in length, which are involved in a wide range of biological processes. We took advantage of deep-sequencing techniques to accurately and comprehensively profile the kidney mi RNA expression of grass carp after 8 weeks of oral exposure to DBDPE. After mapping sequencing data to the genome and Expressed Sequence Tags(ESTs) of grass carp, we identified 493 miRNAs in the sequenced grass carp samples, which included 51 new miRNAs. The results indicated that 5 miRNAs were significantly down-regulated and 36 miRNAs were significantly up-regulated(FDR 0.001,1.5-fold change) after DBDPE exposure. Real-time quantitative PCR(RT-q PCR) was performed on 4 miRNAs from the two samples, and the sequencing and RT-q PCR data were consistent. This study provides the first comprehensive identification of grass carp miRNAs, and the first expression analysis of grass carp miRNAs following DBDPE exposure.The results indicated that miRNAs have potential for use as biomarkers.     

Study on acute toxicity and structure-activity relationship of zebrafish (Danio rerio) exposed to naphthoquinones

In this paper, we evaluated the acute toxicity of five naphthoquinone compounds, expressed as median lethal concentration at 96 h (LC₅₀) using zebrafish as a model. The five compounds were classified as harmful or very toxic. The Gaussian method was used to calculate the quantitative-chemical parameters of each compound. Based on the structure-activity relationship analysis, the interaction between the naphthoquinones and the target is likely mediated by 1-carbonyl and the hydrophobic fraction substituted in α -position of naphthoquinone via hydrogen bonding and hydrophobic interactions. Our results provide a foundation for evaluating the aquatic ecological risk and the mode of action of naphthoquinones in the environment.     

The CO2 emission changes in China’s transportation sector during 1992–2015: a structural decomposition analysis

Environmental Science and Pollution Research - Based on a structural decomposition approach, the present paper simultaneously analyzes seven driving factors and forty sectors, which contribute to...     

三峡水库支流小江鱼类早期资源现状

分别于2017年和2018年的5—7月在三峡库区支流小江渠口断面开展鱼类早期资源监测,以了解小江变动回水区鱼类早期资源现状。监测结果表明:共采集到7种产漂流性卵鱼类的鱼卵以及7种仔鱼;采集的鱼卵以似鳊(Pseudobrama simoni)、银(Squalidus argentatus)、翘嘴鲌(Culter alburnus)和蒙古鲌(Culter mongolicus)为主,而仔鱼则以子陵吻虎鱼(Rhinogobius giurinus)为主;不同年份主要产卵活动发生的时间存在差异;小江渠口镇铺溪村至汉丰湖调节坝之间江段共分布集中产卵场3处。小江变动回水区江段是产漂流性卵鱼类产卵场的分布区域,建议加强该江段生境和鱼类资源保护管理。     

长江三峡库区和上游气候变化特点及其影响

利用1961～2010年逐日气温、降水等气象观测资料分析三峡库区和长江流域等地区气象要素的气候长期变化趋势,并利用监测资料和数值模拟试验初步分析了水库蓄水后对三峡库区附近局地的天气气候的可能影响。结果表明:近50 a来三峡库区平均气温呈现上升趋势,降水量具有年代际变化特征,21世纪以来库区降水转为少雨期;气温和降水的变化都与长江上游乃至整个长江流域的变化趋势基本一致。水库蓄水后对库区附近气温产生调节作用,夏季降温和冬季增温效应明显;蓄水后库区年降水量没有明显变化。总体上,三峡水库对附近气候影响范围一般不超过20 km     

青岛秋冬季PM1中金属元素污染特征及健康风险评估

于2018年11月1日至2019年1月31日（OP_2018-2019）和2019年11月1日至2020年1月20日（OP_2019-2020）在青岛对PM₁进行了连续两年秋冬季逐日采集.将观测期划分为4个空气质量等级（Ⅰ级、Ⅱ级、Ⅲ级和Ⅳ级）,分析了PM₁中金属元素浓度特征及来源,评估了不同人群的非致癌风险（Zn、Pb、Mn、Cu和V）和致癌风险（As、Cr、Ni、Cd和Co）.结果表明,与OP_2018-2019相比,OP_2019-2020期间不同空气质量等级下金属元素总浓度变化与Ca、K和Al浓度变化有关,受扬尘源和生物质燃烧源影响较大.与OP_2018-2019相比,OP_2019-2020期间不同空气质量等级下V浓度分别下降19.0%、60.5%、82.7%和77.5%.推测与船舶国内排放控制区域（DECA）政策实施有关,青岛周边海域船舶改换燃油品质,导致V浓度大幅降低.由富集因子、比值法和气流后向轨迹结果进一步表明V浓度变化主要受DECA政策影响.然而,实施DECA政策后,V/Ni值作为判断区域内受船舶源影响的限值,需进一步探究.由健康风险评估结果表明,OP_2018-2019和OP_2019-2020期间非致癌元素Mn的危险系数范围为0.07~1.22,建议加强管控含Mn污染源的排放.OP_2018-2019和OP_2019-2020期间不同空气质量下As、Cd的终生致癌风险概率（ILCR）值低于10^-4,但高于10^-6,表明存在致癌概率,但仍可接受.OP_2018-2019期间空气质量为Ⅳ级时,Cr的ILCR值高于10^-4,存在致癌风险.