横通道通风对隧道火灾烟气蔓延影响的数值模拟研究

为探究隧道横通道通风对隧道火灾烟气蔓延的影响规律,使用火灾动力学模拟软件FDS,对不同火源位置的横通道临界风速、主隧道温度分布以及烟气层高度进行研究。研究结果表明：在一定火源功率范围内,隧道横通道临界风速与火源功率的1/3次方成正比且火源距横通道越远,临界风速越小;当火源位于交叉口,横通道使用临界风速通风时,隧道内烟气温度明显降低,烟气迅速沉降到2 m以下;当火源距离交叉口10,20 m,横通道通风会加快火源下游烟气沉降,烟气沉降速度随横通道通风速率的增大而增大;当火源位于交叉口时,烟气沉降由横通道通风对烟气的降温作用和涡旋作用共同主导,当火源位于距离交叉口10,20 m时,烟气沉降主要由涡旋作用主导。     

换房换出来的住地游

在一个城市呆得久了,就会想要到别的城市去看看,尝试一种不同的生活。对于很多人而言,这种到其它城市走走看看的想法也只能是一种想法,因为一旦离开家,就要考虑如何到达目的地？如何解决吃、喝、拉、撒、睡的问题,这些在家中根本不用发愁的事情,在家门之外就要和金钱、时间搭上关系。     

基于红外热成像的隧道火焰检测技术研究

精准的火焰检测是有效避免火灾发生的关键,针对传统的火灾探测算法在公路隧道等大空间环境中存在及时性与准确性相互制约的问题,通过研究隧道火焰初期在图像中呈现的静态和动态特征,提出了一种基于红外热成像的公路隧道火灾初期火焰检测方法。利用温度阈值获取疑似火焰区域,根据红外图像在引导滤波器作用下降噪,同时利用区域增长法分割疑似火焰区域;从疑似区域中提取的特征值构成特征向量,进行数据归一化提高SVM收敛速度;利用人工蜂群算法优化参数。结果表明：ABC-SVM能够实现公路隧道火灾初期的火焰识别,检测正确率相较于RBF方法提升了2.26%,运行时间缩短了2.29 ms;检测正确率相较于SVM方法提升了0.87%,运行时间缩短了2.22 ms。本方法可以对初期隧道火灾进行快速、有效检测,并有良好的环境适用性。     

Simultaneous determination of estrogenic odorant alkylphenols,chlorophenols, and their derivatives in water using online headspace solid phase microextraction coupled with gas chromatography-mass spectrometry

A simple online headspace solid-phase microextraction (HS-SPME) coupled with the gas chromatography-mass spectrometry (GC-MS) method was developed for simultaneous determination of trace amounts of nine estrogenic odorant alkylphenols and chlorophenols and their derivatives in water samples. The extraction conditions of HS-SPME were optimized including fiber selection, extraction temperature, extraction time, and salt concentration. Results showed that divinylbenzene/Carboxen/polydimethylsiloxane (DVB/CAR/PDMS) fiber was the most appropriate one among the three selected commercial fibers, and the optimal extraction temperature, time, and salt concentration were 70 °C, 30 min, and 0.25 g/mL, respectively. The developed method was validated and showed good linearity (R ²?>?0.989), low limit of detection (LOD, 0.002–0.5 μg/L), and excellent recoveries (76–126 %) with low relative standard deviation (RSD, 0.7–12.9 %). The developed method was finally applied to two surface water samples and some of these target compounds were detected. All these detected compounds were below their odor thresholds, except for 2,4,6-TCAS and 2,4,6-TBAS wherein their concentrations were near their odor thresholds. However, in the two surface water samples, these detected compounds contributed to a certain amount of estrogenicity, which seemed to suggest that more attention should be paid to the issue of estrogenicity rather than to the odor problem.     

Distribution, sources, and potential risk of polycyclic aromatic hydrocarbons (PAHs) in drinking water resources from Henan Province in middle of China

Distribution and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in drinking water resources have been carried out for the first time in Henan Province, China. Water samples collected from four river systems and their tributaries, as well as groundwater resources, were analyzed according to EPA method 525.2. Total of 68 water samples were collected in 18 cities in Henan province in May, August and November, 2001. Concentrations of sum of 16 priority PAHs in water samples ranged from 15 to 844 ng/L with a mean value of 178 +/- 210 ng/L (n = 68). The spatial and temporal distribution of PAHs showed that the Huanghe and the Huaihe river systems had relatively higher concentrations of total PAHs. Higher concentrations of total PAHs were observed in August and November than in May, with respective mean values of 262, 232 and 33.6 ng/L. Ratios of Ant/(Ant + Phe) and Flur/(Flur + Pyr) were calculated to evaluate the possible sources of PAH contamination, which indicated that the coal combustion sources were the main contributors to PAHs in most drinking water resources. Some petrogenic (or pyrolytic) sources of PAHs were also found. The toxic equivalency factors (TEFs) were used to calculate benzo[a]pyrene equivalents (BaPE) for water samples. The average value of BaPE was 0.6 ng/L. The values in most stations were much lower than the guideline values in drinking water of Chinese Environmental Protection Agency (CEPA, 2.8 ng/L) and the US Environmental Protection Agency (US EPA, 200 ng/L). Overall, the drinking water resources in Henan province showed some carcinogenic potential.     

The concentrations, distribution and sources of PAHs in agricultural soils and vegetables from Shunde, Guangdong, China

The concentrations, distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in 30 agricultural soil and 16 vegetable samples collected from subtropical Shunde area, an important manufacturing center in China. The total PAHs ranged from 33.7 to 350 μg/kg in soils, and 82 to 1,258 μg/kg in vegetables. The most abundant individual PAHs are phenanthrene, fluoranthene, chrysene, pyrene and benzo(b)fluoranthene for soil samples, and anthracene, naphthalene, phenanthrene, pyrene and chrysene for vegetable samples. Average vegetable–soil ratios of total PAHs were 2.20 for leafy vegetables and 1.27 for fruity vegetables. Total PAHs in vegetable samples are not significantly correlated to those in corresponding soil samples. Principal component analyses were conducted to distinguish samples on basis of their distribution in each town, soil type and vegetable specie. Relatively abundant soil PAHs were found in town Jun’an, Beijiao, Chencun, Lecong and Ronggui, while abundant vegetable PAHs were observed in town Jun’an, Lecong, Xingtan, Daliang and Chenchun. The highest level of total PAHs were found in vegetable soil, followed by pond sediment and “stacked soil” on pond banks. The PAHs contents in leafy vegetables are higher than those in fruity vegetables. Some PAH compound ratios suggest the PAHs derived from incomplete combustion of petroleum, coal and refuse from power generation and ceramic manufacturing, and paint spraying on furniture, as well as sewage irrigation from textile industries. Soil PAHs contents have significant logarithmic correlation with total organic carbon, which demonstrates the importance of soil organic matter as sorbent to prevent losses of PAHs.     

Spatial and temporal distribution of polycyclic aromatic hydrocarbons (PAHs) in sediments of the Nansi Lake, China

Polycyclic aromatic hydrocarbons (PAHs) were measured in surface sediments and dated core sediments from the Nansi Lake of China to investigate the spatial and temporal distribution characteristics. The concentrations of 16 kinds priority PAH compounds were determined by GC-MS method. And ²¹⁰Pb isotope dating method was used to determine the chronological age of the sediment as well as the deposition rate. The results indicated that the total PAHs concentration ranges in surface and core sediment samples were 160 ~32,600 and 137 ~ 693 ng/g (dry wt.), respectively. The sediment rate and the average mass sedimentation were calculated to be 0.330 cm·year^???1 and 0.237 g·cm^???2·yr^???1 and the sediment time of the collected core sample ranged from 1899 to 2000. The peak of PAH concentrations came at recent years. The source analysis showed PAHs mainly came from the contamination of low temperature pyrogenic processes, such as coal combustion. The PAHs concentrations were lower than ERL and LEL values for most collected samples. However, in several surface sediment samples especially in estuary sites, the PAHs concentrations were not only higher than ERL and LEL values, but also higher than ERM values.