Polydopamine/NZVI@biochar composite (PDA/NZVI@BC) with high removal efficiency of tetracycline (TC) in aqueous solutions was successfully synthesized. The resultant composite demonstrated high reactivity, excellent stability and reusability over the reaction course. Such excellent performance can be attributed to the presence of the huge surface area on biochar (BC), which could enhance NZVI dispersion and prolong its longevity. The carbonyl group contained on the surface of biochar could combine with the amino group on polydopamine(PDA). The hydroxyl groups in PDA is able to enhance the dispersion and loading of NZVI on BC. Being modified by PDA, the hydrophilicity of biochar was improved. Among BC, pristine NZVI and PDA/NZVI@BC, PDA/ NZVI@BC exhibited the highest activity for removal of TC. Compared with NZVI, the removal efficiency of TC could be increased by 55.9% by using PDA/NZVI@BC under the same conditions. The optimal modification time of PDA was 8h, and the ratio of NZVI to BC was 1:2. In addition, the possible degradation mechanism of TC was proposed, which was based on the analysis of degraded products by LC-MS. Different important factors impacting on TC removal (including mass ratio of NZVI to BC/PDA, initial concentration, pH value and the initial temperature of the solution) were investigated as well. Overall, this study provides a promising alternative material and environmental pollution management option for antibiotic wastewater treatment.
Results of a survey of 156 Chinese mitten crab (Eriocheir sinensis) grow-out farms around Hongze Lake
(118.48–118.72°E; 33.36–33.38°N) are reported. Area farmed has remained relatively
unchanged but production (59 932 t in 2012)
increased steadily over the last 7 years, indicative of the viability and
sustainability of the farming system that has gradually replaced intensive Chinese
major carp polyculture around Hongze Lake. Results showed that production range was
135–2400 kg ha−1 cycle−1
(mean 1144 ± 34). Crab yields correlated linearly to stocking density and conformed
to a normal distribution curve, with 66.7 % of farms yielding
900 kg ha−1 cycle−1 or more.
Yield was negatively correlated to pond size and capture size (p < 0.01), and farms with macrophyte coverage rate
lower than 30 % of water surface were significantly (p < 0.05) lower than those exceeding 30 %.
Electronic supplementary material
The online version of this article (doi:10.1007/s13280-015-0722-0) contains supplementary material, which is available to authorized
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Selecting a material for biogas storage membranes is becoming increasingly vital because of the wide applications of biogas storage membranes in biogas plants. Material selection has numerous influencing factors, including gas permeability, strength, density, and so on. Among these, gas permeability has a vital role in biogas storage membranes. In this study, three kinds of biogas storage membranes with the same thickness were selected to investigate the effects of temperature (10, 20, 30, and 40°C) and relative humidity (RH; 0%, 50%, and 100%) on the permeability rate of biogas storage membranes. Results demonstrated that when various membrane samples with the same RH values were tested, temperature exhibited a strong effect on permeability rate. Kinetic analysis showed that the relationship between permeability and temperature agrees with the Arrhenius equation. However, no remarkable variation in methane permeability was observed for membranes with the same temperature but different RH values, thus suggesting that RH nearly has no obvious direct influence on the permeability rate of membranes. 相似文献
The potential of using mollusk shell powder in aragonite (razor clam shells, RCS) and calcite phase (oyster shells, OS) to remove Pb2+, Cd2+ and Zn2+ from contaminated water was investigated. Both biogenic sorbents displayed very high sorption capacities for the three metals except for Cd on OS. XRD, SEM and XPS results demonstrated that surface precipitation leading to crystal growth took place during sorption. Calcite OS displayed a remarkably higher sorption capacity to Pb than aragonite RCS, while the opposite was observed for Cd. However, both sorbents displayed similar sorption capacities to Zn. These could be due to the different extent of matching in crystal lattice between the metal bearing precipitate and the substrates. The initial pH of the solution, sorbent’s dosage and grain size affected the removal efficiency of the heavy meals significantly, while the organic matter in mollusk shells affected the removal efficiency to a lesser extent. 相似文献