超临界反应的应用

采用环境友好的溶剂在超临界状态下进行的化学反应,能加快化学反应速率,提高反应的产率和选择性,方便地实现反应分离过程的一体化,该技术以其独特的优越性获得了广泛研究与关注。笔者简述了近年来超临界反应在石油化工、环境保护、生物柴油制备领域的应用。     

用H-Kappa方法反演龙门山断裂带及其邻区的莫霍面深度及波速比分布

利用龙门山断裂带及其邻近地区地震台站的远震波形记录,采用时间域迭代反褶积技术求取接收函数,并用多次反射波能量扫描求极大值和波形叠加反演的方法(H-Kappa方法)计算出台站下方的莫霍面深度和波速比。结果显示:莫霍面位于扬子地台西缘部分向西侧倾斜缓降,深度在40～48 km变化,地壳平均波速比值为1.81;都江堰、汶川、耿达一带处在龙门山推覆体范围之内的莫霍面起伏变化不大,深度在45 km左右,地壳平均波速比值为1.707 5;龙门山断裂带西侧的松潘—甘孜地块的平均地壳波速比为1.76,莫霍面深度南面部分比北面深约10 km,呈南深北浅状。     

安徽省TJ-Ⅱ型钻孔体应变同震效应分析

描述了安徽省地震局"十一五"期间安装的5套钻孔体应变仪的地质构造特点与钻孔岩芯物理特性,介绍了TJ-Ⅱ体应变仪的运行情况。通过对两次强震活动的同震效应分析,初步探讨了地理、地质构造条件不同的情况下,各观测井对记录应力活动能力强弱的反映。     

对规范环境监察执法工作的几点思考

结合环境执法工作实际,提出应对新形势下环境保护执法工作中存在问题的方法。     

基于期望理论的违章行为管理思路探讨

通过对企业生产中违章行为心理动因的探索,提出了违章的行为函数,并对弗洛姆的期望理论进行了逆向解读和分析,从而佐证了违章行为函数的合理性,指出了从行为者心理动因角度减少或者杜绝违章行为的策略。     

Kinetics of enzymatic unhairing by protease in leather industry

In leather industry, unhairing is a heavy pollution operation. The conventional lime-sulfide process produces a large amount of sulfide which is toxic to health and difficult to dispose. Moreover, conventional lime-sulfide process leads to the destruction of the hair causing increased COD, BOD and TDS loads in the effluent. As an alternative method, enzymatic unhairing is a promising clean technology. The main utilized enzyme preparations are proteases.There are many reports about enzymatic unhairing, most of which are qualitative. The kinetics of enzymatic unhairing by protease was discussed in this article. It will provide useful information to enzymatic unhairing. In our research, by analysis of the concentrations of released total protein in enzyme bath during protease unhairing, the good linearity between released total protein and square root of time (min^1/2) was obtained at the initial stage. The good linearity suggests that enzymatic unhairing by protease is a diffusion-controlled process at the initial stage. The analysis of kinetics of released saccharides also confirms the same conclusion. On the other hand, the same characteristics between the kinetics of released saccharides and that of released total protein further confirms that it is the hydrolysis of core protein by protease that leads to the degradation of proteoglycans and the release of protein and saccharides. However, in our tests, the kinetics of released collagen indicates that the injury to skin took place in 3-6 h. Therefore, it’s necessary to control the time of protease unhairing within an appropriate limit.     

Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium nitrogen (NH4 +-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4 +-N recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4 +-N recovery from coking wastewater was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4 + molar ratio (Mg/N) and the initial NH4 +-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4 + and CO3 2??/NH4 + molar ratios (Ca/N and CO3 2??/N), respectively. The trends for NH4 +-N removal at different pH and Mg/N levels were similar to the thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3 2??/N), (pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4 +-N recovery.     

Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period

Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir.     

Cadmium removal from wastewater by sponge iron sphere prepared by hydrogen reduction

A new type of sponge iron sphere (NSIS) with 1-5 mm diameter, made of concentrated iron powder and possessed high activity and intension, was prepared by mini-pellet sintering integrated with H₂ direct reduction. Static state experiment has been carried on to investigate the Cd²⁺ removal efficiency from wastewater by the NSIS and to explore the Cd²⁺ removal reaction kinetics. It was suggested that initial pH value and Cd²⁺ original concentration had significant influence on Cd²⁺ removal percentage. Cd²⁺ removal percentage decreased significantly with the increasing of Cd²⁺original concentration whether the original pH value be adjusted to 3.0 or without adjustment. The results showed that the Cd²⁺ removal process followed the first order reaction because the reaction order was from 0.803 to 0.996. The apparent reaction rate constant between Cd²⁺ and NSIS was from 0.0025 to 0.1000 (mg·L^?1)^1-n·min^?1. Compared with SIS reduced by charcoal reduction, NSIS deoxided by hydrogen possessed higher activity, and could remove the same quantity of Cd²⁺ within a shorter period of time.     

土壤pH、Eh对土壤-苦丁茶树系统中铅分布的影响

以苫丁茶冬青(Ilex kudingcha C.J.Tseng)扦插苗(15个月生)进行盆栽实验,通过土施H2SO4、Ca(OH)2和复合肥,改变土壤pH和氧化还原电位(Eh),研究土壤pH、Eh条件对土壤-苦丁茶树系统中铅分布的影响.结果表明:在所研究的土壤pH范围内,从酸性到碱性变化,铅在土壤中含量分布趋于减少,在...