Seasonal changes in daily precipitation extremes in mainland Portugal from 1941 to 2007

This study aims mostly at understanding seasonal variations in the intensity, frequency and duration of extreme precipitation events in mainland Portugal. For this purpose, selected precipitation indices that mainly focus on extremes were calculated at the seasonal scale for daily data recorded in the period 1941–2007 at 57 meteorological stations scattered across the area. These indices were explored for trends at the local and regional levels. The results show that there are marked changes in precipitation indices at the seasonal scale. Trends in spring and autumn precipitation have opposite signals. In spring, statistically significant drying trends are found together with a reduction in extremes. In autumn, wetting trends are detected for all indices, although overall they are not significant at the 5 % level. In addition, the relationship between seasonal extreme precipitation indices and atmospheric large-scale modes of low-frequency variability is analysed by means of a seasonal correlation analysis. Four modes of low-frequency variability are explored. Results confirm that, over mainland Portugal, the North Atlantic Oscillation is one of the most important teleconnection patterns in any season and the mode of variability that has the greatest influence on precipitation extremes in the area, particularly in the winter and autumn.     

Sorption and desorption of sulfentrazone in Brazilian soils

This study was undertaken to obtain information about the behavior of sulfentrazone in soil by evaluating the sorption and desorption of the herbicide in different Brazilian soils. Batch equilibrium method was used and the samples were analyzed by high performance liquid chromatography. Based on the results obtained from the values of Freundlich constants (Kf), we determined the order of sorption (Haplic Planosol < Red-Yellow Latosol < Red Argisol < Humic Cambisol < Regolitic Neosol) and desorption (Regolitic Neosol < Red Argisol < Humic Cambisol < Haplic Planosol < Red-Yellow Latosol) of sulfentrazone in the soils. The process of pesticide sorption in soils was dependent on the levels of organic matter and clay, while desorption was influenced by the organic matter content and soil pH. Thus, the use of sulfentrazone in soils with low clay content and organic matter (low sorption) increases the probability of contaminating future crops.     

Recycling of wastes from fish beneficiation by composting: chemical characteristics of the compost and efficiency of their humic acids in stimulating the growth of lettuce

Waste from the beneficiation of fish was composted with crushed grass aiming to characterize their chemical composition and investigate the possibility of the use of the final compost as source of humic acids (HA) able to stimulate the growth of lettuce. Compost presented pH value, C/N ratio, and electrical conductivity that allow its use as an organic fertilizer. The element content was present in the following order of abundance in the compost: P?>?Ca?>?N?>?Mg?>?K?>?Fe?>?Zn?>?Mn?>?Mo?>?Cu, and the humus composition was similar to that observed in others kind of organic residues composted. The high content of oxygen pointed out a high level of oxidation of HA, in line with the predominance of phenolic acidity in the functional groups. The ¹³C-NMR spectra showed marked resonances due to the presence of lipids and other materials resistant to degradation as methoxy substituent and N-alkyl groups. A concentration of 20 mg L^?1 HA increased significantly both dry and wet root matter in lettuce but the CO₂ assimilation, stomatal conductance, and number of lateral roots of the plants were not affected. However, increases of 64% in the water-use efficiency was observed due to the HA addition, probably related to the root morphology alteration which resulted in 1.6-fold increase of lateral root average length and due to the higher H⁺ extrusion activity. Reuse of residues from the fish beneficiation activity by composting may represent a safe tool to increase the value of recycled organic residues and generate HA with potential use as plant growth stimulants.     

Decision support model for assessing aquifer pollution hazard and prioritizing groundwater resources management in the wet Pampa plain, Argentina

This paper gives an account of the implementation of a decision support system for assessing aquifer pollution hazard and prioritizing subwatersheds for groundwater resources management in the southeastern Pampa plain of Argentina. The use of this system is demonstrated with an example from Dulce Stream Basin (1,000 km² encompassing 27 subwatersheds), which has high level of agricultural activities and extensive available data regarding aquifer geology. In the logic model, aquifer pollution hazard is assessed as a function of two primary topics: groundwater and soil conditions. This logic model shows the state of each evaluated landscape with respect to aquifer pollution hazard based mainly on the parameters of the DRASTIC and GOD models. The decision model allows prioritizing subwatersheds for groundwater resources management according to three main criteria including farming activities, agrochemical application, and irrigation use. Stakeholder participation, through interviews, in combination with expert judgment was used to select and weight each criterion. The resulting subwatershed priority map, by combining the logic and decision models, allowed identifying five subwatersheds in the upper and middle basin as the main aquifer protection areas. The results reasonably fit the natural conditions of the basin, identifying those subwatersheds with shallow water depth, loam–loam silt texture soil media and pasture land cover in the middle basin, and others with intensive agricultural activity, coinciding with the natural recharge area to the aquifer system. Major difficulties and some recommendations of applying this methodology in real-world situations are discussed.     

Recycled Polyethylene Composites Reinforced with Jute Fabric from Sackcloth: Part II-Impact Strength Evaluation

Environmental problems are motivating recycling actions and reuse alternatives for materials with main focus for the application of those renewable and biodegradable materials such as lignocellulosic fibers. Composites reinforced with such fibers are being considered by several industrial sectors, not only from the environmental safety, but also from economic considerations and improved properties. This paper, which is continuation of the work (Part I) by the authors’ use of the recycled polyethylene and used jute fabrics, presents evaluation of its toughness measured by the impact energy using both Izod and Charpy methods. Fabric content used is up to 40 wt. %. It is found that the incorporation of both types (new and used) of jute fabric significantly increased the impact energy of composites, with higher values associated with the new jute fabric. Fractographic analysis revealed that weaved configuration of the jute fibers and their low interfacial resistance with the matrix are responsible for the observed impact performance of these composites.     

Optimization of artificial neural network models through genetic algorithms for surface ozone concentration forecasting

Introduction

This study proposes three methodologies to define artificial neural network models through genetic algorithms (GAs) to predict the next-day hourly average surface ozone (O₃) concentrations. GAs were applied to define the activation function in hidden layer and the number of hidden neurons.

Methods

Two of the methodologies define threshold models, which assume that the behaviour of the dependent variable (O₃ concentrations) changes when it enters in a different regime (two and four regimes were considered in this study). The change from one regime to another depends on a specific value (threshold value) of an explanatory variable (threshold variable), which is also defined by GAs. The predictor variables were the hourly average concentrations of carbon monoxide (CO), nitrogen oxide, nitrogen dioxide (NO₂), and O₃ (recorded in the previous day at an urban site with traffic influence) and also meteorological data (hourly averages of temperature, solar radiation, relative humidity and wind speed). The study was performed for the period from May to August 2004.

Results and discussion

Several models were achieved and only the best model of each methodology was analysed. In threshold models, the variables selected by GAs to define the O₃ regimes were temperature, CO and NO₂ concentrations, due to their importance in O₃ chemistry in an urban atmosphere.

Conclusion

In the prediction of O₃ concentrations, the threshold model that considers two regimes was the one that fitted the data most efficiently.     

Psychosocial and ergonomic survey of office and field jobs in a utility company

Introduction. The effect of different kinds of work on the psychosocial assessment of workers under the same management and organizational environment is investigated. Methods. A voluntary assessment in a utility company was carried out using the short version of the Copenhagen psychosocial questionnaire (CoPsoQ) on two occasions, 1.5 years apart. Initially, 25 office workers (11 men and 14 women) participated, while 14 of those workers (8 women and 6 men) participated in the second assessment together with 32 field workers. The sewage, water treatment and maintenance workers, totaling 32 men, also participated in a field ergonomics assessment using the Washington State Department of Labor and Industries field work ergonomic checklist. Results. The longitudinal outlook was fairly stable, with sustained severe scores in many CoPsoQ subscales and intensification of severity of workers’ control over work and esteem for men. A significantly higher esteem score resulted for field rather than office workers. Workers subjected to foul odors showed similar severity of psychosocial factors. Discussion. For most psychosocial dimensions, the organizational design and management system in place, as well as the overall cultural environment in which it operates, create a much stronger and more decisive impact than job-specific factors.     

Humic substances formation during poultry litter composting and its influence on the structural characteristics of the compost

Journal of Material Cycles and Waste Management - This study aimed to elucidate the formation process of humic substances (HS) during poultry litter (PL) composting and its influence on the...     

Biological activities of the essential oil from the leaves of Lantana montevidensis (Spreng) Briq. in mice

Environment, Development and Sustainability - This work aimed to analyze the chemical composition and evaluate the anti-inflammatory and antinociceptive properties of the essential oil obtained...