全文获取类型
收费全文 | 5544篇 |
免费 | 487篇 |
国内免费 | 1679篇 |
专业分类
安全科学 | 492篇 |
废物处理 | 245篇 |
环保管理 | 512篇 |
综合类 | 3311篇 |
基础理论 | 949篇 |
污染及防治 | 1417篇 |
评价与监测 | 360篇 |
社会与环境 | 239篇 |
灾害及防治 | 185篇 |
出版年
2024年 | 25篇 |
2023年 | 114篇 |
2022年 | 287篇 |
2021年 | 265篇 |
2020年 | 254篇 |
2019年 | 193篇 |
2018年 | 229篇 |
2017年 | 250篇 |
2016年 | 234篇 |
2015年 | 254篇 |
2014年 | 388篇 |
2013年 | 540篇 |
2012年 | 508篇 |
2011年 | 497篇 |
2010年 | 422篇 |
2009年 | 440篇 |
2008年 | 400篇 |
2007年 | 389篇 |
2006年 | 334篇 |
2005年 | 246篇 |
2004年 | 188篇 |
2003年 | 206篇 |
2002年 | 156篇 |
2001年 | 143篇 |
2000年 | 130篇 |
1999年 | 108篇 |
1998年 | 97篇 |
1997年 | 79篇 |
1996年 | 75篇 |
1995年 | 50篇 |
1994年 | 42篇 |
1993年 | 36篇 |
1992年 | 41篇 |
1991年 | 16篇 |
1990年 | 19篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有7710条查询结果,搜索用时 125 毫秒
191.
Bacterial strain Enterobacter aerogenes TJ-D capable of utilizing 2-methylquinoline as the sole carbon and energy source was isolated from acclimated activated sludge under denitrifying conditions. The ability to degrade 2-methylquinoline by E. aerogenes TJ-D was investigated under denitrifying conditions. Under optimal conditions of temperature (35℃) and initial pH 7, 2-methylquinoline of 100 mg/L was degraded within 176 hr. The degradation of 2-methylquinoline by E. aerogenes TJ-D could be well described by the Haldane model (R2 > 0.91). During the degradation period of 2-methylquinoline (initial concentration 100 mg/L), nitrate was almost completely consumed (the removal efficiency was 98.5%), while nitrite remained at low concentration (< 0.62 mg/L) during the whole denitrification period. 1,2,3,4-Tetrahydro-2-methylquinoline, 4-ethyl-benzenamine, N-butyl-benzenamine, N-ethyl-benzenamine and 2,6-diethyl-benzenamine were metabolites produced during the degradation. The degradation pathway of 2-methylquinoline by E. aerogenes TJ-D was proposed. 2-Methylquinoline is initially hydroxylated at C-4 to form 2-methyl-4-hydroxy-quinoline, and then forms 2-methyl-4-quinolinol as a result of tautomerism. Hydrogenation of the heterocyclic ring at positions 2 and 3 produces 2,3-dihydro-2-methyl-4-quinolinol. The carbon-carbon bond at position 2 and 3 in the heterocyclic ring may cleave and form 2-ethyl-N-ethyl-benzenamine. Tautomerism may result in the formation of 2,6-diethyl-benzenamine and N-butyl-benzenamine. 4-Ethyl-benzenamine and N-ethyl-benzenamine were produced as a result of losing one ethyl group from the above molecules. 相似文献
192.
193.
采用美国EPA TO-15的方法,研究了2011年3月份闽南城市区域空气中VOCs的含量及其污染特征。结果表明:1)漳州工业区空气的VOCs浓度为200.5μg/m3,污染较为严重;厦门交通干道VOCs浓度为74.0μg/m3,泉州商住区的VOCs浓度77.1μg/m3,污染较轻。2)漳州工业区采样点TOP5占TVOCs的比例最高,达77.3%;厦门交通干道与泉州商住区两采样点的TOP5占TVOCs的比例相近,分别为64.1%和62.0%。在所有的采样点中出现的TOP5组分比较集中,主要包括甲苯、苯、二氯甲烷、异丙醇、乙酸乙酯、1,1-二氯乙烯、萘等。3)机动车尾气的排放、工业溶剂的挥发和废气排放可能是厦漳泉三地大气VOCs的主要排放源。4)厦漳泉的BTEX主要来源于汽车尾气和汽油挥发;其中厦门和泉州BTEX浓度相比较处在较低污染水平,漳州处在中等水平。 相似文献
194.
Zengsheng Zhang Xuejiang Wang Yin Wang Siqing Xi Ling Chen Yalei Zhang Jianfu Zhao 《环境科学学报(英文版)》2013,25(5):1044-1053
Bamboo charcoal(BC) was used as starting material to prepare iron-modified bamboo charcoal(Fe-MBC) by its impregnation in FeCl 3 and HNO 3 solutions simultaneously,followed by microwave heating.The material can be used as an adsorbent for Pb(Ⅱ) contaminants removal in water.The composites were prepared with Fe molar concentration of 0.5,1.0 and 2.0 mol/L and characterized by means of N 2 adsorption-desorption isotherms,X-ray diffraction spectroscopy(XRD),scanning electron microscopy coupled with energy dispersive X-ray spectrometry(SEM-EDS),Fourier transform infrared(FT-IR) and point of zero charge(pH pzc) measurements.Nitrogen adsorption analyses showed that the BET specific surface area and total pore volume increased with iron impregnation.The adsorbent with Fe molar concentration of 2 mol/L(2Fe-MBC) exhibited the highest surface area and produced the best pore structure.The Pb(Ⅱ) adsorption process of 2Fe-MBC and BC were evaluated in batch experiments and 2Fe-MBC showed an excellent adsorption capability for removal Pb(Ⅱ).The adsorption of Pb(Ⅱ) strongly depended on solution pH,with maximum values at pH 5.0.The ionic strength had a significant effect on the adsorption at pH < 6.0.The adsorption isotherms followed the Langmuir isotherm model well,and the maximum adsorption capacity for Pb(Ⅱ) was 200.38 mg/g for 2Fe-MBC.The adsorption processes were well fitted by a pseudo second-order kinetic model.Thermodynamic parameters showed that the adsorption of Pb(Ⅱ) onto Fe-MBC was feasible,spontaneous,and exothermic under the studied conditions,and the ion exchange mechanism played an significant role.These results have important implications for the design of low-cost and effective adsorbents in the removal of Pb(Ⅱ) from wastewater. 相似文献
195.
Production and characteristics of typical taste and odor (T&O) compounds by Microcystis aeruginosa were investigated. A few terpenoid chemicals, including 2-MIB, β-cyclocitral, and β-ionone, and a few sulfur compounds, such as dimethyl sulfide and dimethyl trisulfide, were detected. β-Cyclocitral and β-carotene concentrations were observed to be relevant to the growth phases of Microcystis. During the stable growth phase, 41-865 fg/cell of β-cyclocitral were found in the laboratory culture. β-Cyclocitral concentrations correlated closely with β-carotene concentrations, with the correlation coefficient R2 = 0.96, as it is formed from the cleavage reaction of β-carotene. For dead cell cases, a high concentration of dimethyl trisulfide was detected at 3.48-6.37 fg/cell. Four T&O compounds, including β-cyclocitral, β-ionone, heptanal and dimethyl trisulfide, were tested and found to be able to inhibit and damage Microcystis cells to varying degrees. Among these chemicals, β-cyclocitral has the strongest ability to quickly rupture cells. 相似文献
196.
船舶大气污染排放的研究进展 总被引:1,自引:0,他引:1
船舶是大气污染的重要来源,其排放的NOx占化石燃料源的15%左右,SO2占人为源的4%~9%。国内外从3个方向开展对船舶大气污染的研究:(1)对大气气候影响;(2)源清单计算;(3)排放因子测量。船舶排放的多种污染物可改变空气质量;对大气辐射收支产生直接和间接影响;对海洋大气的成云效应产生影响。船舶源清单主要有2种计算方法:基于燃料消耗的方法,适用于长时间大尺度计算;基于船舶活动情况的方法,适用于高空间分辨率计算。排放因子测量有台架试验和空中烟羽测量2种方法:前者测量结果准确,条件设定自由;后者可行性高,并能提供颗粒物增长转化信息。国内研究尚处于起步阶段,需要建立完整的船舶排放清单,开展排放因子的测试和修正工作。 相似文献
197.
198.
199.
针对公路危险化学品运输车辆泄漏突发性环境污染事故发生突然、危害严重等特点,阐述了应急监测在污染事故中的关键作用。要求环境监测部门迅速反应,进行快速监测,并报出监测结果,为污染物的控制提供科学依据。本文为公路运输突发性环境污染事故应急监测提出了建议和要求。 相似文献
200.
运用PHAST软件研究泄漏孔径、风速、泄漏时间和大气稳定度对泄漏扩散面积的影响。结果表明:扩散面积随着泄漏孔径的增大、风速的增大及泄漏时间的增长而增加;大气越稳定,泄漏扩散面积越大。 相似文献