水中三嗪类除草剂的检测与分析质量控制

三嗪类除草剂作为预防农田杂草生长的除草剂在世界范围内广泛使用.由于水中农药残留浓度属痕量级,建立高效富集与分析方法非常重要.选取了6种三嗪类物质,建立了对水中痕量三嗪类物质的SPE-HPLC分析方法,并对其分析方法进行了质量保证与质量控制QA/QC研究.研究结果表明: 6种三嗪类物质的回收率在94%～116%之间,方法检测限在0.08～0.18 μg·L-1之间,方法重复性和检测限均能满足痕量分析及其质量控制的要求.3种水样的实际测试结果表明,在某河水中测得莠去津和扑草净的质量浓度分别为(5.28±0.43) μg·L-1和(7.12±0.54) μg·L-1.这说明该水体三嗪类农药的污染需受到重视.     

二氧化锰氧化降解五氯酚

以二氧化锰为氧化剂,研究了pH 4.12的水溶液中五氯酚氧化降解的反应动力学,并讨论了反应溶液的pH对反应动力学的影响.结果表明,五氯酚对二氧化锰的氧化作用具有较强的反应感受性.在pH一定和二氧化锰充分过量的条件下,随着反应的进行,五氯酚的降解速度变慢,遵循的不是简单的准一级反应动力学而是复合的反应动力学.此外,随溶液pH由3.5升高6.6,五氯酚的降解速度发生显著地下降.运用溶剂萃取和气质联用仪的分析方法,检测到2个主产物和1个次产物.其中,次产物是由四氯-1,4-氢醌与四氯儿茶酚组成的混合物;2个主产物是由五氯酚氧自由基偶合而成的二聚体,且是同分异构体.在观测到的表面反应动力学和降解产物的基础上,提出了五氯酚被二氧化锰氧化降解的反应流程图.     

Biotransfer of persistent organic pollutants from a large site in China used for the disassembly of electronic and electrical waste

Samples of groundwater, river water, river sediment, paddy soil, rice seeds, hen eggs, fish, umbilical cord blood, and newborn meconium were collected from October 2002 to October 2003 near a large site in China used for the disassembly of obsolete transformers and other electronic or electrical waste. Six indicator PCB congeners, three non-ortho dioxin-like PCB congeners, and six organochlorine pesticides were determined in the samples by GC with electron capture detector. The results demonstrated that the local environment and edible foods had been seriously polluted by toxic PCBs and organochlorine pesticides. The actual daily intakes (ADIs) of these pollutants were estimated for local residents living in the area. The intake data showed that the contents of PCBs in these local residents were substantial, as the ADI estimates greatly exceed the reference doses set by the World Health Organization and the United States Agency for Toxic Substances and Disease Registry. The presence of the indicator PCB congeners in the cord blood and the meconium samples, as well as significant correlations (r ² > 0.80, p < 0.05) between these levels, suggests a potential biotransfer of these indicators from mothers to their newborns. This preliminary study showed that obsolete transformers and other electronic or electrical waste can be an important source for the emission of persistent organic pollutants into the local environment, such as through leakage, evaporation, runoff, and leaching. Contamination from this source appears to have reached the level considered to be a serious threat to environmental and human health around the disassembly site.     

多源数据融合的城市区域型消防风险分布特征研究 ——以太原都市圈所在区域为例

分析区域消防风险的空间演化特征,针对性建立并调整消防站点,可预见性地降低消防风险.以太原都市圈所在区域作为研究对象,将遥感数据、POI兴趣点数据经标准化处理后融入GIS-GANP模型中,识别城市区域间特异性消防风险因子,探讨区域消防风险系数及空间分布特征,并多角度分析消防站点规划趋势.结果表明:POI数据符合区域融合发...     

活性污泥数学模型(ASM1)入流组分测定及应用

阐述了活性污泥 1号模型 (ASM1)入流中 7个含碳有机物、4个含氮物质、碱度等四大类 13种组分的分析方法 ,并用这些方法测定了西安市北石桥、电子村两个排放口的城市污水水质。实验结果表明快速可生物降解有机物 (SS)采用间歇实验法、慢速可生物降解有机物 (XS)采用测定BOD5间接计算法既操作简单又准确可靠 ,能为利用活性污泥 1号模型进行污水处理厂的设计、模拟及管理提供入流组分分析依据     

三峡库区万州区段长江水中泥沙量对其水质的影响分析

长江三峡库区的生态环境及水质情况。随着三峡工程建设的不断深入而备受社会各界的瞩目。重庆市万州区地处三峡水库腹心地带。长江自西南向东北横穿万州区全境。过境流程83公里。万州区溪流纵横。水网密布，多数河流直接排入长江。而且在三峡库区大移民进程中有大量的移民集中在万州。在三峡大坝即将合龙之际，研究长江万州流域的水质情况无疑对指导库区的清理工作、生态环境建设等具有重大意义。本文对该地区的水污染源进行了初步考察。同时对万州区段长江流域的水质进行了探索性研究。发现该区水土流失情况较为严重，而且水中的泥沙含量与其COD水平有相关关系。江水中大部分的COD是由泥沙携带的有机物的贡献。     

中国水稻收获环节的损失有多高?——基于5省6地的实验调查

受资源禀赋的约束,减少粮食产后损失日益成为增加粮食供给、保障粮食安全的重要措施之一。论文采取实地测量的方法,在全国5省6地开展田间实验和调查访谈,考察了水稻收获环节的损失情况。结果显示：各实验地块水稻收获环节的损失率为1.18%~6.55%。其中,水稻联合收获的损失率显著高于分段收获,先进机型收获的损失率低于普通机型,田地湿度、倒伏程度与水稻收获环节的损失率正相关。结合水稻优势区域的分布推算,全国水稻收获环节的损失率为3.02%。减损的情景模拟表明,当全国水稻收获环节的损失率下降到2.76%（根据农业部《水稻机械化生产技术指导意见》测算）,可节约稻谷54万t,可供439万人消费1 a,相当于节约耕地7.84万hm²,化肥2.61万t（折纯）。     

氯苯对球形红细菌的毒性效应研究

研究不同质量浓度氯苯对光合细菌球形红细菌(Rhodobacter sphaeroides)生长和脱氢酶活性的影响.结果发现,当氯苯质量浓度达到80 mg/L时,即可抑制球形红细菌的生长;当氯苯质量浓度增加到1 000 mg/L时,球形红细菌的生长被完全抑制.球形红细菌脱氢酶活性随氯苯质量浓度增加而明显降低.在此基础上进一步运用化学品对水生生物急性毒性实验的标准方法研究了氯苯对球形红细菌的毒性效应.结果表明,氯苯对球形红细菌生长的安全质量浓度(最低可见效应质量浓度LOEC)为40 mg/L.抑制球形红细菌生长的96 h-EC50为346.7 mg/L.氯苯与球形红细菌的质量浓度-效应方程为y=11.1459-2.416x,R2=0.989 7.对该质量浓度-效应方程进行χ2检验表明,结果符合精度要求,计算出的96 h-EC50真实可靠.     

Photolysis of nonylphenol ethoxylates: the determination of the degradation kinetics and the intermediate products

The photolysis of nonylphenol ethoxylates with an average oligomers length of ten ethoxylate units (NPEO(10)) in aqueous solution under UV, as well as the influence of humic acid (HA) on the photolysis was studied. A 125W high-pressure mercury lamp was employed as the light source. The intermediate products from the photolysis were determined by LC-MS. The results indicated that NPEO(10) underwent direct photolysis upon exposed to UV. The degradation pathway was complex. Besides the generally proposed degradation pathway of ethylene oxide (EO) side chains shortening, the oxidation of alkyl chain and EO chain led to intermediates having both a carboxylated (as well as carbonylated) ethoxylate and alkyl chain of varying lengths. The hydrogenation of benzene ring was also detected. The kinetics data showed that the first order reaction kinetics could be well used to describe the kinetics of NPEO(10) degradation. In the presence of dissolved organic matter by HA addition, the performance of NPEO(10) photodegradation was reduced. The photolysis rate decreased with increased HA concentration.