利用剩余活性污泥生产一次性可降解材料

为了缓解污水处理厂日益严重的污泥处置难题,实现剩余活性污泥的无害化、减量化、稳定化、资源化利用。采用SBR系统对剩余活性污泥进行10 d的驯化,加入4.0 g/L的乙酸钠作为发酵培养基碳源和前体物质,累积聚羟基烷酸酯(polyhydroxyalkanoates,PHA)。30℃好氧发酵10 h后,PHA积累达1 125 mg/L,占污泥浓度(MLSS)的质量分数为35.7%。然后经过离心、烘干、粉碎后模压成型加工成一次性使用的可生物降解材料。使用正交实验进行优化,结果表明:其最佳的物料配比和模压条件为:干污泥57%;稻草纤维20%;聚乙烯醇(PVA)19%;硬脂酸钡2%;氧化钙2%;最佳工艺条件为100℃,加热1.5 h,此时加工出来的产品具有最优的抗压强度和拉伸强度。以本方法制成的可生物降解花盆其所含细菌总数、粪大肠菌群、蛔虫卵死亡率均达到国标所规定的污泥农用生物安全要求;另外,试样中未检出病毒;其重金属含量也达到国标所规定的污泥农用标准;其可生物降解性能达到了可降解材料的要求。因而本研究制备的一次性使用可降解花盆具有较好的开发和应用价值。     

Fe-MCM-41催化氧化2,4-二氯苯氧乙酸

采用水热法合成了Fe-MCM-41中孔分子筛,紫外、红外及XRD表征显示铁离子已进入中孔分子筛骨架。以H2O2为氧化剂形成类Fenton试剂,实验结果表明,在催化剂加入量为1 g/L、H2O2体积分数为6%、pH为4、反应时间为10h、反应温度为35℃的条件下,处理质量浓度为50 mg/L的2,4-D废水的降解率达94.95%。宏观动力学研究显示,该反应近似为一级反应,反应速率常数、表观活化能分别为0.21667 min-1和26.65 kJ/mol。     

3种运行模式下CAST工艺脱氮性能

以模拟城市污水为处理对象,采用循环式活性污泥法（CAST）反应器,对3种运行模式（M1：常规模式,M2：缺氧好氧模式、M3：缺氧好氧交替模式）下系统的脱氮性能进行了研究,比较了各模式下CAST反应器的氨氮和总氮的去除效率,并对各模式下典型周期内氮基质浓度变化进行了考察,以确定系统的脱氮模式。结果表明,在氨氮去除不成为限制条件（去除率〉90％）的条件下,3种运行模式下系统总氮的平均去除率分别为67．3％、70．6％和82．4％,以缺氧好氧交替模式下的最高;M1、M2和M3均可实现亚硝酸型硝化,但随着温度的升高,亚硝酸型硝化逐渐消失。静态实验分析表明,3种模式下系统的氨氧化速率大小次序为：vN：M1〉vN：M2〉vN：M3,反硝化速率大小次序为：vDN,M2〉vDN,M3〉vDN,M1。     

CNTs/TiO2/CS光降解苯的动力学

综合光催化氧化苯的动力学过程、光辐射场模型和质量守恒定律,采用平板型反应器建立了碳纳米管/二氧化钛/壳聚糖(CNTs/TiO2/CS)催化薄膜光催化氧化气相苯的数学模型;该模型考虑了光强、相对湿度、初始浓度与气体流速对气相苯光降解的影响。结果表明,建立的数学模型与实验结果吻合较好。     

Factors controlling phosphate interaction with iron oxides

Factors such as pH, solution ion composition, and the presence of natural organic matter (NOM) play a crucial role in the effectiveness of phosphorous adsorption by iron oxides. The interplay between these factors shows a complicated pattern and can sometimes lead to controversial results. With the help of mechanistic modeling and adsorption experiments, the net macroscopic effect of single and combined factors can be better understood and predicted. In the present work, the relative importance of the above-mentioned factors in the adsorption of phosphate was analyzed using modeling and comparison between the model prediction and experimental data. The results show that, under normal soil conditions, pH, concentration of Ca, and the presence of NOM are the most important factors that control adsorption of phosphate to iron oxides. The presence of Ca not only enhances the amount of phosphate adsorbed but also changes the pH dependency of the adsorption. An increase of dissolved organic carbon from 0.5 to 50 mg L can lead to a >50% decrease in the amount of phosphate adsorbed. Silicic acid may decrease phosphate adsorption, but this effect is only important at a very low phosphate concentration, in particular at high pH.     

昆明市污水排水系统产甲烷规律的模拟实验研究

通过对昆明市餐饮和居民生活污水厌氧模拟实验研究,初步探讨生活污水中CH4的产生规律,实验结果表明,在自然条件下,餐饮和居民生活污水中产生的甲烷浓度最大值分别为1.63 mg/L和3.82 mg/L。并且将COD、硫酸盐、硫化物、TN的浓度变化与甲烷浓度变化进行Pearson简单相关性分析,结果表明,1/COD、COD/硫酸盐和1/TN与甲烷在置信度为0.01时极显著相关,硫化物与甲烷在置信度为0.05时不相关;COD、硫酸盐和TN浓度的变化对生活污水中甲烷的产生起关键性作用。对居民生活污水中甲烷产生规律进行温度和pH控制分析研究,实验结果表明,生活污水在25~30℃时,24 h内甲烷产生量最大值为8.6494 mg/L,明显大于其他温度段的甲烷产生量;在pH为7~8之间时,甲烷的产生量在24 h内达到的最大值为3.0477 mg/L,明显高于其他pH控制段的甲烷产生量。     

盐酸溶液改性蛭石对气态单质汞的吸附性能

采用盐酸溶液对蛭石进行浸渍处理,考察了盐酸溶液改性蛭石对气态单质汞的吸附能力。研究结果表明：盐酸溶液改性蛭石对气态单质汞的吸附效果好于未改性蛭石,盐酸浓度为4．0mol／L时,盐酸溶液改性蛭石对气态单质汞的吸附效果较佳;进气中气态单质汞的质量浓度越高,盐酸溶液改性蛭石对气态单质汞的去除率越低;适当提高吸附温度对盐酸溶液改性蛭石吸附气态单质汞较有利;降低蛭石粒径,盐酸溶液改性蛭石对气态单质汞的去除率提高。     

Distribution,sources, and ecological risk assessment of SVOCs in surface sediments from Guan River Estuary,China

The contamination of semi-volatile organic compounds (SVOCs) in the surface sediments of the Guan River Estuary, China was fully investigated. Total concentrations of 56 species of SVOCs ranged from 132 to 274 ng/g with an average of 186 ng/g (dry weight). Polycyclic aromatic hydrocarbon (PAH) concentrations were positively correlated with clay content and negatively correlated with sediment grain size. Source identification indicated that PAHs originated mainly from pyrolytic sources. However, intense ship traffic in the estuary may provide sources of petrogenic PAHs. Organochlorine pesticides (OCPs) mainly originated from direct input of dichlorodiphenyltrichloroethanes (DDTs) during some industrial processes. The SVOC concentrations were also compared with International Sediments Quality Guidelines and Sediments Quality Criteria, and the results indicated that negative biological impacts may originate from high concentrations of FLO, p,p′-DDE, and total DDTs.     

云南兰花生物技术的商品化开发

云南是我国兰科植物资源最丰富的地区，云南兰花共１００属４７２种，中国传统的观赏兰花－兰属植物和具开发潜力的热带兰种类多、分布广，使云南成为天然的兰花资源基因 。近年来，采挖性的商品开发导致云南丰富的兰花资源遭到严重破坏。     

九峰山地区的生物资源及其保护

九峰山地区天然植被保存完整,动植物资源颇为丰富。该区有维管束植物82科302属596种;陆栖脊椎动物134种,其中兽类25种、鸟类100种(另有2亚种)、两栖和爬行类7种、鱼类2种。蒙古扁桃和黄芪为国家三类保护植物,青羊和雪豹为国家二类保护兽类,金雕等13种鸟为国家二类保护鸟类;另外还有其它用途的经济动、植物。