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71.
阐述了GHS产生的背景及其在减少化学品事故,提高化学品安全管理水平,消除贸易壁垒,降低监管、企业成本等方面发挥的重要作用。介绍了GHS国内应用情况,对国内推行GHS提出了几点建议。 相似文献
72.
Manita Thakur Deepak Pathania Gaurav Sharma Mu. Naushad Amit Bhatnagar Mohammad Rizwan Khan 《Journal of Polymers and the Environment》2018,26(4):1415-1424
Gelatin-Zr(IV) phosphate composite (GT/ZPC) was synthesized by sol–gel method. Different techniques viz. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray powdered diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used for the characterisation of GT/ZPC composite ion exchanger. The ion exchange capacity (IEC) of GT/ZPC was observed to be better (1.04 meq g?1) than its inorganic counterpart (0.64 meq g?1). The pH studies revealed the monofunctional nature of GT/ZPC with one inflection point. The distribution studies showed that the GT/ZPC was highly selective for Cd2+ as compare to other metal ions. The environmental applicability of ion exchanger has been analysed for binary separations of metal ions using column method. Cd2+ was effectively removed from synthetic mixture of metal ions (Zn2+, Pb2+, Ni2+, Co2+ and Cu2+). 相似文献
73.
Zhanguo Liang Jun Mu Ying Mu Jiaming Shi Wenjing Hao Xuewei Dong Hongquan Yu 《环境科学学报(英文版)》2013,(S1):S106-S109
We have created a new method of ZnS nanospheres synthesis. By interface-mediated precipitation method (IMPM), monodisperse ZnS nanoparticles was synthesized on the particle surface of sulfate-reducing bacterium nutritious agar culture. Sulfate-reducing bacterium (SRB) was used as a sulfide producer because of its dissimilatory sulfate reduction capability, meanwhile produced a variety of amino acids acting as templates for nanomaterials synthesis. Then zinc acetate was dispersed into nutritious agar plate. Subsequently agar plate was broken into particles bearing much external surface, which successfully mediated the synthesis of monodisperse ZnS nanoparticles. The morphology of monodisperse ZnS nanospheres and SRB were examined by scanning electron microscopy (SEM), and the microstructure was investigated by X-ray diffraction (XRD). The thermostability of ZnS nanoparticles was determined by thermo gravimetric-differential thermo gravimetric (TG-DTG). The maximum absorption wavelengh was analysed with an ultravioletvisible spectrophotometer within a range of 199-700 nm. As a result, monodisperse ZnS nanoparticles were successfully synthesized, with an average diameter of 80 nm. Maximum absorption wavelengh was 228 nm, and heat decomposed temperature of monodisperse ZnS nanoparticles was 596℃. 相似文献
74.
石油污染地的土壤修复技术 总被引:1,自引:0,他引:1
对石油污染土壤的各类修复技术进行了总结和归纳,并对各项技术的优缺点加以比较,提出了一套石油污染地生态恢复的流程。 相似文献
75.
Rojas-Avelizapa NG Roldán-Carrillo T Zegarra-Martínez H Muñoz-Colunga AM Fernández-Linares LC 《Chemosphere》2007,66(9):1595-1600
The remediation of drilling mud-polluted sites in the Southeast of Mexico is a top priority for Mexican oil industry. The objective of this work was to find a technology to remediate these sites. A field trial was performed by composting in biopiles, where four 1ton soil-biopiles were established, one treatment in triplicate and one unamended biopile. Amended biopiles were added with nutrients to get a C/N/P ratio of 100/3/0.5 plus a bulking agent (straw) at a soil/straw ratio of 97/3. Moisture content was maintained around 30-35%. Results showed that, after 180 d, total petroleum hydrocarbon (TPH) concentrations decreased from 99300+/-23000mgTPHkg(-1) soil to 5500+/-770mgTPHkg(-1) for amended biopiles and to 22900+/-7800mgTPHkg(-1) for unamended biopile. An undisturbed soil control showed no change in TPH concentrations. Gas chromatographic analysis showed residual alkyl dibenzothiophene type compounds. Highest bacterial counts were observed during the first 30 d which correlated with highest TPH removal, whereas fungal count increased at the end of the experimentation period. Results suggested an important role of the straw, nutrient addition and water content in stimulating aerobic microbial activity and thus hydrocarbon removal. This finding opens an opportunity to remediate old polluted sites with recalcitrant and high TPH concentration. 相似文献
76.
Two different kinds of black liquor from the papermaking industry were treated by acidification and reuse. The experimental parameters and conditions were discussed in detail. The experimental results indicated that the treatment process mentioned in this article is an effective process for the treatment of black liquor from the papermaking industry. By the treatment, the solid materials in black liquor are transferred into two by-products and the other components are reused or evaporated. Thus, no wastewater except some condensation water would be discharged in pulping process and the problem of oollution of black liauor would be effectively solved. 相似文献
77.
78.
1引言 近年来,在北京市委、市政府的领导下,各职能部门的协同努力下,北京市危险化学品安全生产工作取得了显著成绩,制定了一系列危险化学品安全生产管理规范,开展了危险化学品从业单位安全质量标准化活动,进一步提高了从业单位的安全生产管理水平,我市危险化学品安全生产状况总体趋向好转. 相似文献
79.
80.
Sequential removal of heavy metals ions and organic pollutants using an algal-bacterial consortium 总被引:1,自引:0,他引:1
The residual algal-bacterial biomass from photosynthetically supported, organic pollutant biodegradation processes, in enclosed photobioreactors, was tested for its ability to accumulate Cu(II), Ni(II), Cd(II), and Zn(II). Salicylate was chosen as a model contaminant. The algal-bacterial biomass combined the high adsorption capacity of microalgae with the low cost of the residual biomass, which makes it an attractive biosorbent for environmental applications. Cu(II) was preferentially taken-up from the medium when the metals were present both separately and in combination. There was no observed competition for adsorption sites, which suggested that Cu(II), Ni(II), Cd(II), and Zn(II) bind to different sites and that active Ni(II), Cd(II) and Zn(II) binding groups were present at very low concentrations. Therefore, special focus was given to Cu(II) biosorption. Cu(II) biosorption by the algal-bacterial biomass was characterized by an initial fast cell surface adsorption followed by a slower metabolically driven uptake. pH, Cu(II), and algal-bacterial concentration significantly affected the biosorption capacity for Cu(II). Maximum Cu(II) adsorption capacities of 8.5+/-0.4 mg g-1 were achieved at an initial Cu(II) concentration of 20 mg l-1 and at pH 5 for the tested algal-bacterial biomass. These are consistent with values reported for other microbial sorbents under similar conditions. The desorption of Cu(II) from saturated biomass was feasible by elution with a 0.0125 M HCl solution. Simultaneous Cu(II) and salicylate removal in a continuous stirred tank photobioreactor was not feasible due to the high toxicity of Cu(II) towards the microbial culture. The introduction of an adsorption column, packed with the algal-bacterial biomass, prior to the photobioreactor reduced Cu(II) concentration, thereby allowing the subsequent salicylate biodegradation in the photobioreactor. 相似文献