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911.
The longitudinal dependence of black carbon concentration on traffic volume in an urban environment 总被引:1,自引:0,他引:1
deCastro BR Wang L Mihalic JN Breysse PN Geyh AS Buckley TJ 《Journal of the Air & Waste Management Association (1995)》2008,58(7):928-939
The purpose of this study was to evaluate the effect of traffic volume on ambient black carbon (BC) concentration in an inner-city neighborhood "hot spot" while accounting for modifying effects of weather and time. Continuous monitoring was conducted for 12 months at the Baltimore Traffic Study site surrounded by major urban streets that together carry over 150,000 vehicles per day. Outdoor BC concentration was measured with an Aethalometer; vehicles were counted pneumatically on two nearby streets. Meteorological data were also obtained. Missing data were imputed and all data were normalized to a 5-min observational interval (n = 105,120). Time-series modeling accounted for autoregressively (AR) correlated errors. This study found that outdoor BC was positively correlated at a statistically significant level with neighborhood-level vehicle counts, which contributed at a rate of 66 +/- 10 (SE) ng/m3 per 100 vehicles every 5 min. Winds from the SW-S-SE quarter were associated with the greatest increases in BC (376-612 ng/m3). These winds would have entrained BC from Baltimore's densely trafficked central business district, as well as a nearby interstate highway. The strong influence of wind direction implicates atmospheric transport processes in determining BC exposure. Dew point, mixing height, wind speed, season, and workday were also statistically significant predictors. Background exposure to BC was estimated to be 905 ng/m3. The optimal, statistically significant representation of BC's autocorrelation was AR([1:6]) x 288 x 2016, where the short-term AR factor (lags 1-6) indicated that BC concentrations are correlated for up to 30 min, and the AR factors for lags 288 and 2016 indicate longer-term autocorrelations at diurnal and weekly cycles, respectively. It was concluded that local exposure to BC from mobile sources is substantially modified by meteorological and temporal conditions, including atmospheric transport processes. BC concentration also demonstrates statistically significant autocorrelation at several time scales. 相似文献
912.
膜基活化溶液中活化剂在回收温室气体CO2过程中的作用 总被引:1,自引:0,他引:1
将AMP和PZ作为活化剂添加于MDEA溶液中,形成活化溶液,研究了膜基活化溶液回收温室气体CO2性能,着重考察活化剂的活化作用和对膜接触器传质加强的影响,提出一个活化机理来解释活化现象,建立了阻力层方程模型,并模拟膜基活化溶液回收CO2的传质过程。结果表明,活化剂对膜接触器传质的加强起到重要作用,具有双氨基环状结构的PZ对传质的加强作用高于具有空间位阻结构的AMP;活化溶液的CO2回收率和传质通量明显高于未活化的MDEA溶液,活化性能PZ〉AMP;活化剂的活化效应与分子结构有关;流体力学的改变对传质的影响有限,活化剂的反应动力学对传质的加强起主导作用;阻力层方程模型能较好地模拟膜基活化溶液回收CO2传质过程,传质通量和总传质系数的模型值与实验值符合较好。 相似文献
913.
Multivariate Analysis of Interactions Between Phytoplankton Biomass and Environmental Variables in Taihu Lake, China 总被引:1,自引:0,他引:1
Phytoplankton variation in large shallow eutrophic lakes is characterized by high spatial and temporal heterogenity. Understanding
the pattern of phytoplankton variation and the relationships between it and environmental variables can contribute to eutrophic
lakes management. In this study Taihu Lake, one of the largest eutrophic fresh water lake in China, was taken as study area.
The water body of Taihu Lake was divided into five regions viz. Wuli bay (WB), Meilian Bay (MB), West Taihu Lake (WTL), Main
Body of Taihu Lake (MBTL) and East Taihu Lake (ETL). Concentrations of chlorophyll-a and the related environmental variables
were determined in each region in the period 2000–2003. Factor analysis and multivariate analysis were applied to evaluate
the interactions between phytoplankton variation and environmental variables. Results showed that the highest average concentrations
of TN, TP and Chl-a were observed in WB, followed in a descending order by MB and WTL, and the lowest concentrations of TN,
TP and Chl-a were observed in MBTL and ETL. Chl-a and TP concentrations in most regions (except ETL) declined during the study
period. It suggested that to some extent the lake was recovering from eutrophication. However, persistent ascending of TN
and NH4–N in all five regions indicated the deteriorating of water quality in the study period. Results of multivariate showed that
the relationships between phytoplankton biomass and environmental variables varied among regions. TP illustrated itself a
controlling role on phytoplankton in WB, MB, WTL and MBTL according to the significant positive relations to phytoplankton
biomass in these regions. Nitrogen could be identified as a limiting factor to phytoplankton biomass in ETL in view of the
positive correlations between TN and phytoplankton and between NH4–N and phytoplankton. Spatial variation of interactions between phytoplankton and environmental parameters suggested proper
eutrophication control measures were needed to restore ecological system in each region of Taihu Lake. 相似文献
914.
The determination of trace amount nitrobenzene in wastewater on a hanging mercury drop electrode was studied. The determination
conditions of pH, supporting electrolyte, accumulation potential, accumulation time, and voltammetric response were optimized.
The sharp peak of the nitrobenzene was appeared at 0.05 V. The peak electric current was proportional to the concentration
of nitrobenzene in the range of 1.47 × 10−5 ∼ 1.0 × 10−3 mol/l with relative standard deviations of 3.99 ∼ 8.94%. The detection limit of the nitrobenzene in water was 5 × 10−6 mol/l. The proposed method offered low limit of determination, easy operation, the use of simple instrumentation, high sensitivity
and good reproducibility. It was applied to the determination of nitrobenzene in wastewater with an average recovery of 94.0%
∼ 105%. The proposed method provided fast, sensitive and sometimes real time detection of nitrobenzene. 相似文献
915.
An experimental study on recolonization and succession of marine macrobenthos in defaunated sediment 总被引:3,自引:0,他引:3
Hypoxia/anoxia in coastal waters is a world wide problem which often results in mass mortality and defaunation of benthos.
In this study, field experiments were carried out to examine recolonization and succession of macrobenthic infauna in defaunated
sediments, and the time required for recovery from complete defaunation to a stable community. Trays (33 cm length × 25.5 cm
width × 11 cm depth) of defaunated sediment were exposed at the subtidal of a pristine site in subtropical Hong Kong. Temporal
changes of macrobenthic communities in defaunated sediment were analyzed by univariate and multivariate statistics, and compared
with those in undisturbed natural sediment at the same site. Initial colonization of macrobenthos occurred rapidly. A total
of 42 species was found, with an average of 258 animals per tray and 24 species per tray recorded in the first month. Abundance
showed a small peak (496 animals per tray) after 3 months, reached a sharp peak (1154 animals per tray) after 6 months, and
declined thereafter. Species number increased gradually, reached a maximum (68 species per tray) after 9 months, and then
decreased. Recolonization was predominantly contributed by larval settlement rather than adult migration. Temporal changes
in abundance, species number and diversity of the macrobenthic community in defaunated sediment resemble the spatial changes
along a decreasing pollution gradient previously defined by other authors. Results of this experiment suggest that newly available
sediment may allow more species to colonize (or coexist) than sediment pre-occupied by an established community. This is probably
due to less interspecific competition in the former habitat. No significant difference in abundance or species richness was
observed between defaunated and natural sediments after 15 months, suggesting that a stable community had been achieved, although
minor variations in species composition were still discernible between defaunated and natural sediments.
Received: 24 May 1999 / Accepted: 20 October 1999 相似文献
916.
917.
918.
生物处理过程中活性污泥对氯代芳香化合物吸附性能的研究 总被引:8,自引:0,他引:8
本文研究了邻二氯苯 和邻氯酚生物处理过程中在活性污泥上的吸附特性及影响因素。通过测定等温吸附曲线,表明这两种有机化合物在活性污泥上的吸附符合线性吸附等温式:属于在疏水键力作用下的表面物理吸附,对难溶于水的邻二氯苯具有较强的吸附能力。 相似文献
919.
920.
从监测目标、监测点位布设及采样频率等几个方面论述了地面水监测网的设计及优化,简要地回顾了80年代中期以来地面水监测网设计及优化方面的部分研究情况。通过综述指出了监测目标是整个监测计划的重要方面,应用优化技术必须以监测目标的确定为前提;采样设计的统计学分析是监测网设计问题的中心;监测网设计可归结为额定预算条件下寻求最优统计功效或在特定统计功效下寻求费用最低值;统计法和模拟法相结合是地面水监测网设计及 相似文献