不干胶废弃物热解与燃烧动力学特性

采用热重分析方法对不干胶废弃物(PSAs)进行了热解和燃烧失重分析,并采用Doyle法拟合计算了PSAs热解和燃烧动力学参数。结果表明:当温度低于200℃或高于600℃,PSAs的热解和燃烧失重过程具有性;300~600℃时,PSAs热解过程具有3个失重峰,而其燃烧过程具有2个失重峰。动力学分析结果表明:PSAs的热解是由多阶段复杂的热裂解反应组成,其热解过程可用4个一级反应来描述,随着升温速率的提高热解阶段第1峰区表观活化能降低;而第2、3峰区以及半焦深度裂解阶段的第4峰区活化能逐渐升高;PSAs燃烧过程可用3个一级反应来描述,随着升温速率的提高,PSAs燃烧过程的表观活化能均逐渐降低,并且燃烧表观活化能均低于热解表观活化能。     

阳宗海沉积物中磷的稳定性

絮凝剂(FeCl3)治理阳宗海砷污染的过程中,水体中的磷被大量沉积进入底泥,弄清其是否会在环境条件变化后发生反溶形成二次污染对湖泊富营养化防治具有重要意义。通过模拟实验模拟泥-水界面pH变化、物理扰动和微生物活动的变化,旨在分析这些环境因子变化对沉积物中磷溶出的影响。结果表明,阳宗海水体在目前这种磷浓度下,底泥的磷会随时间的增加而溶出再次造成水体磷污染,当暴露在清洁水条件下时磷的释放率会增加;这种由于絮凝剂吸附沉淀到湖底的磷,在上覆水pH增加0.5时底泥磷解吸附释放速率增加;每年秋季湖泊上下层水的交换活动会造成水体磷浓度的季节性升高,形成不可忽视的磷内源。而夏季水温分层导致湖泊底部厌氧,使厌氧微生物活性增强,这将进一步促进底泥中磷的释放。     

Comprehensive Environmental Investigation at Former Industrial/Petroleum Underground Storage Tank Sites in Long Beach,CA: A Forensic Perspective

Two industrial sites were investigated based on years of available hydrogeologic information and monitoring data for soil and groundwater. Collected data were forensically evaluated using age-dating and fingerprinting methods. The previous business uses of the project sites were as a gas station, laundry/dry-cleaning service, and car wash with petroleum underground storage tanks (USTs). As a result, these sites were exposed to a number of toxic contaminants at relatively high concentrations. Source control was necessary for successful remediation and the ultimate removal of the remaining compounds from these industrial sites. Although contaminated soil around the source was excavated during the remedial action and the high concentrations of contaminants were reduced, typical groundwater contaminants such as petroleum hydrocarbons as gasoline (TPH-G), benzene, toluene, ethylbenzene, xylenes (BTEX), and oxygenates including methyl tert-butyl ether (MTBE), diisopropyl ether (DIPE), ethyl tert-butyl ether (ETBE), tert-amyl methyl ether (TAME), and tert-butyl alcohol (TBA) were persistently found at the studied sites around the source points. The plume and concentration of contaminants had changed their shapes and strength for all monitoring periods. Thus, additional source control seems to be a requirement for the complete removal of source contamination, which must be ascertained with groundwater and soil monitoring on a regular time base. For the study sites, monitored natural attenuation was relatively feasible for the long-term plan; however, it did not offer a perfect remediation solution for an ultimate goal because of residual toxic compounds that might have affected the surrounding residential areas at higher concentrations than their health limits. Therefore, as a remediation strategy, the combination of clean-up technology and natural attenuation with monitoring activities are more highly recommended than either clean-up or natural attenuation used separately.     

密相塔半干法烟气脱硫塔内加湿降温及其对脱硫效率的影响

为了实现密相塔半干法脱硫工艺的精确加湿进一步提高系统脱硫效率,利用推导出的传热传质计算方法,得到烟气温度降低和加水量的关系.结合3组密相塔半干法工程实际数据,发现理论计算值和实测值误差区间仅为2.9%~5.4%.通过选取河北某钢厂210 m2烧结烟气密相塔半干法脱硫项目实际在线检测数据,发现循环脱硫灰含湿量为3%的系统脱硫效率整体高于含湿量为5%和4%的样品,最大值达93.56%.通过粒度分析、扫描电镜、X射线衍射及差热-热重对2种不同含湿量的循环脱硫灰进行表征,结果表明,含湿量为3%的循环脱硫灰较含湿量为5%的样品粒径小、比表面积大,无团聚现象,物相分析还证实相对于含湿量为5%样品,其Ca(OH)2和结晶水含量少,几乎都是CaSO4和CaSO3干态物质,因此脱硫反应进行彻底,脱硫效率较高.     

双氰胺-甲醛聚合物-聚合氯化铝复合絮凝剂的合成及应用

以双氰胺、甲醛、氯化铝为主要原料,加入添加剂合成了双氰胺-甲醛聚合物（DF）-聚合氯化铝（PAC）复合絮凝剂。采用模拟印染废水考察了各种因素对DF—PAC复合絮凝剂混凝脱色性能的影响。实验结果表明,在双氰胺、甲醛、氯化铝、添加剂加入量分别为29．1,57．8,4．8,12．5g,反应温度（70±1）℃、反应时间2．5h的条件下制得的DF—PAC复合絮凝剂的絮凝脱色性能良好,COD去除率不小于90％,色度去除率不小于99％。与PAC和DF絮凝剂相比,DF—PAC复合絮凝剂对实际印染废水的絮凝脱色效果更好。     

四氮唑废水处理工艺设计

高浓度、高盐分的四氮唑生产废水通过三效蒸发浓缩,馏出液经铁炭氧微电解和混凝预处理,再采用水解酸化一接触氧化一反应二沉主体组合工艺进行处理。研究了该工艺所需构筑物和设备的设计与选型。该工艺在正常运行条件下,处理后出水pH6～9,COD 302mg／L,BOD5 108mg／L,SS30mg／L,色度36倍,水质达到GB8978--1996（污水综合排放标准》三级标准。     

沼液的综合利用

沼液是厌氧发酵的残留物,由于其富含营养物质及微量元素,可提高动植物的抗病能力,故已在农业、畜牧业、养殖业等方面得到广泛应用.阐述了沼液的基本性质,并就其作为饲料掺拌剂、肥料、浸种剂、农药等的应用现状做了综述.     

Status and fuzzy comprehensive assessment of combined heavy metal and organo-chlorine pesticide pollution in the Taihu Lake region of China

The status of combined heavy metal and organo-chlorine pesticide (OCPs; i.e. HCH and DDT) pollution was investigated and the soil environmental quality of the Taihu Lake watershed, one of the most developed regions in China, was evaluated using a fuzzy comprehensive assessment. Statistical analyses showed the presence of combined pollution in the soil. At many sampling sites, heavy metal concentrations were above corresponding background values, indicating the effects of extraneous pollutants. It has been over 20 years since China banned the use of OCPs, but they can still be found in soil samples of this region. HCH levels at all investigated sites were below the Chinese Environmental Quality Standard for Soils. Fuzzy comprehensive assessment showed that the overall soil quality in this region could be categorized as class I. Nevertheless, the high coefficients of variation for levels of DDT, Cd and Hg indicated the existence of some point-source pollution. Continuous monitoring and further studies of the region are recommended to prevent pollution of farmland from these sources.     

大气中SO2的液相氧化研究

大气中ＳＯ２液相氧化是形成酸雨的重要途径，降雨中含有各种无机离子和有机物质，它们可能催化或抑制液相氧化反应的进行。本文根据四川酸雨样品组成，进行了ＳＯ２在模拟雨水及实际雨水中的氧化实验，考查了Ｖ，Ｆｅ，Ｍｎ等离子对ＳＯ２氧化的催化作用，Ｈ２Ｏ２对ＳＯ２的氧化以及降水中有机物质甲醛对各反应的影响。实验结果为了解酸雨的成固，研究酸雨控制对策提供了科学依据。