全文获取类型
收费全文 | 159篇 |
免费 | 8篇 |
国内免费 | 86篇 |
专业分类
安全科学 | 12篇 |
废物处理 | 22篇 |
环保管理 | 20篇 |
综合类 | 79篇 |
基础理论 | 37篇 |
污染及防治 | 69篇 |
评价与监测 | 5篇 |
社会与环境 | 4篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 3篇 |
2022年 | 10篇 |
2021年 | 4篇 |
2020年 | 6篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 11篇 |
2016年 | 4篇 |
2015年 | 8篇 |
2014年 | 11篇 |
2013年 | 17篇 |
2012年 | 11篇 |
2011年 | 13篇 |
2010年 | 6篇 |
2009年 | 14篇 |
2008年 | 15篇 |
2007年 | 10篇 |
2006年 | 12篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 13篇 |
2002年 | 5篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 17篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有253条查询结果,搜索用时 15 毫秒
241.
Wenyan Wang Wei Ouyang Fanghua Hao Yun Luan Bo Hu 《Frontiers of Environmental Science & Engineering》2016,10(4):17
The dynamics of agricultural and forestry biomass are highly sensitive to climate change, particularly in high latitude regions. Heilongjiang Province was selected as research area in North-east China. We explored the trend of regional climate warming and distribution feature of biomass resources, and then analyzed on the spatial relationship between climate factors and biomass resources. Net primary productivity (NPP) is one of the key indicators of vegetation productivity, and was simulated as base data to calculate the distribution of agricultural and forestry biomass. The results show that temperatures rose by up to 0.37°C/10a from 1961 to 2013. Spatially, the variation of agricultural biomass per unit area changed from -1.93 to 5.85 t·km–2·a–1 during 2000–2013. More than 85% of farmland areas showed a positive relationship between agricultural biomass and precipitation. The results suggest that precipitation exerts an overwhelming climate influence on agricultural biomass. The mean density of forestry biomass varied from 10 to 30 t·km–2. Temperature had a significant negative effect on forestry biomass in Lesser Khingan and northern Changbai Mountain, because increased temperature leads to decreased Rubisco activity and increased respiration in these areas. Precipitation had a significant positive relationship with forestry biomass in south-western Changbai Mountain, because this area had a warmer climate and stress from insufficient precipitation may induce xylem cavitation. Understanding the effects of climate factors on regional biomass resources is of great significance in improving environmental management and promoting sustainable development of further biomass resource use. 相似文献
242.
采用固相微萃取(SPME)与气相色谱-质谱联用,分析了3种养殖模式鱼塘沉积物中氯酚类(CPs)化合物的污染特征.结果表明,一般四大家鱼养殖模式(A)沉积物中总CPs质量分数(干质量)为9.91 ng·g-1,猪.鱼综合养殖模式(B)与鸭-鱼综合养殖模式(C)沉积物总CPs质量分数分别为7.79 ng·g-1和4.84 ng·g-1.总CPs及15种CPs化合物在A、B模式和鸭-鱼综合养殖模式(C)沉积物中的分布特征相似,质量分数由高到低的顺序为A模式,B模式,C模式.沉积物中质量分数比较高的一氯酚、二氯酚、三氯酚和四氯酚分别是4-CP、2,4-DCP、2,4,6-TCP和2,3,4,6-TeCP.五氯酚(PCP)质量分数与4-CP、2,5+2,6+3,5-DCP、3,4-DCP、2,4,5-TCP、2,3,6-TCP、2,3,4-TCP、2,3,5,6-TeCP、2,3,4,6-TeCP、2,3,4,5-TeCP等氯酚化合物质量分数显著正相关,显示PCP与它们之间存在降解物与产物的关系.参照美国EPA相关标准,上述鱼塘沉积物中的PCP和Ky氯酚(2,3,4,6-TeCP、2,4,6-TCP和PCP)导致生态风险的可能性较低. 相似文献
243.
Residue of pentachlorophenol in freshwater sediments and human breast milk collected from the Pearl River Delta, China 总被引:3,自引:0,他引:3
Pentachlorophenol (PCP) was investigated in freshwater sediments and human breast milk collected from the Pearl River Delta, China. The average level of PCP in river sediments was 7.93 ng/g based on dry weight, ranging from 1.44 to 34.4 ng/g. As to the sediments from fishponds, samples from Zhongshan had the highest PCP levels (37.5 ng/g on average), followed by Dongguan (21.1 ng/g on average) and the least in Shenzhen (3.69 ng/g on average) and Shunde (2.20 ng/g on average). Negative relationship was obtained between the PCP level and pH value in sediment (r=0.553, n=13, p<0.05), while positive relationship was found between the PCP levels and the total organic matter (TOM) levels in sediment (r=0.700, n=17, p<0.01). These results indicated that pH and TOM played important roles during the process of PCP settling down to the sediment. PCP was also detected in human breast milk with an average of 2.15 ng/g. The PCP concentration increased with the age increasing of donors. The estimated PCP body burden for mother, daily and yearly PCP intake of infants ranged from 0.16 to 4.17 mg/person, from 0.26 to 10.23 mug/infant.day and from 0.09 to 3.73 mg/infant.year, respectively. 相似文献
244.
245.
Deyin Hou Jun Wang Changwei Zhao Baoqiang Wang Zhaokun Luan Xiangcheng Sun 《环境科学学报(英文版)》2010,22(12):1860-1867
The direct contact membrane distillation applied for fluoride removal from brackish groundwater was investigated.The self-prepared polyvinylidene fluoride membrane exhibited high rejection of inorganic salt solutes.The maximum permeate flux 35.6 kg/(m2 ·hr) was obtained with the feed solution at 80°C and the cold distillate water at 20°C.The feed concentration had no significant impact on the permeate flux and the rejection in fluoride.The precipitation of CaCO3 would clog the hollow fiber inlets and foul the membrane surface with increasing concentration factor when natural groundwater was used directly as the feed,which resulted in a rapid decline in the module efficiency.This phenomenon was diminished by acidification of the feed.The experimental results showed that the permeate flux and the quality of obtained distillate kept stable before concentration factor reached 5.0 with the acidified groundwater as feed.The membrane module efficiency began to decline gradually when the feed continued to be concentrated,which can be mainly attributed to the formation of CaF2 deposits on the membrane surface.In addition,a 300 hr continuous fluoride removal experiment of acidified groundwater was carried out with concentration factor at 4.0,the permeate flux kept stable and the permeate fluoride was not detected. 相似文献
246.
Xiaojing Ren Changwei Zhao Songshan Du Tao Wang Zhaokun Luan Jun Wang Deyin Hou 《环境科学学报(英文版)》2010,22(9):1335-1341
The feasibility of employing nanofiltration for the removal of chromium(VI) from wastewater was investigated. Poly (m-phenylene
isophthalamide) (PMIA) was used to fabricate asymmetric nanofiltration membrane through the phase-inversion technique. Scanning
electron microscopy (SEM) and atomic force microscopy (AFM) were used to characterize the obtained membrane, and the both
confirmed a much smoother surface which could reduce membrane fouling. The PMIA membrane showed di erent rejections to
electrolytes in a sequence of Na2SO4 > MgSO4 > NaCl > MgCl2, which was similar to the sequence of the negatively charged
nanofiltration membranes. Separation experiments on chromium(VI) solution were conducted at various operating conditions, such
as feed concentration, applied pressure and pH. It is concluded that chromium(VI) could be e ectively removed from chromiumcontaining
wastewater by the PMIA nanofiltration membranes while maintaining their pollution resistance under alkaline condition. 相似文献
247.
碳(C)、氮(N)、磷(P)是土壤重要的营养元素,其生态化学计量特征可以反映土壤供肥能力和质量状况,在揭示生态系统稳态机制中具有重要作用.水盐环境对河口湿地生态化学计量特征具有重要影响,但土壤C、 N、 P生态化学计量特征对水盐环境变化的响应仍不清楚.以黄河口湿地为研究对象,采用土柱移位培养法,将淡水湿地土壤分别移位至不同潮滩部位(高潮滩、中潮滩和低潮滩)的盐沼湿地,研究水盐环境对C、 N、 P生态化学计量特征的影响.结果表明,移位23个月后,淡水湿地土壤含水量(SWC)和电导率(EC)与C、 N、 P生态化学计量特征均发生了不同程度的变化.土壤SWC在高潮滩和中潮滩降低(P<0.05),在低潮滩升高(P<0.05); EC在3种潮滩上均有不同程度的升高(P<0.05).土壤有机碳(TOC)和全氮(TN)在高潮滩显著降低(P<0.05),全磷(TP)则在中潮滩和高潮滩显著降低(P<0.05); C∶N在高潮滩和中潮滩及C∶P和N∶P在高潮滩显著降低(P<0.05); C、 N、 P生态化学计量比在低潮滩变化均不显著(P>0.05).水盐环境主要... 相似文献
248.
ZnBiYO4 was synthesized by a solid-state reaction method for the first time. The structural and photocatalytic properties of ZnBiYO4 were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV–Vis diffuse reflectance.ZnBiYO4 crystallized with a tetragonal spinel structure with space group I41/A. The lattice parameters for ZnBiYO4 were a = b = 11.176479 and c = 10.014323 . The band gap of ZnBiYO4 was estimated to be 1.58 e V. The photocatalytic activity of ZnBiYO4 was assessed by photodegradation of methyl orange under visible light irradiation. The results showed that ZnBiYO4 had higher catalytic activity compared with N-doped Ti O2 under the same experimental conditions using visible light irradiation. The photocatalytic degradation of methyl orange with ZnBiYO4 or N-doped Ti O2 as catalyst followed first-order reaction kinetics, and the first-order rate constant was 0.01575 and 0.00416 min-1for ZnBiYO4 and N-doped Ti O2, respectively. After visible light irradiation for 220 min with ZnBiYO4 as catalyst, complete removal and mineralization of methyl orange were observed. The reduction of total organic carbon, formation of inorganic products, SO2-4and NO-3, and evolution of CO2 revealed the continuous mineralization of methyl orange during the photocatalytic process. The intermediate products were identified using liquid chromatography–mass spectrometry. The ZnBiYO4/(visible light) photocatalysis system was found to be suitable for textile industry wastewater treatment and could be used to solve other environmental chemical pollution problems. 相似文献
249.
聚合氯化铁在微絮凝-深床过滤工艺中的应用 总被引:7,自引:0,他引:7
以聚铝(PAC)为参照比较研究了聚合氯化铁(PFC)在微絮凝深床过滤工艺中的应用效果.结果表明PFC投药量少(Fe:Al=3:5),其水头滤程可达63h,周期产水率可达1504m3/m2,而PAC的水头滤程为53h,周期产水率为1266 m3/m2;PFC表现出利于延长运行周期,提高产水率等优势.通过截污机理研究表明,PFC具有形成絮体快,与滤料作用迅速,脱水性能好等特点,与PAC相比PFC更适用于微絮凝-深床过滤工艺. 相似文献
250.
利用粤港珠三角区域空气质量监控网中天湖、金果湾与万顷沙3个区域站2010年全年SO2、NO2、PM10、O3、PM2.5与CO自动监测的数据,分析了实施环境空气质量新标准(GB 3095—2012)对这3个子站空气质量评价的影响。研究发现,若采用新标准,万顷沙的NO2、PM10和PM2.5年均浓度将不同程度超标。这3个子站空气质量达标率下降7~28个百分点,空气污染指数从91%~99%下降至63%~91%;O3的引入是导致空气质量达标率下降的最主要的原因;O3将取代PM10成为最主要的首要污染物,出现频率大于50%,且O3(8 h)平均浓度的影响大于O3 (1 h)浓度的影响。PM2.5的纳入也是导致空气质量达标率下降的重要因素,其超标率为3%(金果湾)~16%(万顷沙)。NO2标准的收严未对天湖与金果湾空气质量评价造成影响,但导致万顷沙NO2的超标率从2%上升至10%,且NO2作为首要污染物的比例达24%。 相似文献