Assesment of Trace Elements and Organic Pollutants from a Marine Oil Complex into the Coral Reef System of Cayo Arcas, Mexico

Possible contaminants produced by the Petroleos Mexicanos (PEMEX) marine oil complex in the vicinity of the Cayo Arcas (Mexico) coral reef ecosystem were evaluated by analyzing sediments and sea water for hydrocarbons and metal elements. We found that the concentrations of aliphatic hydrocarbons in the sea water were generally low, with the highest values detected near the oil station; the concentration of polycyclic aromatic hydrocarbons (PAHs) was generally below the detection limit. The hydrocarbons found in the sediments seem to have a pyrogenic origin, and were probably produced by marine traffic in the study area. The total PAH concentration did not exceed the NOAA criteria, although levels of some individual PAHs did. The only metal detected in the sea water at high concentrations was nickel. The Ni/V ratio in the sediments indicates the contribution of crude oil to the system. The high content of Ni and Zn was attributed to the ballast waters from the oil tankers that load at the station's monobuoys. The presence of fine sediments that commonly originate from terrestrial ecosystems supported this assumption.     

The Precautionary Principle as a Robust Cost-Effectiveness Problem

This paper offers an interpretation of the precautionary principle in terms of a safety target that a decision-maker has to reach at a minimal cost in a robust way. A two-period model is used. The precautionary principle corresponds to a situation in which the decision-maker, facing an ex ante indecision, is not able to reach a safe target from the initial condition in a worst-case framework. However, he can efficiently succeed whenever the uncertainty at the second period is revealed to him. An example coping with the management of a renewable resource illustrates the general results of the paper.

Evolution of building façade road traffic noise levels in Flanders

The evolution of daytime fa?ade noise levels by road traffic at 250 dwellings in Flanders is assessed. Three identical man-operated measurement campaigns have been conducted in the years 1996, 2001 and 2009, during fall. A practical methodology has been developed, based on short time noise measurements and context observations at these locations. The uncertainty introduced by short-term sampling has been quantified as a function of the noise level. Furthermore, a correction is proposed for measuring at a random moment during daytime. Analysis of the data showed that road traffic noise levels hardly changed globally over this period of 13 years. The distribution of changes in noise level at corresponding measurement locations is nevertheless rather wide-all improvements are equally compensated by increases in noise levels at other locations. The percentage of the dwelling fa?ades exposed to daytime noise levels above 65 dBA has increased slightly between 1996 and 2001, but seems to stagnate in 2009. In spite of the increased interest and actions of policy makers during the past decades, noise exposure caused by road traffic at dwelling fa?ades is a persistent problem.     

Methods,fluxes and sources of gas phase alkyl nitrates in the coastal air

The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3–C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO₂ levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor.     

环境监测主动适应生态文明建设新特征的路径

简述了环境保护新特征的系统诊断,指出面对环境保护呈现的新特征,环境监测管理及建设存在环境监测的各项技术、标准、规范、管理措施滞后于社会经济基本现代化的发展要求,体制机制滞后于环境保护的发展要求,服务能力滞后于公共服务的需求,质量管理滞后于严格的环境管理需求等问题。提出,应从传统的环境监测向资源环境承载力监测预警转变,从条块管理向垂直管理的体制转变,从监测信息相对封闭向监测信息主动公开转变,由单纯依靠自身监测向依靠各部门和全社会监测转变,从污染物总量监测为主向污染物总量,环境质量监测并重转变,从实验室质控为主向全过程质控转变,从以生态,环境为核心的环境监测向以人为本的环境监测转变。     

Mitigation Portfolio and Policy Instruments When Hedging Against Climate Policy and Technology Uncertainty

In this paper, we use a stochastic integrated assessment model to evaluate the effects of uncertainty about future carbon taxes and the costs of low-carbon power technologies. We assess the implications of such ambiguity on the mitigation portfolio under a variety of assumptions and evaluate the role of emission performance standards and renewable portfolios in accompanying a market-based climate policy. Results suggest that climate policy and technology uncertainties are important with varying effects on all abatement options. The effect varies with the technology, the type of uncertainty, and the level of risk. We show that carbon price uncertainty does not substantially change the level of abatement, but it does have an influence on the mitigation portfolio, reducing in particular energy R&D investments in advanced technologies. When investment costs are uncertain, investments are discouraged, especially during the early stages, but the effect is mitigated for the technologies with technological learning prospects. Overall, these insights support some level of regulation to encourage investments in coal equipped with carbon capture and storage and clean energy R&D.     

Application of DET (diffusive equilibrium in thin films) and DGT (diffusive gradients in thin films) techniques in the study of the mobility of sediment-bound metals in the outer section of Songkhla Lake, Southern Thailand

The techniques of diffusive equilibrium in thin films (DET) and diffusive gradients in thin films (DGT) were used in the outer section of Songkhla Lake, Thailand in order to obtain high-resolution profiles of total dissolved and labile trace metals in the sediment pore water and investigate benthic fluxes. Six DET probes and six DGT probes were deployed at the mouths of the Phawong, Samrong and U-Taphao canals. A close correspondence could be observed between the high-resolution profiles of Fe and As, revealing a close link between the reductive remobilization of Fe oxides and the reduction of As(V). Co and Ni DGT profiles showed a close correspondence with Mn, but a narrow mobilization zone. Reductive mobilization of Mn oxides and associated metals and sulfide precipitation control the behaviour of these metals. The DGT profiles of Cu, Zn, Cd and Pb show surface maximum, probably linked to organic matter degradation. Important benthic fluxes, especially for As, were found at the mouths of the U-Taphao and Phawong canals.     

空气-乙炔火焰原子吸收法测铬时的干扰及消除

对空气-乙炔火焰原子吸收法测铬(Cr)时共存元素对其测定结果的干扰进行研究。结果表明,当ρ(共存元素)/ρ(Cr)100时,Mg、Co、Al、V、Ni、Fe、Na、Ca对Cr测定有影响,而K、Mn、Zn、Mo、Pb、Si、Cu均不影响Cr的测定;当ρ(共存元素)/ρ(Cr)为10和30时,加入1%HNO_3和2%NH_4Cl可消除干扰;当ρ(共存元素)/ρ(Cr)30时,加入5%HCl和超过1%的NH_4Cl可消除干扰;5%HCl作为介质消除Cr测定干扰的效果要优于1%HNO_3介质。     

Air pollution impact assessment on agroecosystem and human health characterisation in the area surrounding the industrial settlement of Milazzo (Italy): a multidisciplinary approach

In order to evaluate the impact of atmospheric pollutants emitted by the industrial settlement of Milazzo (Italy) on agriculture, sulphur dioxide and ozone levels in air were monitored and the data were used to estimate yield losses of the most widespread cultures. Trace element concentrations in crops and soils were also detected and metabolic profiles of soil microbial communities were considered. Vibrio fischeri test was used to appraise airborne pollutant ecotoxicity and epidemiological studies on causes of death distribution were carried out to characterize health state of people living in the area. All the sampling points were selected in farms on the basis of a theoretical meteo-diffusive model of industrial air pollutants. Experimental SO₂ and O₃ values mainly exceeded the threshold established by Italian and EU regulations to protect vegetation and they correspond to estimated significant crop losses. Conversely toxic element residues in soils and in agroalimentary products were generally lower than the fixed values. SO₂ and O₃ concentrations, toxic element contents and ecotoxicity levels of airborne pollutants were not related only to industrial site emissions, while the fluctuations on metabolic profiles of soil microbial communities seem to agree with the predicted deposition of xenobiotic compounds from the industrial plants. The epidemiological study evidenced a better health state of populations living in the investigated area than in the Messina province and the Sicily region but, inside the area, males living in the municipalities closest to the industrial settlement exhibited a worst health state than those in the very far ones.     

Human Capital,Innovation, and Climate Policy: an Integrated Assessment

This paper looks at the interplay between human capital and innovation when climate and educational policies are implemented. Following recent empirical studies, human capital and general purpose research and development (R&D) are introduced in an integrated assessment model used to study the dynamics of climate change mitigation. Our results suggest that climate policy stimulates general purpose as well as clean R&D but reduces the incentive to invest in human capital formation. Both innovation and human capital have a scale effect, which increases pollution, as well as a technique effect, which saves emissions for each unit of output produced. While the energy-saving effect prevails when innovation increases, human capital is pollution-using, also because of the gross complementarity between the labor and energy input. When the role of human capital is the key input in the production of general purpose and energy knowledge is accounted for, the crowding-out of education induced by climate policy is mitigated, though not completely offset. By contrast, a policy mix that combines educational as well as climate objectives offsets the human capital crowding-out, at moderate and short-term costs. Over the long run, the policy mix leads to global welfare gains.