GEOHYDROLOGY AND HYDROCHEMISTRY OF THE DAKOTA AQUIFER,CENTRAL UNITED STATES1

ABSTRACT: The Dakota aquifer, composed of the Dakota Sandstone and stratigraphically equivalent sandstone units of Cretaceous age, is the upper-most regional aquifer underlying the extensively developed High Plains aquifer of the midwestern United States. The concentration of dissolved solids in ground water of the Dakota aquifer ranges from less than 500 milligrams per liter in calcium bicarbonate type water in the eastern outcrop area to more than 100,000 milligrams per liter in sodium chloride type oilfield brine in the Denver Basin to the west. Preliminary maps showing the distribution of dissolved solids confirm the complex nature of the Dakota aquifer as inferred from stratigraphic and hydraulic evidence. Extensive vertical leakage through confining layers, local recharge at the truncated eastern boundary, and a barrier to recharge along the western edge of the Denver Basin are consistent with the distribution of hydraulic head and dissolved solids.     

Modeling channel management impacts on river migration: a case study of Woodson bridge state recreation area,Sacramento river,California, USA

Understanding how hydraulic factors control alluvial river meander migration can help resource managers evaluate the long-term effects of floodplain management and bank stabilization measures. Using a numerical model based on the mechanics of flow and sediment transport in curved river channels, we predict 50 years of channel migration and suggest the planning and ecological implications of that migration for a 6.4-km reach (river miles 218–222) of the Sacramento River near the Woodson Bridge State Recreation Area, California, USA. Using four different channel management scenarios, our channel migration simulations suggest that: (1) channel stabilization alters the future channel planform locally and downstream from the stabilization; (2) rock revetment currently on the bank upstream from the Woodson Bridge recreation area causes more erosion of the channel bank at the recreation area than if the revetment were not present; (3) relocating the channel to the west and allowing subsequent unconstrained river migration relieves the erosion pressure in the Woodson Bridge area; (4) the subsequent migration reworks (erodes along one river bank and replaces new floodplain along the other) 26.5 ha of land; and (5) the river will rework between 8.5 and 48.5 ha of land in the study reach (over the course of 50 years), depending on the bank stabilization plan used. The reworking of floodplain lands is an important riparian ecosystem function that maintains habitat heterogeneity, an essential factor for the long-term survival of several threatened and endangered animal species in the Sacramento River area.     

Photodegradation of the herbicide EPTC and the safener dichlormid, alone and in combination

Photodegradation of the herbicide EPTC (S-ethyl-N, N-dipropylthiocarbamate), and the safener dichlormid (2,2-dichloro-N, N-diallylacetamide) has been examined in methanol and in water solutions. Irradiation of EPTC and dichlormid with UV light at 254 nm caused rapid degradation in both media. Remarkable and gradual changes in color of EPTC irradiated solution was observed from clear to yellow then to intense orange. EPTC half-life of elimination in water was 14.0, and 18.5 min, and in methanol 37.2 and 32.2 min, when irradiated with and without dichlormid, respectively. There was significant difference between rate of EPTC degradation in water and methanol in the presence or in the absence of dichlormid. Negligible degradation of EPTC or dichlormid at > 290 nm was observed. Photoproducts were separated and identified using GC or/and thin-layer chromatography then identified using mass spectrometry. It appeared that some products have high molecular weight that formed as a result of dimerization. This is possibly a result of the coupling of radicals that formed through EPTC degradation. The cleavage of C-S and C-N bonds accounted for the formation of these radicals. Gradual dealkylation of the acid chains of EPTC has also occurred. EPTC-sulfoxide, EPTC-sulfone, Propylamine and dipropylamine were detected as photoproducts of EPTC at 254 nm. Dichlormid pathways of degradation at 254 nm were characterized as dechlorination, dealkylation, and hydrolysis both in water and methanol. The findings showed that dichlormid did not significantly affect EPTC photodegradation either at 254 nm or at > 290 nm. The biological/toxicological properties of the photoproducts need further study, particularly the dimer compounds.     

Reactive nitrogen and public policies for environmental protection

A core goal of both US and European pollution control policies has been to establish rules and regulations pertaining to the movement of reactive-nitrogen (Nr) through the environment. This is manifest in US federal legislation such as the Clean Air Act Amendments and the Clean Water Act Amendments and in various protocols of the United Nations Economic Commission for Europe (UNECE) and its Convention on Long-Range Transboundary Air Pollution (CLRTAP). In this paper, we begin by reviewing the two US laws and their effectiveness and make some comparisons with the approaches used mainly in Europe by the UNECE and CLRTAP. Next we use the Mississippi drainage/Gulf of Mexico hypoxia case study to highlight the importance of applying a "systems approach" to address the reactive nitrogen problem at the regional scale. After briefly posing a number of unanswered questions related to nitrogen control policies, we conclude by sketching a blueprint for future actions related to the development of improved policies to regulate reactive nitrogen.     

Prediction of ambient PM10 and toxic metals using artificial neural networks

In this study, an artificial neural network is employed to predict the concentration of ambient respirable particulate matter (PM10) and toxic metals observed in the city of Jaipur, India. A feed-forward network with a back-propagation learning algorithm is used to train the neural network the behavior of the data patterns. The meteorological variables of wind speed, wind direction, relative humidity, temperature, and time are taken as input to the network. The results indicate that the network is able to predict concentrations of PM10 and toxic metals quite accurately.     

What's wrong with virtual trees? Restoring from stress in a mediated environment

Restorative environments are environments that can help restore depleted attention resources or reduce emotional and psychophysiological stress. These effects have been demonstrated not only in real environments, but also in mediated (projected, broadcasted, etc.) environments. However, the importance of simulation qualities to restoration outcomes has not been systematically studied. The present experiment investigates the importance of immersion in a mediated environment in relation to restoration. Is a projected natural environment more restorative when one is more immersed in it, and hence feels more present in it? The hypothesis was that a more immersive projection would show stronger stress-reducing effects of a mediated restorative environment. After performing a stress-inducing task, participants watched a nature film on either a high or low immersive screen. Physiological measurements (heart period and skin conductance level) were taken throughout the experiment. In addition, we measured self-reported affect and presence using the ITC-Sense of Presence Questionnaire. Significant effects of the screen size manipulation appeared on physiological measures, but not on self-reported affect. The data showed an interaction between screen size and restorative phase on heart period and skin conductance level, indicating stronger restoration for the immersive screen condition over time. We therefore conclude that immersion enhances restorative potential of a mediated natural environment. Self-reported affect did correlate significantly with experienced presence, illustrating the relevance of this experiential counterpart of immersion, although a mediating effect of presence has not yet been established.     

CHARACTERIZATION OF HYDROLOGIC CONDITIONS TO SUPPORT PLATTE RIVER SPECIES RECOVERY EFFORTS1

ABSTRACT: Efforts are under way to recover habitat for several threatened and endangered species in and along the Platte River in central Nebraska. A proposed recovery program for these species requires a means of characterizing “wet” versus “normal” versus “dry” hydrologic conditions in order to set corresponding Platte River instream flow targets. Methods of characterizing hydrologic conditions in real time were investigated for this purpose. Initially, 10 watershed variables were identified as potentially valuable indicators of hydrologic conditions. Ultimately, six multiple linear regression equations were developed for six periods of the year using a subset of these variables expressed as frequencies of nonexceedence. The adequacy of these equations for characterizing conditions was assessed by evaluating their historic correlation to subsequent flow in the central Platte River (1947–1994). These equations explained 54 to 82 percent of variability in the observed flow exceedences in the validation datasets, depending upon the period of year evaluated. These equations will provide initial criteria for setting applicable flow targets to determine, in real time, whether water regulation projects associated with the species recovery effort can divert or store flows without conflicting with recovery objectives.     

Designating Air Quality Management Areas (AQMAs) in the UK Implications for Securing UK Air Quality Objectives

Across the United Kingdom, the majority of local authoritieshave now completed their first phase of local air qualityreview and assessment work, as required under the AirQuality Strategy for England, Scotland, Wales and NorthernIreland (DETR, 2000a). Emerging from this first phasework is an anticipated suite of over 110 Air QualityManagement Areas (AQMAs). These areas are identifiedlocations where one or more of the national air qualityobjectives are predicted to exceed by specific target dates,and their spatial extent and shape is emerging as highlyvariable. Local authorities are guided to use a variety ofscientific tools to underpin the scientific assessments, anda consideration of uncertainty in both the tools used andsubsequent delineation of AQMAs is likely to affect theemerging management areas significantly. With subsidiarity underpinning the process of local air qualitymanagement (LAQM), local decision-making is anticipated toinfluence the outcome of the LAQM process in its entirety,with the declaration of AQMAs necessitating the preparationand implementation of air quality action plans. UKexperience of the effective management of local air quality,through the designation of AQMAs, demonstrates a valuableframework for other European countries developing mechanismsto manage air quality locally.     

Chemical Changes in Sediment Pore-Waters of an Acidic Mining Lake After Addition of Organic Substrate and Lime for Stimulating Lake Remediation

In the past five years, enclosures have beeninstalled in an acidic mining lake in Lusatia to investigate insitu remediation processes. They were treated with straw, withstraw and Carbokalk, or with Carbokalk alone, where Carbokalkis a by-product of the sugar industry (solid precipitate ofnon-sugars after lime clarification of extracted sugar beetjuice). Sediment samples were taken as cores to get informationabout the behaviour of organic and inorganic components insediment pore-water with depth. Vertical distributions of pH,soluble reactive phosphate, nitrate, ammonium, silica,aluminium, iron, manganese, calcium, magnesium, sodium,potassium, sulphate, and DOC were measured. The resultingprofiles, each consisting of 15 data points at differentdepths, were compared by cluster analysis. The similarities ofsediment cores from different treated enclosures relating toprofiles of chemical components were discussed. Increasedconcentrations of potassium and sulphate were found in pore-water after substrate treatment. The data imply dissolution ofpotassium iron sulphate hydroxide minerals (jarosite) after anincrease of pH caused by dissolution of lime and by sulphatereducing processes which were stimulated by organic substrateaddition.