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831.
Sulfate removal from waste chemicals by precipitation 总被引:3,自引:0,他引:3
Chemical oxidation using Fenton's reagent has proven to be a viable alternative to the oxidative destruction of organic pollutants in mixed waste chemicals, but the sulfate concentration in the treated liquor was still above the acceptable limits for effluent discharge. In this paper, the feasibility of sulfate removal from complex laboratory wastewaters using barium and calcium precipitation was investigated. The process was applied to different wastewater cases (two composite samples generated in different periods) in order to study the effect of the wastewater composition on the sulfate precipitation. The experiments were performed with raw and oxidized wastewater samples, and carried out according to the following steps: (1) evaluate the pH effect upon sulfate precipitation on raw wastewaters at pH range of 2-8; (2) conduct sulfate precipitation experiments on raw and oxidized wastewaters; and (3) characterize the precipitate yielded. At a concentration of 80 g L(-1), barium precipitation achieved a sulfate removal up to 61.4% while calcium precipitation provided over 99% sulfate removal in raw and oxidized wastewaters and for both samples. Calcium precipitation was chosen to be performed after Fenton's oxidation; hence this process configuration favors the production of higher quality precipitates. The results showed that, when dried at 105 degrees C, the precipitate is composed of hemidrate and anhydrous calcium sulfate ( approximately 99.8%) and trace metals ( approximately 0.2%: Fe, Cr, Mn, Co, Ag, Mg, K, Na), what makes it suitable for reuse in innumerous processes. 相似文献
832.
Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review 总被引:6,自引:0,他引:6
Dias JM Alvim-Ferraz MC Almeida MF Rivera-Utrilla J Sánchez-Polo M 《Journal of environmental management》2007,85(4):833-846
Commercial activated carbon is a preferred adsorbent for the removal of micropollutants from the aqueous phase; however, its widespread use is restricted due to high associated costs. To decrease treatment costs, attempts have been made to find inexpensive alternative activated carbon (AC) precursors, such as waste materials. Some reviews report the use of waste materials for the preparation of AC; however, these studies are restricted to either type of wastes, preparation procedures, or specific aqueous-phase applications. The present work reviews and evaluates literature dedicated both to the preparation of AC by recycling different types of waste materials and also to its application in various aqueous-phase treatments. It is clear that conventional (from agriculture and wood industry) and non-conventional (from municipal and industrial activities) wastes can be used to prepare AC, that can be applied in various aqueous treatment processes, namely to remove organic pollutants, dyes, volatile organic compounds, and heavy metals. Moreover, high surface areas can be obtained using either physical or chemical activation; however, combined treatments might enhance the surface properties of the adsorbent, therefore increasing its adsorption capacity. It is evident from the revision made that AC prepared from both conventional and non-conventional wastes might effectively compete with the commercial ones. This happens mostly when the activation procedures are optimized considering both the raw material used to produce the carbons and the contaminants to be removed. 相似文献
833.
In multiphase systems capillary pressures play a significant role on fluid movement and retention. The facility to predict
the effect of different thermal remediation strategies requires the knowledge of the effect of temperature on capillary pressure-saturation
relationships in the soils.
The objective of recent study was (a) to develop a technique for routinely measuring the pressure-saturation curves of soil
samples saturated with a nonpolar liquid at different regulated temperatures (b) to build a database using the measured pressure-saturation
curves and the physical, chemical properties of the model soils (c) to establish the dependence of nonaqueous phase liquid
retention on the soil properties and the temperature.
The retention curves (extraction isotherms) with nonaqueous phase liquid were determined using a modified
pressure plate extractor. The wetting phase was a non-aromatic hydrocarbon distillation product. Pressure plates were designed and constructed in
the laboratory of our department. The temperature was held constant at 20, 40 and 60 ∘C.
Statistical analysis was performed involving selected soil parameters and the measured nonaqueous phase liquid retention data.
The results show that knowing some easily measurable soil parameters (bulk density, particle size distribution, humus and
lime content) we can estimate the nonaqueous phase liquid retention of the soils. The measured “extraction isotherms” provide
essential information about the temperature-dependency of pressure-saturation curves. 相似文献
834.
黄河口及邻近海域溶解态无机磷、有机磷、总磷的分布研究 总被引:3,自引:0,他引:3
于2003年8月下旬对黄河口及邻近海域进行了十船连续同步27h采样调查,分析了调查区域的溶解态无机磷、有机磷、总磷的平面分布、断面分布、时间分布特征.结果表明,在调查区域内,溶解态无机磷浓度很低,而溶解态有机磷浓度较高(占溶解态总磷的85%以上),是溶解态总磷的主要组成部分.各形态磷的平面分布、断面分布均呈现出由河口向邻近海域降低的趋势,溶解态总磷、溶解态有机磷梯度变化较溶解态无机磷更为明显;潮汐对河口浅水区的各形态磷浓度影响较大,对邻近调查海域的影响不明显. 相似文献
835.
Izaskun Zorita Joana Larreta Natalia Montero José Germán Rodríguez Javier Franco Ángel Borja 《Chemistry and Ecology》2013,29(5):432-445
Bioaccumulation and biological effects of pollution were assessed in mussels (Mytilus galloprovincialis) caged for one month at three sites in the Oiartzun estuary (south-eastern Bay of Biscay, Spain) with the aim of evaluating their usefulness within the investigative monitoring defined in the European Union Water Framework Directive (WFD). The highest concentrations of organic contaminants determined in mussels' tissue were detected towards the inner part of the estuary but no gradient pattern was found for metal bioaccumulation. Population fitness responses measured as condition index, stress on stress and gonad index were similar in all caged mussels and did not follow the organic pollution gradient. However, biomarkers determined at tissue, cell and protein level (histopathology, micronuclei frequency, malondialdehyde levels and vitellogenin-like protein levels) revealed a higher stress syndrome at the inner part of the estuary showing signs of genotoxicity, oxidative stress and endocrine disruption. Overall, the integrated chemical–biological approach in connection with mussel caging technique proved to be a useful tool to assess environmental pollution, allowing a better understanding of the cause–effect relationship within the investigative monitoring defined in the WFD. 相似文献
836.
Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials 总被引:47,自引:0,他引:47
Rauret G López-Sánchez JF Sahuquillo A Rubio R Davidson C Ure A Quevauviller P 《Journal of environmental monitoring : JEM》1999,1(1):57-61
The Standards, Measurements and Testing Programme (formerly BCR) of the European Commission proposed a three-step sequential extraction procedure for sediment analysis, following extensive expert consultations and two interlaboratory studies. This scheme was recently used to certify the extractable trace element contents of a sediment reference material (CRM 601). Although this procedure offers a means to ensure the comparability of data in this field, some difficulties concerning the interlaboratory reproducibility still remain, and a new project is currently being conducted to determine the causes of poor reproducibility in the extraction scheme. The final objective of the project is the certification of new sediment and soil reference materials for their extractable contents of Cd, Cr, Cu, Ni, Pb and Zn. This paper presents the results of a small-scale interlaboratory study, which aimed to test a revised version of the extraction schemes by comparing the original and the modified protocols using the CRM 601 sample. This work offers an improvement to the BCR sequential extraction procedure through intercomparison exercises. This improved procedure will allow the obtaining of CRMs to validate analytical data in the analysis of soils and sediments, and it will also facilitate comparability of data in the European Union. 相似文献
837.
L. M. Simon K. László M. Kotormán A. Vértesi K. Bagi J. Nemcsók 《Journal of environmental science and health. Part. B》2013,48(5):819-828
Abstract The effects of pyrethroid pesticides (deltamethrin, permethrin and cypermethrin) and an organophosphate ester (methidation) on the activities of carp trypsin, α‐chymotrypsin, carboxypeptidase A and lipase were studied. The enzymes were isolated from the gastrointestinal tract and the effects of the pesticides were investigated during incubation for 5 min. The activity of trypsin was influenced only slightly by the presence of deltamethrin and methidation, whereas permethrin and cypermethrin caused significant inhibition. The pyrethroid pesticides at lower concentrations resulted in a slight activation of α‐chymotrypsin. Methidation inhibited the α‐chymotrypsin activity by about 20%. These pesticides modified the lipase activity to a lesser extent; the highest inhibition was measured with cypermethrin. The carboxypeptidase A activity was inhibited by both pyrethroid pesticides and methidation. The results suggest that these pesticides might interact with the active conformation of the studied hydrolytic enzymes, resulting in changes in their activities. 相似文献
838.
Benyei Petra Cohen Marianne Gresillon Etienne Angles Stéphane Araque-Jiménez Eduardo Alonso-Roldán María Espadas-Tormo Isidro 《Regional Environmental Change》2018,18(2):595-605
Regional Environmental Change - In the context of climate change, concern is raising about the negative effects of some pruning waste management practices. On the one hand, burning of pruning... 相似文献
839.
Marmett Bruna Carvalho Roseana Böek Dorneles Gilson Pires da Silva Igor Martins Romão Pedro Roosevelt Torres Nunes Ramiro Barcos Rhoden Cláudia Ramos 《Environmental science and pollution research international》2020,27(31):39019-39028
Environmental Science and Pollution Research - Obesity and physical inactivity threaten human health, and both could be solved with exercise. However, a higher amount of pollutants is inhaled... 相似文献
840.
Despite much discussion about the utility of remote sensing for effective conservation, the inclusion of these technologies in species recovery plans remains largely anecdotal. We developed a modeling approach for the integration of local, spatially measured ecosystem functional dynamics into a species distribution modeling (SDM) framework in which other ecologically relevant factors are modeled separately at broad scales. To illustrate the approach, we incorporated intraseasonal water-vegetation dynamics into a cross-scale SDM for the Common Snipe (Gallinago gallinago), which is highly dependent on water and vegetation dynamics. The Common Snipe is an Iberian grassland waterbird characteristic of European agricultural meadows and a member of one of the most threatened bird guilds. The intraseasonal dynamics of water content of vegetation were measured using the standard deviation of the normalized difference water index time series computed from bimonthly images of the Sentinel-2 satellite. The recovery plan for the Common Snipe in Galicia (northwestern Iberian Peninsula) provided an opportunity to apply our modeling framework. Model accuracy in predicting the species’ distribution at a regional scale (resulting from integration of downscaled climate projections with regional habitat–topographic suitability models) was very high (area under the curve [AUC] of 0.981 and Boyce's index of 0.971). Local water-vegetation dynamic models, based exclusively on Sentinel-2 imagery, were good predictors (AUC of 0.849 and Boyce's index of 0.976). The predictive power improved (AUC of 0.92 and Boyce's index of 0.98) when local model predictions were restricted to areas identified by the continental and regional models as priorities for conservation. Our models also performed well (AUC of 0.90 and Boyce's index of 0.93) when projected to updated water-vegetation conditions. Our modeling framework enabled incorporation of key ecosystem processes closely related to water and carbon cycles while accounting for other factors ecologically relevant to endangered grassland waterbirds across different scales, allowed identification of priority areas for conservation, and provided an opportunity for cost-effective recovery planning by monitoring management effectiveness from space. 相似文献